Mechanisms of the Planar Growth of Lithium Metal Enabled by the 2D Lattice Confinement from a Ti 3 C 2 T x MXene Intermediate Layer

2021 ◽  
pp. 2010987
Author(s):  
Di Yang ◽  
Chunyu Zhao ◽  
Ruqian Lian ◽  
Lin Yang ◽  
Yizhan Wang ◽  
...  
Keyword(s):  
Intermediate Layer ◽  
Lithium Metal ◽  
Planar Growth

Formation of self-limited, stable and conductive interfaces between garnet electrolytes and lithium anodes for reversible lithium cycling in solid-state batteries

2018 ◽  
Vol 6 (24) ◽  
pp. 11463-11470 ◽  
Author(s):  
Minghui He ◽  
Zhonghui Cui ◽  
Cheng Chen ◽  
Yiqiu Li ◽  
Xiangxin Guo
Keyword(s):  
Thin Film ◽  
Solid State ◽  
Solid Electrolyte ◽  
Intermediate Layer ◽  
Lithium Metal ◽  
Lithium Transport ◽  
Solid State Batteries

Modification of the garnet-type solid electrolyte with a 10 nm Sn thin-film improves the contact and wetting performance between the garnet and the lithium metal and, thus enables fast and reversible lithium transport across their interface by forming a self-limited, conductive Li–Sn intermediate layer.

Microstructure of YBa2Cu3O7-x thin films deposited by dc sputtering

1989 ◽  
Vol 47 ◽  
pp. 172-173
Author(s):  
O. Eibl ◽  
G. Gieres ◽  
H. Behner
Keyword(s):  
Thin Films ◽  
Cross Sections ◽  
Intermediate Layer ◽  
Amorphous State ◽  
Critical Currents ◽  
Dc Sputtering ◽  
State Process ◽  
Diffraction Patterns ◽  
Film Substrate ◽  
Substrate Temperatures

The microstructure of high-Tc YBa2Cu3O7-X thin films deposited by DC-sputtering on SrTiO3 substrates was analysed by TEM. Films were either (i) deposited in the amorphous state at substrate temperatures < 450°C and crystallised by a heat treatment at 900°C (process 1) or (ii) deposited at around 740°C in the crystalline state (process 2). Cross sections were prepared for TEM analyses and are especially useful for studying film substrate interdiffusion (fig.1). Films deposited in process 1 were polycristalline and the grain size was approximately 200 nm. Films were porous and the size of voids was approximately 100 nm. Between the SrTiO3 substrate and the YBa2Cu3Ox film a densly grown crystalline intermediate layer approximately 150 nm thick covered the SrTiO3 substrate. EDX microanalyses showed that the layer consisted of Sr, Ba and Ti, however, did not contain Y and Cu. Crystallites of the layer were carefully tilted in the microscope and diffraction patterns were obtained in five different poles for every crystallite. These patterns were consistent with the phase (Ba1-XSrx)2TiO4. The intermediate layer was most likely formed during the annealing at 900°C. Its formation can be understood as a diffusion of Ba from the amorphously deposited film into the substrate and diffusion of Sr from the substrate into the film. Between the intermediate layer and the surface of the film the film consisted of YBa2Cu3O7-x grains. Films prepared in process 1 had Tc(R=0) close to 90 K, however, critical currents were as low as jc = 104A/cm2 at 77 K.

Tunnel Magnetoresistance Effect for Double Tunnel Junctions with Al Intermediate Layer.

2001 ◽  
Vol 25 (4−2) ◽  
pp. 767-770 ◽  
Author(s):  
T. Daibou ◽  
M. Oogane ◽  
Y. Ando ◽  
C. Kim ◽  
O. Song ◽  
...  
Keyword(s):  
Intermediate Layer ◽  
Tunnel Junctions ◽  
Magnetoresistance Effect ◽  
Tunnel Magnetoresistance

Enhanced Ion Transport in an Ether Aided Super Concentrated Ionic Liquid Electrolyte for Long-Life Practical Lithium Metal Battery Applications

2020 ◽  
Author(s):  
Urbi Pal ◽  
Fangfang Chen ◽  
Derick Gyabang ◽  
Thushan Pathirana ◽  
Binayak Roy ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ion Transport ◽  
Current Density ◽  
Coulombic Efficiency ◽  
High Energy ◽  
Liquid Electrolyte ◽  
High Mass ◽  
Lithium Metal ◽  
Ionic Liquid Electrolyte ◽  
Lithium Metal Battery

We explore a novel ether aided superconcentrated ionic liquid electrolyte; a combination of ionic liquid, <i>N</i>-propyl-<i>N</i>-methylpyrrolidinium bis(fluorosulfonyl)imide (C<sub>3</sub>mpyrFSI) and ether solvent, <i>1,2</i> dimethoxy ethane (DME) with 3.2 mol/kg LiFSI salt, which offers an alternative ion-transport mechanism and improves the overall fluidity of the electrolyte. The molecular dynamics (MD) study reveals that the coordination environment of lithium in the ether aided ionic liquid system offers a coexistence of both the ether DME and FSI anion simultaneously and the absence of ‘free’, uncoordinated DME solvent. These structures lead to very fast kinetics and improved current density for lithium deposition-dissolution processes. Hence the electrolyte is used in a lithium metal battery against a high mass loading (~12 mg/cm<sup>2</sup>) LFP cathode which was cycled at a relatively high current rate of 1mA/cm<sup>2</sup> for 350 cycles without capacity fading and offered an overall coulombic efficiency of >99.8 %. Additionally, the rate performance demonstrated that this electrolyte is capable of passing current density as high as 7mA/cm<sup>2</sup> without any electrolytic decomposition and offers a superior capacity retention. We have also demonstrated an ‘anode free’ LFP-Cu cell which was cycled over 50 cycles and achieved an average coulombic efficiency of 98.74%. The coordination chemistry and (electro)chemical understanding as well as the excellent cycling stability collectively leads toward a breakthrough in realizing the practical applicability of this ether aided ionic liquid electrolytes in lithium metal battery applications, while delivering high energy density in a prototype cell.

MICROSTRUCTURAL EVOLUTION OF DIRECTIONALLY SOLIDIFIED Ni--BASED SUPERALLOY DZ125 UNDER PLANAR GROWTH

2010 ◽  
Vol 46 (9) ◽  
pp. 1075-1080 ◽  
Author(s):  
Zhixian MIN ◽  
Jun SHEN ◽  
Lingshui WANG ◽  
Zhourong FENG ◽  
Lin LIU ◽  
...  
Keyword(s):  
Microstructural Evolution ◽  
Directionally Solidified ◽  
Planar Growth
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