Using Soft X-ray Absorption Spectroscopy to Examine the Structural Changes Taking Place around Si and Al Atoms in Kaolinite Following Flash Calcination

1993 ◽  
Vol 32 (S2) ◽  
pp. 652 ◽  
Author(s):  
K. J. Roberts ◽  
J. Robinson ◽  
T. W. Davies ◽  
R. M. Hooper
Keyword(s):  
Absorption Spectroscopy ◽  
Structural Changes ◽  
X Ray ◽  
Flash Calcination ◽  
X Ray Absorption

Ascertaining the nanocluster formation within an ion-irradiated Pt/Ni/C multi-trilayer with X-ray absorption spectroscopy

2012 ◽  
Vol 20 (1) ◽  
pp. 137-144
Author(s):  
Nitya Ramanan ◽  
Sumalay Roy ◽  
Debdutta Lahiri ◽  
Surinder M. Sharma ◽  
B. N. Dev
Keyword(s):  
Absorption Spectroscopy ◽  
Structural Changes ◽  
Nearest Neighbor ◽  
Ion Irradiation ◽  
Physical Adsorption ◽  
X Ray ◽  
Bimetallic Nanoclusters ◽  
Wave Technique ◽  
Wide Scale ◽  
X Ray Absorption

In this work nanoclusters formed in a Pt/Ni/C multi-trilayer by the ion-irradiated method of synthesis are characterized. In particular, an attempt to understand the role of interfaces in the synthesis is made. With this objective, ion-irradiation-induced structural changes in a Pt/Ni/C multi-trilayer using X-ray absorption spectroscopy (at the NiK-edge) in conjunction with the X-ray standing-wave technique are investigated. The XANES analysis identifies chemical binding at pristine Ni/C and Ni/Pt interfaces, in contrast with physical adsorption at the Pt/C interface. The chemical nature of the interfaces determines their relative stability with respect to irradiation and controls the extent of metallic diffusion. The most interesting structural change, upon irradiation, is the disruption of the Pt/C interface and subsequent migration of Pt atoms towards pre-diffused Ni atoms within the C layer, leading to the formation of Ni-centered Ni–Pt bimetallic nanoclusters (with Ni:Pt = 60:40). These clusters are highly disordered beyond their nearest neighbor and find wide-scale applications as, for example, magnetic devicesetc. The implications of these findings on the design goals are discussed.

The structure and bonding properties of tiopronin-protected silver nanoparticles as studied by X-ray absorption spectroscopy

2018 ◽  
Vol 96 (7) ◽  
pp. 749-754 ◽  
Author(s):  
J. Daniel Padmos ◽  
David J. Morris ◽  
Peng Zhang
Keyword(s):  
Optical Properties ◽  
Absorption Spectroscopy ◽  
Structural Changes ◽  
Chemical Properties ◽  
Structure Property ◽  
Ag Nps ◽  
X Ray ◽  
Ligand Shell ◽  
Bonding Properties ◽  
X Ray Absorption

Thiolate-protected Ag nanoparticles (NPs) exhibit interesting physical and chemical properties which may lead to various sensing, diagnostic, and therapeutic applications. Further, understanding structure–property relationships of Ag NPs is of great interest to optimize their application. Herein, we used TEM, UV–vis, and a series of synchrotron X-ray spectroscopy techniques to probe the local structure and chemical bonding properties of thiolate-stabilized Ag NPs. Compared with other Ag nanostructures prepared under slightly modified conditions, the Ag NPs were found to have pronounced structural changes, which led to immensely different optical properties. Notably, the NPs were also found to have similar surface structure to recently elucidated Ag nanoclusters prepared with different thiolates. These findings suggest that the NP structure and optical properties can be sensitively tailored by controlling the synthetic conditions. The multi-element, multi-core excitation approach (i.e., Ag K-, Ag L3-, and S K-edges) employed in the X-ray absorption spectroscopy measurements was also demonstrated as an effective tool to uncover the NP structure from both the metal core and the ligand shell perspectives.

Local electronic and atomic structures of the mixed B-site ions in SrFe1−xMnxO3−δ studied with X-ray absorption spectroscopy

2021 ◽  
pp. 2140048
Author(s):  
Masatsugu Oishi ◽  
Fumito Fujishiro ◽  
Toshiaki Ina ◽  
Hirona Yamagishi ◽  
Iwao Watanabe ◽  
...  
Keyword(s):  
Fine Structure ◽  
Absorption Spectroscopy ◽  
Structural Changes ◽  
Perovskite Oxides ◽  
X Ray ◽  
Atomic Structures ◽  
Exafs Analysis ◽  
Mn Content ◽  
X Ray Absorption ◽  
Fe Ions

Local electronic and atomic structures of the B-site ions in perovskite SrFe[Formula: see text]Mn[Formula: see text]O[Formula: see text] were evaluated with X-ray absorption spectroscopy (XAS) at Mn, Fe [Formula: see text]- and [Formula: see text]-edges and O [Formula: see text]-edge. The energy of [Formula: see text]- and [Formula: see text]-edge peaks for Mn and Fe ions stayed unchanged against the change in Mn content [Formula: see text]. The analysis of Mn [Formula: see text]-edge extended X-ray absorption fine structure (EXAFS) revealed that Mn−O polyhedra was kept as an octahedron with Mn[Formula: see text] irrespective of the [Formula: see text] value, agreeing with the results of [Formula: see text]-edge spectra. The Fe [Formula: see text]-edge EXAFS analysis showed that the Fe–O distance decreased with decrease of the Mn contents, suggesting that the ratio of FeO5 polyhedra to FeO6 octahedra is increased due to smaller oxygen amount. By analyzing both the [Formula: see text]-edge and [Formula: see text]-edge spectra, we clarified the local electronic and atomic structural changes particularly occurred in the B-site mixed perovskite oxides.

scholarly journals Pressure-induced structural changes in α-MoO3 probed by X-ray absorption spectroscopy

2019 ◽  
Vol 503 ◽  
pp. 012018 ◽  
Author(s):  
Inga Jonane ◽  
Andris Anspoks ◽  
Lucie Nataf ◽  
Francois Baudelet ◽  
Tetsuo Irifune ◽  
...  
Keyword(s):  
Absorption Spectroscopy ◽  
Structural Changes ◽  
X Ray ◽  
X Ray Absorption

Electronic and local structural changes with lithium-ion insertion in TiO2-B: X-ray absorption spectroscopy study

2011 ◽  
Vol 21 (39) ◽  
pp. 15369 ◽  
Author(s):  
Toyoki Okumura ◽  
Tomokazu Fukutsuka ◽  
Asuki Yanagihara ◽  
Yuki Orikasa ◽  
Hajime Arai ◽  
...  
Keyword(s):  
Absorption Spectroscopy ◽  
Structural Changes ◽  
Lithium Ion ◽  
Spectroscopy Study ◽  
X Ray ◽  
X Ray Absorption ◽  
Ion Insertion
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