scholarly journals A THEORETICAL ANALYSIS OF THE FIELD EVAPORATION IN THE CONFIGURATION OF SCANNING TUNNELING MICROSCOPE

1998 ◽  
Vol 47 (8) ◽  
pp. 1383
Author(s):  
LI ZHI-YANG ◽  
LIU WU ◽  
LI XING-JIAO
Keyword(s):  
Theoretical Analysis ◽  
Scanning Tunneling Microscope ◽  
Scanning Tunneling ◽  
Field Evaporation ◽  
Tunneling Microscope

The First Molecular Wheel: A Theoretical Investigation

2011 ◽  
Vol 1286 ◽  
Author(s):  
Gustavo Brunetto ◽  
Fernando Sato ◽  
Xavier Bouju ◽  
Douglas S. Galvao
Keyword(s):  
Molecular Dynamics ◽  
Theoretical Analysis ◽  
Scanning Tunneling Microscope ◽  
Copper Substrate ◽  
Spatial Separation ◽  
Rolling Process ◽  
Scanning Tunneling ◽  
Hydrocarbon Molecule ◽  
Tunneling Microscope ◽  
Molecular Dynamics Methods

ABSTRACTRecently, the first molecular nanowheel was synthesized and characterized from Scanning Tunneling Microscope (STM) experiments. It was demonstrated that a specifically designed hydrocarbon molecule (C44H24) could roll on a copper substrate along the [110] surface direction. In this work we report a preliminary theoretical analysis of the isolated molecule and of its rolling processes on different Cu surfaces. We have used ab initio and classical molecular dynamics methods. The simulations showed that the rolling mechanism is only possible for the [110] surface. In this case, the spatial separation among rows of copper atoms is enough to ‘trap’ the molecule and to create the necessary torque to roll it. Other surface orientations ([111] and [100]) are too smooth and cannot provide the necessary torque for the rolling process.

Scanning tunneling microscopy of E. coli RNA polymerase deposited onto an Au substrate by an electrochemical process

1991 ◽  
Vol 49 ◽  
pp. 378-379
Author(s):  
Rebecca W. Keller ◽  
Carlos Bustamante ◽  
David Bear
Keyword(s):  
Scanning Tunneling Microscope ◽  
Biological Sample ◽  
Substrate Surface ◽  
Electrochemical Process ◽  
Atomic Resolution ◽  
Scanning Tunneling ◽  
Tunneling Microscopy ◽  
Tunneling Microscope ◽  
E Coli ◽  
Preparation Techniques

Under ideal conditions, the Scanning Tunneling Microscope (STM) can create atomic resolution images of different kinds of samples. The STM can also be operated in a variety of non-vacuum environments. Because of its potentially high resolution and flexibility of operation, it is now being applied to image biological systems. Several groups have communicated the imaging of double and single stranded DNA.However, reproducibility is still the main problem with most STM results on biological samples. One source of irreproducibility is unreliable sample preparation techniques. Traditional deposition methods used in electron microscopy, such as glow discharge and spreading techniques, do not appear to work with STM. It seems that these techniques do not fix the biological sample strongly enough to the substrate surface. There is now evidence that there are strong forces between the STM tip and the sample and, unless the sample is strongly bound to the surface, it can be swept aside by the tip.

STM of freeze-fracture replicas: Problems and promises

1993 ◽  
Vol 51 ◽  
pp. 68-69
Author(s):  
J. T. Woodward ◽  
J. A. N. Zasadzinski
Keyword(s):  
Scanning Tunneling Microscope ◽  
Organic Materials ◽  
Freeze Fracture ◽  
Atomic Resolution ◽  
Scanning Tunneling ◽  
Tunneling Microscope ◽  
Molecular Scale ◽  
Organic Surfaces ◽  
Metal Layers ◽  
Conductive Surfaces

The Scanning Tunneling Microscope (STM) offers exciting new ways of imaging surfaces of biological or organic materials with resolution to the sub-molecular scale. Rigid, conductive surfaces can readily be imaged with the STM with atomic resolution. Unfortunately, organic surfaces are neither sufficiently conductive or rigid enough to be examined directly with the STM. At present, nonconductive surfaces can be examined in two ways: 1) Using the AFM, which measures the deflection of a weak spring as it is dragged across the surface, or 2) coating or replicating non-conductive surfaces with metal layers so as to make them conductive, then imaging with the STM. However, we have found that the conventional freeze-fracture technique, while extremely useful for imaging bulk organic materials with STM, must be modified considerably for optimal use in the STM.

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