scholarly journals EXPLANATION OF THE QUANTIZED MAGNETORESIS-TANCE IN MULTPLY CONNECTED PERIMETERS IN TWO-DIMENSION ELECTRON SYSTEMS

1990 ◽  
Vol 39 (9) ◽  
pp. 1461
Author(s):  
PENG JIAN-PING ◽  
ZHOU SHI-XUN
Author(s):  
M. Ali ◽  
◽  
A. P. Kiryanov ◽  
V. I. Kovalev ◽  
V. I. Pustovoit ◽  
...  

Author(s):  
Shiwei Wang ◽  
Anton Chavez ◽  
Simil Thomas ◽  
Hong Li ◽  
Nathan C. Flanders ◽  
...  

This work reports on the assembly of imine-linked macrocycles that serve as models of two-dimensional covalent organic frameworks (2D COFs). Interlayer interactions play an important role in the formation of 2D COFs, yet the effect of monomer structure on COF formation, crystallinity, and susceptibility to exfoliation are not well understood. For example, monomers with both electron-rich and electron-poor π-electron systems have been proposed to strengthen interlayer inter-actions and improve crystallinity. Here we probe these effects by studying the stacking behavior of imine-linked macrocycles that represent discrete models of 2D COFs. <div><br></div><div>Specifically, macrocycles based on terephthaldehyde (PDA) or 2,5-dimethoxyterephthaldehyde (DMPDA) stack upon cooling molecularly dissolved solutions. Both macrocycles assemble cooperatively with similar ΔHe values of -97 kJ/mol and -101 kJ/mol, respectively, although the DMPDA macrocycle assembly process showed a more straightforward temperature dependence. Circular dichroism spectroscopy performed on macrocycles bearing chiral side chains revealed a helix reversion process for the PDA macrocycles that was not observed for the DMPDA macrocycles. <br></div><div><br></div><div>Given the structural similarity of these monomers, these findings demonstrate that the stacking processes associated with nanotubes derived from these macrocycles, as well as for the corresponding COFs, are complex and susceptible to kinetic traps, casting doubt on the relevance of thermodynamic arguments for improving materials quality. <br></div>


Author(s):  
Cong Wang ◽  
Yongxue Zhang ◽  
Hucan Hou ◽  
Zhiyi Yuan

Low efficiency and bad cavitation performance restrict the development of the ultra-low specific-speed centrifugal pump (ULSSCP). In this research, combined turbulent boundary layer theory with two-dimension design and two-dimension viscous hydraulic design method has been proposed to redesign a ULSSCP. Through the solution of the displacement thickness in the boundary layer, a less curved blade profile with a larger outlet angle was obtained. Then the hydraulic and cavitation performance of the reference pump and the designed pump were numerically studied. The comparison of performance of the reference pump calculated by the numerical and experimental results revealed a better agreement. Research shows that the average hydraulic efficiency and head of the designed pump improve by 2.9% and 3.3%, respectively. Besides, the designed pump has a better cavitation performance. Finally, through the internal flow analysis with entropy production diagnostic model, a 24.8% drop in head loss occurred in the designed pump.


Sign in / Sign up

Export Citation Format

Share Document