scholarly journals Characterization of LIBS emission lines for the identification of chlorides, carbonates, and sulfates in salt/basalt mixtures for the application to MSL ChemCam data

2017 ◽  
Vol 122 (4) ◽  
pp. 744-770 ◽  
Author(s):  
D. E. Anderson ◽  
B. L. Ehlmann ◽  
O. Forni ◽  
S. M. Clegg ◽  
A. Cousin ◽  
...  
Keyword(s):  
2018 ◽  
Vol 73 (2) ◽  
pp. 203-213 ◽  
Author(s):  
Jhonatha R. dos Santos ◽  
Jonas Jakutis Neto ◽  
N. Rodrigues ◽  
M.G. Destro ◽  
José W. Neri ◽  
...  

In this work, we suggest a methodology to determine the impact parameter for neutral dysprosium emission lines from the characterization of the plasma generated by laser ablation in a sealed chamber filled with argon. The procedure is a combination of known consistent spectroscopic methods for plasma temperature determination, electron density, and species concentration. With an electron density of 3.1 × 1018 cm–3 and temperature close to 104 K, we estimated the impact electron parameter for nine spectral lines of the neutral dysprosium atom. The gaps in the impact parameter data in the literature, mainly for heavy elements, stress the importance of the proposed method.


Crystals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 148 ◽  
Author(s):  
P. Popielarski ◽  
J. Zeler ◽  
P. Bolek ◽  
T. Zorenko ◽  
K. Paprocki ◽  
...  

This work is dedicated to the preparation and characterization of the radio-, thermo-, and photoluminescent properties of Lu2O3:Eu and Lu2O3:Tb nanopowder (NPs) scintillators, prepared by means of hydrothermal processing, and their film analogues made of these NPs by the spin coating method. The luminescent properties of NPs and films were characterized by cathodoluminescence (CL), photoluminescence (PL), X-ray excited radioluminescence (RL), and thermoluminescence (TL) at low and high temperatures. In Lu2O3:Eu NPs and films, mostly the luminescence of Eu3+ ions occupying the C2 site of the host, with the most intensive peaks at 611.6 nm and a decay time of 1.5 ms, was observed. On the contrary, two types of Tb3+ centers in the C2 and C3i sites with the main emission lines at 542.4 and 544.0 nm and the corresponding 4f→5d excitation bands at 270 and 305 nm and decay times of t1/e = 2.17 and 3.96 ms were observed in the case of Lu2O3:Tb NPs and films. Indications were noted that Tb3+ in the C3i symmetry position was most active in the CL spectra of Lu2O3:Tb NPs and a respective film. Thermoluminescent peaks at 110 °C and 170 °C for Lu2O3:Eu NPs and at 75 °C and 120 °C in Lu2O3:Tb NPs were observed corresponding to the hole and electron traps, respectively. Significantly different onsets of temperature quenching of Eu3+ and Tb3+ luminescence in Lu2O3:Eu and Lu2O3:Tb NPs were found at ~90 °C and ~320 °C, respectively.


2018 ◽  
Vol 618 ◽  
pp. A128 ◽  
Author(s):  
V. Casasola ◽  
L. Magrini ◽  
F. Combes ◽  
E. Sani ◽  
J. Fritz ◽  
...  

