Catalytic Synthesis of 4, 5, 8a-Triphenylhexahydropyrimido[4,5-d]-pyrimidine-2,7(1H,3H)-diones Derivatives by using Nano-SiO2-Supported Preyssler Heteropoly Acid

2014 ◽  
Keyword(s):  
Heteropoly Acid ◽  
Catalytic Synthesis ◽  
Nano Sio2

One-Pot Synthesis of 1-Benzoylpyrene over Heteropoly Acid Catalysts

2012 ◽  
Vol 560-561 ◽  
pp. 294-299
Author(s):  
Xiao Qing Lu ◽  
Min Xing ◽  
Ai Xia Pan ◽  
Yin Yin Wu ◽  
Ji Min Xie ◽  
...  
Keyword(s):  
Benzoyl Chloride ◽  
Heteropoly Acid ◽  
Active Catalyst ◽  
Catalytic Synthesis ◽  
Acid Catalysts ◽  
Acylation Reaction ◽  
One Pot ◽  
Experimental Parameters ◽  
Product Separation ◽  
Ft Ir

A novel one-pot catalytic synthesis of 1-benzoylpyrene through acylation of pyrene with benzoyl chloride catalyzed by various Keggin type heteropoly acids (salts) was investigated. Pure 1-benzoylpyrene was obtained and the structure of 1-benzoylpyrene was identified by GC/MS, FT-IR and 1H NMR spectra. H3PW12O40 (PW) was found to be the most active catalyst in the acylation. The yield and the selectivity of 1-benzoylpyrene were up to 97.6 % and 100 %, respectively. The effects of experimental parameters on the catalytic acylation reaction and the recycling performance of PW catalyst were studied. PW catalyst shows well catalytic activity after running for 5 times. The facile product separation and the recycling performance of PW catalyst is expected to contribute to the development of clean and environmentally friendly strategy for the synthesis of 1-benzoylpyrene.

Preparation of H5PMo10V2O40 /SBA-15 Catalyst and Application in Synthesis of Tributyl Citrate

2011 ◽  
Vol 236-238 ◽  
pp. 1019-1022
Author(s):  
Bing Hu ◽  
Chuan Qun Hu ◽  
Long Hui Nie ◽  
Ming Xia Fan
Keyword(s):  
Catalytic Activity ◽  
Structural Stability ◽  
Heteropoly Acid ◽  
Acid Catalyst ◽  
Catalytic Synthesis ◽  
High Catalytic Activity ◽  
Impregnation Method ◽  
Dispersion Characteristics ◽  
Fine Dispersion ◽  
Ft Ir

The heteropoly acid catalyst of H5PMo10V2O40 supported on SBA-15 mesoporous mole-cular sieve was prepared by an impregnation method and characterized by nitrogen physisorption, FT-IR,SEM, and used in catalytic synthesis of tributyl citrate. The results show that the heteropoly acid catalyst has fine dispersion characteristics, structural stability, high catalytic activity and better reusability.

scholarly journals Preparation supported heteropoly (acid)/polyaniline catalysts and catalytic synthesis of tributyl citrate

RSC Advances ◽  
2019 ◽  
Vol 9 (57) ◽  
pp. 33124-33129
Author(s):  
Limin Wang ◽  
Bin Ding ◽  
Miao Zhang
Keyword(s):  
Room Temperature ◽  
Heteropoly Acid ◽  
Catalytic Synthesis ◽  
Heteropoly Acids ◽  
Simple Method

A series of polyaniline supported heteropoly acids were prepared through a simple method at room temperature.

Selective catalytic synthesis of short chain oxymethylene ethers by a heteropoly acid – a reaction parameter and kinetic study

2021 ◽  
Author(s):  
Daniel Huth ◽  
Marcus Rose
Keyword(s):  
Kinetic Study ◽  
Diesel Fuel ◽  
Heteropoly Acid ◽  
Catalytic Synthesis ◽  
Short Chain ◽  
Oxidation States ◽  
Reaction Parameter ◽  
Platform Chemicals ◽  
Low Emission

Oxymethylene ethers (OME) are considered as low-emission additive or replacement to diesel fuel. They can be synthesized by different routes based on C1 platform chemicals in different oxidation states. The...

Catalytic Synthesis of Cyclic Guanidines via Hydrogen Atom Transfer and Radical-Polar Crossover

2020 ◽  
Author(s):  
Shunya Ohuchi ◽  
Hiroki Koyama ◽  
Hiroki Shigehisa
Keyword(s):  
Hydrogen Atom ◽  
Functional Group ◽  
Hydrogen Atom Transfer ◽  
Catalytic Synthesis ◽  
Membered Ring ◽  
Biologically Active ◽  
Atom Transfer ◽  
Powerful Method ◽  
Protective Groups ◽  
The Common

A catalytic synthesis of cyclic guanidines, which are found in many biologically active compounds and natu-ral products, was developed, wherein transition-metal hydrogen atom transfer and radical-polar crossover were employed. This mild and functional-group tolerant process enabled the cyclization of alkenyl guanidines bearing common protective groups, such as Cbz and Boc. This powerful method not only provided the common 5- and 6-membered rings but also an unusual 7-membered ring. The derivatization of the products afforded various heterocycles. We also investigated the se-lective cyclization of mono-protected or hetero-protected (TFA and Boc) alkenyl guanidines and their further derivatiza-tions.

Synthesis of 3,4-Dihydropyrimidin-2(1H)-one Derivatives Using Activated Montmorillonite as Catalyst

2018 ◽  
Vol 16 (1) ◽  
pp. 59-65
Author(s):  
Sofiane Mekki ◽  
Lahcen Krabia ◽  
Saleh Mahmoud Saleh Mohamed ◽  
Salima Saidi-Besbes
Keyword(s):  
Catalytic Synthesis ◽  
Montmorillonite Clays

An efficient catalytic synthesis of 4-aryl-3,4-dihydropyrimidine-2(1H)-one derivatives using copper (II), iron (III) and zinc (II) exchanged montmorillonite clays as a catalyst is described. The desired products were obtained in good yields.

Sign in / Sign up

Export Citation Format

Share Document