scholarly journals THE ABSORPTION SPECTRUM AND QUANTUM STATES OF NEODYMIUM ION (Nd3+) IN SINGLE CRYSTAL OF ANHYDROUS NEODYMIUM CHLORIDE AND ANHYDROUS PRASEDYMIUM CHLORIDE

1980 ◽  
Vol 29 (5) ◽  
pp. 602
Author(s):  
SONG ZENG-FU ◽  
ZHANG HE-YI ◽  
XU YAO-ZHOU ◽  
LUO ZHEN-JI ◽  
JIAN HONG-ZHONG ◽  
...  
2012 ◽  
Vol 16 (01) ◽  
pp. 154-162 ◽  
Author(s):  
Edwin W.Y. Wong ◽  
Daniel B. Leznoff

The reduction of magnesium phthalocyanine (MgPc) with 2.2 equivalents of potassium graphite in 1,2-dimethoxyethane (DME) gives [K2(DME)4]PcMg(OH)(1) in 67% yield. Compound 1 was structurally characterized using single crystal X-ray crystallography and was found to be a monomeric, heterometallic complex consisting of a μ3-OH ligand that bridges a [MgIIPc3-]- anion to two potassium cations solvated by four DME molecules. An absorption spectrum of 1 confirms the Pc ligand is singly reduced and has a 3–charge. The solid-state structure of 1 does not indicate breaking of the aromaticity of the Pc ligand. Compound 1 is only the second Pc3- complex and the first reduced MgPc to be isolated and structurally characterized.


1997 ◽  
Vol 39 (12) ◽  
pp. 1916-1920 ◽  
Author(s):  
Yu. P. Sukhorukov ◽  
N. N. Loshkareva ◽  
A. S. Moskvin ◽  
V. L. Arbuzov ◽  
A. S. Ovchinnikov ◽  
...  

1987 ◽  
Vol 37 (11) ◽  
pp. 1296-1300 ◽  
Author(s):  
B. C. Venkata Reddy ◽  
B. K. Syamala Devi ◽  
B. Munibhadraiah

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