Aims. The aim of this paper is the spectroscopic study of 13 galaxies belonging to the field of the protocluster associated with the radio galaxy 7C 1756+6520 at z = 1.4156. In particular, we focus on the characterization of the nuclear activity. Methods. This analysis has been performed on rest-frame optical spectra taken with the Large Binocular Telescope, using the spectrograph LUCI, which is operative in the near-infrared domain. The adopted spectral coverage allowed us to observe emission lines such as Hα, Hβ, [O III]λ 5007 Å, and [N II]λ 6583 Å at the redshift of the central radio galaxy. We observed the central part of the protocluster, which is suitable to include the radio galaxy, several spectroscopically confirmed active galactic nuclei (AGN) belonging to the protocluster, and other objects that might be members of the protocluster. Results. For four previously identified protocluster members, we derived the redshift by detecting emission lines that have never detected before for these galaxies. We identified a new protocluster member and eight new possible protocluster members. The stacked spectrum of the galaxies in which we detected the [O III]λ 5007 Å emission line revealed the second line of the [O III] doublet at 4959 Å and the Hβ line, which confirms that they belong to the protocluster. By collecting all members identified so far in this work and other members from the literature, we defined 31 galaxies, including the central radio galaxy, around the redshift 1.4152 ± 0.056. This corresponds to peculiar velocities ≲5000 km s−1 with respect to the radio galaxy. The position versus velocity phase-space diagram suggests that three AGN of the protocluster and the central radio galaxy might be a virialized population that has been coexisting for a long time in the densest core region of this forming structure. This protocluster is characterized by a high fraction of AGN (~23%). For one of them, AGN1317, we produced two so-called Baldwin, Phillips & Terlevich (BPT) diagrams. The high fraction of AGN and their distribution within the protocluster seem to be consistent with predictions of some theoretical models on AGN growth and feedback. These models are based on galaxy interactions and ram pressure as triggers of AGN activity. Conclusions. The high fraction of AGN belonging to the protocluster suggests that they were likely triggered at the same time, maybe by the ongoing formation of the protocluster. Observations of AGN in this protocluster and in other distant clusters will help clarifying whether the resulting high fraction of AGN is unusual or typical for such structures at high redshift. Our next step will be analyses of previously acquired high-resolution radio data of the central radio galaxy to derive information on the nature of the radio galaxy and connect it with its cosmic evolution.


1985 ◽  
Vol 57 (14) ◽  
pp. 2901-2907 ◽  
Author(s):  
Kazuaki. Wagatsuma ◽  
Kichinosuke. Hirokawa

2016 ◽  
Vol 49 (5) ◽  
pp. 1443-1453 ◽  
Author(s):  
Marcelo Goncalves Honnicke ◽  
Leonardo M. Bianco ◽  
Sergio A. Ceppi ◽  
Cesar Cusatis ◽  
XianRong Huang ◽  
...  

The construction and characterization of a focusing X-ray spherical analyzer based on α-quartz 4{\bar 4}04 are presented. The performance of the analyzer was demonstrated by applying it to a high-resolution X-ray spectroscopy study of theKα1,2emission spectrum of Ni. An analytical representation based on physical grounds was assumed to model the shape of the X-ray emission lines. Satellite structures assigned to 3dspectator hole transitions were resolved and determined as well as their relative contribution to the emission spectrum. The present results on 1s−13d−1shake probabilities support a recently proposed calculation framework based on a multi-configuration atomic model.


2011 ◽  
Vol 134 (1) ◽  
Author(s):  
Ivo Alxneit ◽  
Henri Schmit

In this publication, the detailed spectral characterization of the concentrated radiation of PSI’s 50 kW xenon arc lamp based solar simulator (HFSS) is reported. Spectra are presented for the range of 350–1600 nm recorded at different radial distances from the position of maximum concentration, i.e., from the center of the spot. The analysis shows that the relative intensity of the short wavelength region decreases with increasing radial distance from the center of the spot. At the same time, the relative contribution of the xenon emission lines increases. All spectra can be decomposed into a broad background described by a blackbody spectrum with a temperature of T = 6000 ± 200 K and the characteristic line spectrum of xenon.


2005 ◽  
Vol 892 ◽  
Author(s):  
Iman Roqan ◽  
Carol Trager-Cowan ◽  
Ben Hourahine ◽  
Katharina Lorenz ◽  
Emilio Nogales ◽  
...  

AbstractComparative studies have been carried out on the cathodoluminescence (CL) and photoluminescence (PL) properties of GaN implanted with Tm and GaN co-implanted with Tm and a low concentration of Er. Room temperature CL spectra were acquired in an electron probe microanalyser to investigate the rare earth emission. The room temperature CL intensity exhibits a strong dependence on the annealing temperature of the implanted samples. The results of CL temperature dependence are reported for blue emission (∼ 477 nm) which is due to intra 4f-shell electron transitions (1G4 → 3H6) associated with Tm3+ ions. The 477 nm blue CL emission is enhanced strongly as the annealing temperature increases up to 1200°C. Blue PL emission has also been observed from the sample annealed at 1200°C. To our knowledge, this is the first observation of blue PL emission from Tm implanted GaN samples. Intra-4f transitions from the 1D2 level (∼ 465 nm emission lines) of Tm3+ ions in GaN have been observed in GaN:Tm films at temperatures between 20–200 K. We will discuss the temperature dependent Tm3+ emission in both GaN:Tm,Er and GaN:Tm samples.


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