scholarly journals Phase Formation through Synthetic Control: Polymorphism in the Sodium-Ion Solid Electrolyte Na4P2S6

2021 ◽  
Author(s):  
Tanja Scholz ◽  
Christian Schneider ◽  
Roland Eger ◽  
Viola Duppel ◽  
Igor Moudrakovski ◽  
...  
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Solid Electrolyte ◽  
Phase Formation ◽  
Solid Electrolytes ◽  
Fast Track ◽  
Sodium Ion ◽  
Synthetic Control ◽  
Storage Solutions ◽  
Sodium Batteries

The development of all-solid-state sodium batteries for scalable energy storage solutions requires fast sodium conducting solid electrolytes. To fast-track their discovery, candidate materials need to be identified that are synthesized...

Enhanced ionic conductivity of Na3Zr2Si2PO12 solid electrolyte with Na2SiO3 by liquid phase sintering for Na+ solid-state batteries

Nanoscale ◽  
2021 ◽  
Author(s):  
Han Wang ◽  
Genfu Zhao ◽  
Shimin Wang ◽  
Dangling Liu ◽  
Zhi-Yuan Mei ◽  
...  
Keyword(s):  
Solid State ◽  
Liquid Phase ◽  
Ionic Conductivity ◽  
Solid Electrolyte ◽  
Solid Electrolytes ◽  
Liquid Phase Sintering ◽  
High Ionic Conductivity ◽  
Nasicon Type ◽  
Sodium Batteries ◽  
Solid State Batteries

NASICON-type Na3Zr2Si2PO12 (NZSP) is supposed to be one of the most potential solid electrolytes with the characteristics of high ionic conductivity and safety for solid-state sodium batteries. Many methods have...

Theoretical formulation of Na3AO4X (A = S/Se, X = F/Cl) as high-performance solid electrolytes for all-solid-state sodium batteries

2019 ◽  
Vol 7 (38) ◽  
pp. 21985-21996 ◽  
Author(s):  
Yuran Yu ◽  
Zhuo Wang ◽  
Guosheng Shao
Keyword(s):  
Solid State ◽  
Solid Electrolytes ◽  
High Performance ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Theoretical Formulation ◽  
Sodium Batteries ◽  
Solid State Electrolytes

It is very important and yet extremely challenging to develop solid state electrolytes to make sodium ion batteries (SIBs) safer, since the much larger size of Na+ than that of Li+ makes transport of Na+ rather difficult.

NASICON-structured Na ion conductor for next generation energy storage

2021 ◽  
pp. 2130005
Author(s):  
Qing Huang ◽  
Gongxuan Chen ◽  
Ping Zheng ◽  
Wei Li ◽  
Tian Wu
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Ionic Conductivity ◽  
Solid Electrolytes ◽  
Electrical Energy ◽  
Next Generation ◽  
Ion Conductor ◽  
Electrical Energy Storage ◽  
Composition Properties ◽  
Stable Structures

The demand for electrical energy storage (EES) is ever increasing in order to develop better batteries. NASICON-structured Na ion conductor represents a class of solid electrolytes, which is of great interest due to its superior ionic conductivity and stable structures. They are widely employed in all-solid-state ion batteries, all-solid-state air batteries, and hybrid batteries. In this review, their structure, composition, properties, and applications for next generation energy storage are reviewed.

scholarly journals Lithium-ion conductivity in Li6Y(BO3)3: a thermally and electrochemically robust solid electrolyte

2016 ◽  
Vol 4 (18) ◽  
pp. 6972-6979 ◽  
Author(s):  
Beatriz Lopez-Bermudez ◽  
Wolfgang G. Zeier ◽  
Shiliang Zhou ◽  
Anna J. Lehner ◽  
Jerry Hu ◽  
...  
Keyword(s):  
Energy Storage ◽  
Solid Electrolyte ◽  
Solid Electrolytes ◽  
Lithium Ion ◽  
Ion Conductivity ◽  
Ion Diffusion ◽  
New Energy ◽  
Li Ion ◽  
Lithium Ion Conductivity ◽  
Storage Technologies

The development of new frameworks for solid electrolytes exhibiting fast Li-ion diffusion is critical for enabling new energy storage technologies.

A Dramatic Reduction in the Sintering Temperature of the Refractory Sodium β’’-Alumina Solid Electrolyte via Cold Sintering

2021 ◽  
Author(s):  
Zane A. Grady ◽  
Arnaud Ndayishimiye ◽  
Clive A Randall
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Sintering Temperature ◽  
Sodium Ion ◽  
Dramatic Reduction ◽  
Sintering Process ◽  
Sodium Beta Alumina ◽  
Beta Alumina

The cold sintering process is successfully applied to one of the most refractory solid-state sodium-ion electrolytes, namely sodium beta alumina (SBA). By using a hydroxide-based transient solvent, SBA is densified...

Grain-boundary-resistance-less Na3SbS4-Se solid electrolytes for all-solid-state sodium batteries

Nano Energy ◽  
2019 ◽  
Vol 66 ◽  
pp. 104109 ◽  
Author(s):  
Hongli Wan ◽  
Jean Pierre Mwizerwa ◽  
Fudong Han ◽  
Wei Weng ◽  
Jing Yang ◽  
...  
Keyword(s):  
Solid State ◽  
Grain Boundary ◽  
Solid Electrolytes ◽  
Boundary Resistance ◽  
Sodium Batteries

Electrochemical Stability and Performance of Li2OHCl Substituted by F or Br as Solid-State Electrolyte

2020 ◽  
Vol 18 (2) ◽  
Author(s):  
Yong-Seok Lee ◽  
Su-Yeon Jung ◽  
Kwang-Sun Ryu
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Solid Electrolytes ◽  
Interstitial Site ◽  
Electrochemical Stability ◽  
The Other ◽  
Chemical Bonds ◽  
Solid State Electrolyte ◽  
And Performance

Abstract Li2(OH)0.9F0.1Cl, Li2(OH)0.9Br0.1Cl, and Li2OHCl0.8Br0.2 solid electrolytes were synthesized and compared with Li2OHCl to analyze the exact improvement mechanism for Li+ conductivity and electrochemical stability of Li2OHX-type solid electrolyte. The substituted materials exhibit improved electrochemical stability and Li+ conductivity Li2OHCl. Among these materials, Li(OH)0.9F0.1Cl has improved Li+ conductivity due to a reduction of the OH– concentration and the conductivity of Li2OHCl0.8Br0.2 was also increased compared with Li2OHCl due to the large interstitial site. In the case of Li2(OH)0.9Br0.1Cl, it had the highest Li+ conductivity and good Li+ migration by both effects because of a larger interstitial site and low OH− concentration. Furthermore, the electrochemical stability of four materials was compared due to the different structural stabilities and strengths of binary chemical bonds such as Li–X, H–X, and O–X. Comparing the Li+ conductivity of Li2(OH)0.9F0.1Cl and Li2OHCl0.8Br0.2, the Li+ conductivity is influenced by the OH− concentration unlike the other mechanisms.

Na10SnSb2S12: A nanosized air-stable solid electrolyte for all-solid-state sodium batteries

2020 ◽  
pp. 127692
Author(s):  
Gaozhan Liu ◽  
Xiaorui Sun ◽  
Xiqian Yu ◽  
Wei Weng ◽  
Jing Yang ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Sodium Batteries
Sign in / Sign up

Export Citation Format

Share Document