scholarly journals Theoretical research on radiative transition probabilities of 2p4f—2p3d for NⅡ

2007 ◽  
Vol 56 (10) ◽  
pp. 5715
Author(s):  
Shen Xiao-Zhi ◽  
Yuan Ping ◽  
Li Ji-Guang ◽  
Dong Chen-Zhong ◽  
Xie Lu-You ◽  
...  
Author(s):  
A.O. KHARCHENKO ◽  
A.A. KHARCHENKO

The article presents the results of analysis and theoretical research in the direction of improving equipment for internal threading of parts in a flexible automated production. Methods for assessing the flexibility and readjustability of equipment are considered, which can be used as the basis for the developed methodology for the synthesis of technological elements of modules in conditions of computer-aided design. It is proposed to consider the technological system of the flexible manufacturing module (FMM) of threading, as a system in which transitions from state to state occur under the action of the simplest flows with the parameters of the transition probabilities of a continuous Markov chain. The developed mathematical model, which describes the states of a FMM, taking into account the readjustment of its technological elements, makes it possible to reflect the influence on the operation of the module of the parameters of applications for the changeover of processing modes, a tool, a power threading head, basic elements of a machine tool, a device, a loading device. The structure of the model and the labeled graph of the states of the system can be improved as the number of parameters and characteristics is refined. The solution of the resulting system of equations of final probabilities using the normalization condition allows for given (or experimentally obtained) intensities of arrival and service of changeover requests for FMM of threading, to obtain the values of the probability of non-changeover operation, as well as the probabilities of finding the system in an inoperative state due to the corresponding changeovers. For complete information and an objective assessment of the preferred option for use in FMS conditions, it is also necessary to take into account the stochastic processes occurring in the system under real operating conditions.


The technique described in part I has been used to obtain constants of interest in molecular spectroscopy. The vibration-rotation interaction factor, F for HCl has been evaluated from the infra-red emission spectrum. The critical parameter in F is θ = M 0 / M 1 r e , where M 0 and M 1 are the first two coefficients in the electric dipole moment expansion about the equilibrium internuclear distance r e . A value of θ = + 1.12 ± 0.18 has been obtained. It is shown that for molecules with θ = +1 the total band intensity in emission is independent of the rotational distribution in the vibrational state from which the emission occurs. This has been made use of in evaluating radiative transition probabilities. For the HCl v (3-1) transition a value for | R 3 1 | 2 (= 1.60 x 10 -4 debye 2 ) was obtained for the first time. The same method yields a value of | R 2 1 | 2 / | R 2 0 | 2 = 204, in good agreement with an earlier estimate from absorption data.


2014 ◽  
Vol 69 (8-9) ◽  
pp. 397-402
Author(s):  
Leyla Özdemir ◽  
Sadiye Tuna

We have investigated the correlation, relativistic, and isotope shift effects on the fine structure levels in the ground state configuration for the antimony anion ( Sb-). Energies and radiative transition probabilities (for magnetic dipole, M1, and electric quadrupole, E2) have been obtained using the multiconfiguration Hartree-Fock method within the framework of the Breit-Pauli Hamiltonian. Therefore, the most important configuration interaction and relativistic effects have been included. Comparisons with other available works are presented. For some M1 and E2 lines the considered transition probabilities are reported for the first time


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