Inorganic Solid Electrolytes for All‐Solid‐State Sodium Batteries: Fundamentals and Strategies for Battery Optimization

2020 ◽  
pp. 2008165
Author(s):  
Jian‐Fang Wu ◽  
Rui Zhang ◽  
Qing‐Feng Fu ◽  
Jie‐Song Zhang ◽  
Xiao‐Yan Zhou ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
Sodium Batteries ◽  
Battery Optimization

Grain-boundary-resistance-less Na3SbS4-Se solid electrolytes for all-solid-state sodium batteries

Nano Energy ◽  
2019 ◽  
Vol 66 ◽  
pp. 104109 ◽  
Author(s):  
Hongli Wan ◽  
Jean Pierre Mwizerwa ◽  
Fudong Han ◽  
Wei Weng ◽  
Jing Yang ◽  
...  
Keyword(s):  
Solid State ◽  
Grain Boundary ◽  
Solid Electrolytes ◽  
Boundary Resistance ◽  
Sodium Batteries

Liquid-Phase Synthesis of Nanosized Na11Sn2PS12 Solid Electrolytes for Room Temperature All-Solid-State Sodium Batteries

2021 ◽  
Vol 4 (2) ◽  
pp. 1467-1473
Author(s):  
Wei Weng ◽  
Hongli Wan ◽  
Gaozhan Liu ◽  
Liping Wu ◽  
Jinghua Wu ◽  
...  
Keyword(s):  
Solid State ◽  
Liquid Phase ◽  
Solid Electrolytes ◽  
Room Temperature ◽  
Phase Synthesis ◽  
Sodium Batteries

Enhanced ionic conductivity of Na3Zr2Si2PO12 solid electrolyte with Na2SiO3 by liquid phase sintering for Na+ solid-state batteries

Nanoscale ◽  
2021 ◽  
Author(s):  
Han Wang ◽  
Genfu Zhao ◽  
Shimin Wang ◽  
Dangling Liu ◽  
Zhi-Yuan Mei ◽  
...  
Keyword(s):  
Solid State ◽  
Liquid Phase ◽  
Ionic Conductivity ◽  
Solid Electrolyte ◽  
Solid Electrolytes ◽  
Liquid Phase Sintering ◽  
High Ionic Conductivity ◽  
Nasicon Type ◽  
Sodium Batteries ◽  
Solid State Batteries

NASICON-type Na3Zr2Si2PO12 (NZSP) is supposed to be one of the most potential solid electrolytes with the characteristics of high ionic conductivity and safety for solid-state sodium batteries. Many methods have...

Theoretical formulation of Na3AO4X (A = S/Se, X = F/Cl) as high-performance solid electrolytes for all-solid-state sodium batteries

2019 ◽  
Vol 7 (38) ◽  
pp. 21985-21996 ◽  
Author(s):  
Yuran Yu ◽  
Zhuo Wang ◽  
Guosheng Shao
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
High Performance ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Theoretical Formulation ◽  
Sodium Batteries ◽  
Solid State Electrolytes

It is very important and yet extremely challenging to develop solid state electrolytes to make sodium ion batteries (SIBs) safer, since the much larger size of Na+ than that of Li+ makes transport of Na+ rather difficult.

scholarly journals Solid electrolytes and interfaces in all-solid-state sodium batteries: Progress and perspective

Nano Energy ◽  
2018 ◽  
Vol 52 ◽  
pp. 279-291 ◽  
Author(s):  
Wenru Hou ◽  
Xianwei Guo ◽  
Xuyang Shen ◽  
Khali Amine ◽  
Haijun Yu ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
Sodium Batteries

Polyether/Na3Zr2Si2PO12 Composite Solid Electrolytes for All-Solid-State Sodium Batteries

2020 ◽  
Vol 124 (40) ◽  
pp. 21948-21956
Author(s):  
Koji Hiraoka ◽  
Masaki Kato ◽  
Takeshi Kobayashi ◽  
Shiro Seki
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
Sodium Batteries ◽  
Composite Solid Electrolytes ◽  
Composite Solid

scholarly journals Phase Formation through Synthetic Control: Polymorphism in the Sodium-Ion Solid Electrolyte Na4P2S6

2021 ◽  
Author(s):  
Tanja Scholz ◽  
Christian Schneider ◽  
Roland Eger ◽  
Viola Duppel ◽  
Igor Moudrakovski ◽  
...  
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Solid Electrolyte ◽  
Phase Formation ◽  
Solid Electrolytes ◽  
Fast Track ◽  
Sodium Ion ◽  
Synthetic Control ◽  
Storage Solutions ◽  
Sodium Batteries

The development of all-solid-state sodium batteries for scalable energy storage solutions requires fast sodium conducting solid electrolytes. To fast-track their discovery, candidate materials need to be identified that are synthesized...

Development of Solid Electrolytes for All-Solid-State Batteries

2019 ◽  
Vol 92 (11) ◽  
pp. 430-434
Author(s):  
Akitoshi HAYASHI ◽  
Atsushi SAKUDA ◽  
Masahiro TATSUMISAGO
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
Solid State Batteries ◽  
All Solid State Batteries

Operando Visualization of Morphological Dynamics in All-Solid-State Batteries

2019 ◽  
Author(s):  
Xiaohan Wu ◽  
Juliette Billaud ◽  
Iwan Jerjen ◽  
Federica Marone ◽  
Yuya Ishihara ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
Rational Design ◽  
Morphological Evolution ◽  
Active Material ◽  
Composite Layer ◽  
Transference Number ◽  
Thermal Stabilities ◽  
Solid State Batteries ◽  
All Solid State Batteries

<div> <div> <div> <p>All-solid-state batteries are considered as attractive options for next-generation energy storage owing to the favourable properties (unit transference number and thermal stabilities) of solid electrolytes. However, there are also serious concerns about mechanical deformation of solid electrolytes leading to the degradation of the battery performance. Therefore, understanding the mechanism underlying the electro-mechanical properties in SSBs are essentially important. Here, we show three-dimensional and time-resolved measurements of an all-solid-state cell using synchrotron radiation x-ray tomographic microscopy. We could clearly observe the gradient of the electrochemical reaction and the morphological evolution in the composite layer. Volume expansion/compression of the active material (Sn) was strongly oriented along the thickness of the electrode. While this results in significant deformation (cracking) in the solid electrolyte region, we also find organized cracking patterns depending on the particle size and their arrangements. This study based on operando visualization therefore opens the door towards rational design of particles and electrode morphology for all-solid-state batteries. </p> </div> </div> </div>

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