Three-Dimensional Assembly of Polymer Microstructures at Low Temperatures

2004 ◽  
Vol 16 (6) ◽  
pp. 560-564 ◽  
Author(s):  
Y. Yang ◽  
C. Zeng ◽  
L. J. Lee
2002 ◽  
Vol 718 ◽  
Author(s):  
N.D. Zakharov ◽  
P. Werner

AbstractThe structure and composition of UMo8O26 synthesized by solid state reaction method have been investigated by High Resolution Transmission Electron Microscopy (HRTEM), Selected Area Electron Diffraction, and EDX microanalysis. The ordering of U vacancies results in considerable enlargement of unit cell parameters: an=6.44 nm, bn=1.45 nm, cn=1.6 nm. It is build up of four layers piled up in c direction. Each following layer is shifted relative to previous one by vector bn/4. Eight hexagonal tunnels in each layer are filled by U atoms, while the eight others are vacant (V). Interaction between U cations and vacancies is driving force for ordering. The variation of stoichiometry can be a reason for appearance of incommensurate modulations in these crystals. It seems plausible that this structure might also exhibit superconductivity at low temperatures.


Crystals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 127
Author(s):  
YongChao Wang ◽  
YinBo Zhu ◽  
HengAn Wu

The porous characteristics of disordered carbons are critical factors to their performance on hydrogen storage and electrochemical capacitors. Even though the porous information can be estimated indirectly by gas adsorption experiments, it is still hard to directly characterize the porous morphology considering the complex 3D connectivity. To this end, we construct full-atom disordered graphene networks (DGNs) by mimicking the chlorination process of carbide-derived carbons using annealing-MD simulations, which could model the structure of disordered carbons at the atomic scale. The porous characteristics, including pore volume, pore size distribution (PSD), and specific surface area (SSA), were then computed from the coordinates of carbon atoms. From the evolution of structural features, pores grow dramatically during the formation of polyaromatic fragments and sequent disordered framework. Then structure is further graphitized while the PSD shows little change. For the obtained DGNs, the porosity, pore size, and SSA increase with decreasing density. Furthermore, SSA tends to saturate in the low-density range. The DGNs annealed at low temperatures exhibit larger SSA than high-temperature DGNs because of the abundant free edges.


1978 ◽  
Vol 56 (10) ◽  
pp. 1390-1394
Author(s):  
K. P. Srivastava

An extensive numerical study on specific heat at constant volume (Cv) for ordered and isotopically disordered lattices has been made. Cv at various temperatures for ordered and disordered linear and two-dimensional lattices have been compared and no appreciable difference in Cv between these two structures has been observed. Effect of concentration of light atoms on Cv for three-dimensional isotopically disordered lattices has also been shown.In spite of taking next-nearest-neighbour interaction into account, no substantial change in Cv between the ordered and isotopically disordered linear lattices has been found. It is shown that the low lying modes contribute substantially at low temperatures.


2018 ◽  
Vol 51 (2) ◽  
pp. 541-548 ◽  
Author(s):  
Michael Solar ◽  
Nils Trapp

A procedure for preparing and mounting crystals under inert conditions is demonstrated, using a specialized apparatus (μCHILL) to provide a cold gas stream fed from a liquid nitrogen (LN2) reservoir or an open bath heat exchanger. A second, dry gas stream at room temperature enwraps the cold gas, protecting the sample preparation zone from ambient moisture. The technique is extremely flexible, requiring only a single operator, little practice and almost no preparation time. The device enables operation in a wide temperature range (at least 213 K to room temperature), providing temperature control and very stable conditions with no icing for extended time periods. The flexible, modular and low-cost design is based on three-dimensional-printed parts and readily available standard components, potentially making the device available to a wide range of users and applications not limited to single-crystal studies.


2018 ◽  
Vol 6 (24) ◽  
pp. 11405-11415 ◽  
Author(s):  
L. Q. Lu ◽  
N. Schriever ◽  
J. Th. M. De Hosson ◽  
Y. T. Pei

In this work we developed a solid-state-growth approach for the synthesis of 3D interconnected bicontinuous nanoporous graphene (NPG) with the aid of nanoporous Ni templates at low temperatures (below 800 °C).


