scholarly journals Achieving zT > 1 in Inexpensive Zintl Phase Ca9 Zn4+ x Sb9 by Phase Boundary Mapping

2017 ◽  
Vol 27 (20) ◽  
pp. 1606361 ◽  
Author(s):  
Saneyuki Ohno ◽  
Umut Aydemir ◽  
Maximilian Amsler ◽  
Jan-Hendrik Pöhls ◽  
Sevan Chanakian ◽  
...  
Author(s):  
Rachel Orenstein ◽  
James P. Male ◽  
Michael Toriyama ◽  
Shashwat Anand ◽  
G. Jeffrey Snyder

A new understanding of the MgSi–MgSn miscibility gap is reached through phase boundary mapping the Mg–Si–Sn ternary phase diagram.


2019 ◽  
Vol 7 (2) ◽  
pp. 621-631 ◽  
Author(s):  
Brenden R. Ortiz ◽  
Kiarash Gordiz ◽  
Lídia C. Gomes ◽  
Tara Braden ◽  
Jesse M. Adamczyk ◽  
...  

Phase boundary mapping in Cu2HgGeTe4allows discovery of Hg2GeTe4and further enables carrier density control over 4 orders of magnitude.


Research ◽  
2020 ◽  
Vol 2020 ◽  
pp. 1-9 ◽  
Author(s):  
Xiaofang Li ◽  
Pengbo Yang ◽  
Yumei Wang ◽  
Zongwei Zhang ◽  
Dandan Qin ◽  
...  

The solubility range of interstitial Ni in the ZrNi1+xSn half-Heusler phase is a controversial issue, but it has an impact on the thermoelectric properties. In this study, two isothermal section phase diagrams of the Zr-Ni-Sn ternary system at 973 K and 1173 K were experimentally constructed based on the binary phase diagrams of Zr-Ni, Zr-Sn, and Ni-Sn. The thermodynamic equilibrium phases were obtained after a long time of heating treatment on the raw alloys prepared by levitation melting. Solubilities of x<0.07 at 973 K and x<0.13 at 1173 K were clearly indicated. An intermediate-Heusler phase with a partly filled Ni void was observed, which is believed to be beneficial to the lowered lattice thermal conductivity. The highest ZT value~0.71 at 973 K was obtained for ZrNi1.11Sn1.04. The phase boundary mapping provides an important instruction for the further optimization of ZrNiSn-based materials and other systems.


2018 ◽  
Vol 6 (47) ◽  
pp. 24175-24185 ◽  
Author(s):  
Caitlin M. Crawford ◽  
Brenden R. Ortiz ◽  
Prashun Gorai ◽  
Vladan Stevanovic ◽  
Eric S. Toberer

Experimental and computational investigation of the phase stability and thermoelectric properties of the Co4Sn6Te6 skutterudite.


2020 ◽  
Vol 142 (36) ◽  
pp. 15464-15475 ◽  
Author(s):  
Priyanka Jood ◽  
James P. Male ◽  
Shashwat Anand ◽  
Yoshitaka Matsushita ◽  
Yoshiki Takagiwa ◽  
...  

2021 ◽  
pp. 2100181
Author(s):  
Maxwell Wood ◽  
Michael Y. Toriyama ◽  
Shristi Dugar ◽  
James Male ◽  
Shashwat Anand ◽  
...  

Joule ◽  
2018 ◽  
Vol 2 (1) ◽  
pp. 141-154 ◽  
Author(s):  
Saneyuki Ohno ◽  
Kazuki Imasato ◽  
Shashwat Anand ◽  
Hiromasa Tamaki ◽  
Stephen Dongmin Kang ◽  
...  

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