NMR of Nanosized Magnetic Systems, Ultrathin Films, and Granular Systems

2003 ◽  
pp. 297-327
Author(s):  
Pierre Panissod
Author(s):  
Yoshichika Bando ◽  
Takahito Terashima ◽  
Kenji Iijima ◽  
Kazunuki Yamamoto ◽  
Kazuto Hirata ◽  
...  

The high quality thin films of high-Tc superconducting oxide are necessary for elucidating the superconducting mechanism and for device application. The recent trend in the preparation of high-Tc films has been toward “in-situ” growth of the superconducting phase at relatively low temperatures. The purpose of “in-situ” growth is to attain surface smoothness suitable for fabricating film devices but also to obtain high quality film. We present the investigation on the initial growth manner of YBCO by in-situ reflective high energy electron diffraction (RHEED) technique and on the structural and superconducting properties of the resulting ultrathin films below 100Å. The epitaxial films have been grown on (100) plane of MgO and SrTiO, heated below 650°C by activated reactive evaporation. The in-situ RHEED observation and the intensity measurement was carried out during deposition of YBCO on the substrate at 650°C. The deposition rate was 0.8Å/s. Fig. 1 shows the RHEED patterns at every stage of deposition of YBCO on MgO(100). All the patterns exhibit the sharp streaks, indicating that the film surface is atomically smooth and the growth manner is layer-by-layer.


1988 ◽  
Vol 49 (7) ◽  
pp. 1097-1101 ◽  
Author(s):  
N. Schopohl ◽  
T.J. Sluckin
Keyword(s):  

1992 ◽  
Vol 162 (7) ◽  
pp. 81 ◽  
Author(s):  
K.N. Alekseev ◽  
G.P. Berman ◽  
V.I. Tsifrinovich ◽  
A.M. Frishman

2003 ◽  
Author(s):  
Ronald N. Kostoff ◽  
J. A. del Rio ◽  
Esther O. Garcia ◽  
Ana M. Ramirez ◽  
James A. Humenik

1996 ◽  
Vol 61 (4) ◽  
pp. 536-563
Author(s):  
Vladimír Kudrna ◽  
Pavel Hasal

To the description of changes of solid particle size in population, the application was proposed of stochastic differential equations and diffusion equations adequate to them making it possible to express the development of these populations in time. Particular relations were derived for some particle size distributions in flow and batch equipments. It was shown that it is expedient to complement the population balances often used for the description of granular systems by a "diffusion" term making it possible to express the effects of random influences in the growth process and/or particle diminution.


Author(s):  
Jean-Pierre Launay ◽  
Michel Verdaguer

After preliminaries about electron properties, and definitions in magnetism, one treats the magnetism of mononuclear complexes, in particular spin cross-over, showing the role of cooperativity and the sensitivity to external perturbations. Orbital interactions and exchange interaction are explained in binuclear model systems, using orbital overlap and orthogonality concepts to explain antiferromagnetic or ferromagnetic coupling. The phenomenologically useful Spin Hamiltonian is defined. The concepts are then applied to extended molecular magnetic systems, leading to molecular magnetic materials of various dimensionalities exhibiting bulk ferro- or ferrimagnetism. An illustration is provided by Prussian Blue analogues. Magnetic anisotropy is introduced. It is shown that in some cases, a slow relaxation of magnetization arises and gives rise to appealing single-ion magnets, single-molecule magnets or single-chain magnets, a route to store information at the molecular level.


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