Author(s):  
Jean-Philippe Mathieu ◽  
Olivier Diard ◽  
Karim Inal ◽  
Sophie Berveiller

The present study describes a multiscale representation of mechanisms involved in brittle fracture of a french Reactor Pressure Vessel (RPV) steel (16MND5 equ. ASTM A508 Cl.3) at low temperatures. Attention will be focused on the representation of stress heterogeneities inside the ferritic matrix during plastic straining, which is considered as critical for further micromechanical approach of brittle fracture. This representation is tuned on experimental results [1]. Modeling involves micromechanical a description of plastic glide, a mean field (MF) model and a realistic three-dimensional aggregates Finite Element (FE) simulation, all put together inside a multiscale approach. Calibration is done on macroscopic stress-strain curves at different low temperatures, and modeling reproduces experimental stress heterogeneities. This modeling allows to apply a local micromechanical fracture criterion of crystallographic cleavage for triaxial loadings on the Representative Volume Element (RVE). Deterministic computations of time to fracture for different carbide sizes random selection provide a probability of fracture for an Elementary Volume (EV) consistant with the local approach. Results are in good agreement with hypothesis made by local approach to fracture. Hence, the main difference is that no phenomenological dependence on loading or microstructure is supposed for probability of fracture on the EV: this dependence is naturally introduced by the micromechanical description.


2014 ◽  
Vol 1079-1080 ◽  
pp. 553-557
Author(s):  
Tao Wan

When the large oil-immersed transformer start with heavy load in cold regions, due to the high viscosity of the oil at low temperatures, the flow of the oil is extremely slow in the early start of heavy load, resulting in a negative heat radiation. At the same time, the winding and the core are rapidly increasing heat in the early start of heavy load. Rapid increase in heat and the lack of heat dissipation caused a series of problems. In this paper, we study the process of heating and cooling when the large oil-immersed transformer start with heavy load in cold region and takes a transformer of 31.5MVA as example to build a three-dimensional model ,the model is based on the actual size of the transformer. We use the finite volume method to calculate three-dimensional temperature field distribution changing with time when the oil-immersed transformer startup with heavy load in - 35 °C,-30 °C and-25 °C three cases. The results show that the viscosity coefficient of transformer oil is very high at low temperatures. In the early start of the transformer, because of the poor fluidity of the oil, the heat cannot be dissipated in time and the transformer local overheating near the winding. Then we analyzes the damage of local overheating for a short period of time in the transformer, especially the damage of the oiled paper's insulation At last ,we analysis of the causes of transformer internal local overheating and give some measures to avoid local overheating when oil-immersed transformer start with heavy load in cold regions.KEYWORDS: oil-immersed transformer, cold regions, start with heavy load, FVM, three-dimensional temperature distribution


2010 ◽  
Vol 10 ◽  
pp. 49-61 ◽  
Author(s):  
Ulrich Wulf ◽  
Hans Richter

Starting from a three-dimensional transport model in the Landauer-Buttiker formalism we derive a scale-invariant expression for the drain current in a nano-transistor. Apart from dimensionless external parameters representing temperature, gate-, and drain voltage the normalized drain current depends on two dimensionless transistor parameters which are the characteristic length l and -width w of the electron channel. The latter quantities are the physical length and -width of the channel in units of the scaling length = ~(2mF )1=2. Here F is the Fermi energy in the source contact and m is the eective mass in the electron channel. In the limit of wide transistors and low temperatures we evaluate the scale-invariant IDVD characteristics as a function of the characteristic length. In the strong barrier regime, i. e. for l & 20 long-channel behavior is found. At weaker barriers source-drain tunneling leads to increasingly signicant deviations from the long-channel behavior. We compare with experimental results.


2014 ◽  
Vol 69 (9-10) ◽  
pp. 1003-1009 ◽  
Author(s):  
Walter Schnelle ◽  
Reinhard K. Kremer ◽  
Rolf-Dieter Hoffmann ◽  
Ute Ch. Rodewald ◽  
Rainer Pöttgen

Abstract Polycrystalline CeNiIn4 was prepared by arc-melting of the elements and subsequent annealing at 970 K in vacuum. EuNiIn4 and EuCuIn4 were synthesized from the elements by reactions in sealed tantalum tubes. These indium-rich compounds crystallize with the YNiAl4-type structure which was refined for EuCuIn4 from single-crystal X-ray diffraction data: Cmcm, a=450:04(9), b=1698:7(4), c = 740:2(2) pm, wR2 = 0:0606, 495 F2 values, 24 variables. The EuCuIn4 structure is built up from a complex three-dimensional [CuIn4] polyanion (265 - 279 pm Cu-In and 296 - 331 pm In- In) in which the europium atoms occupy distorted hexagonal channels. The Eu-Eu distances within these channels (450 pm) are significantly shorter than the distances between Eu atoms in neighboring channels (552 pm). The magnetic properties and the specific heats of the europium compounds have been investigated. Both europium compounds show the magnetism of divalent Eu ions and antiferromagnetic ordering at low temperatures. EuCuIn4 is magnetically ordered via a surprisingly complex sequence of three transitions


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