scholarly journals Life Cycle Assessment of Renewable Polyol Monomers for Polyurethane Production

2020 ◽  
Author(s):  
◽  
Anda Fridrihsone

ycle Inventory of winter and spring rapeseed production in Latvia as a case study country in Northern Europe. In-depth and up-to-date agricultural practices used in the region under study data were provided by a large agricultural company located in Zemgale region in Latvia. Chapter III Part II presents an inventory of rapeseed oil mill stage with data provided by operation oil mill in Zemgale region. Different allocation methods are applied to further investigate the effect of different allocation methods on the environmental profiles of rapeseed oil-based bio-polyols and the consequences of applying these methods considering the main aims of the study. Chapter III Part III presents Life Cycle Impact Assessment of winter and spring rapeseed production and rapeseed oil production. Environmental performance is analyzed with Cumulative energy demand impact indicator along with the ReCiPe impact assessment methodology. The main environmental hotspots were identified. Sensitivity analysis was performed. Chapter III Part IV presents results of the Life Cycle Assessment of two rapeseed oil-based bio-polyols. Life Cycle Inventories were built on experimental data for polyol synthesis that were performed in a pilot-scale (50 L reactor). Bio-based polyols were compared with the petrochemical counterpart. The two developed rapeseed oil-based polyols were analyzed with three different modelling approaches for the bio-based feedstock stage. Sensitivity analysis was performed.

2020 ◽  
Vol 12 (14) ◽  
pp. 5699 ◽  
Author(s):  
Anda Fridrihsone ◽  
Francesco Romagnoli ◽  
Ugis Cabulis

There is a major international effort to improve the availability of data for life cycle assessment (LCA), as these assessments have become one of the main pillars driving European policy with respect to the sustainable use of resources. However, there is still a lack of data even for Europe. This study presents a cradle-to-farm gate assessment, or LCA, of winter and spring rapeseed produced in the northern European country of Latvia. The LCA model is based on an in-depth and up-to-date agricultural practice used in the region and covers the time span of 2008–2016. An LCA of rapeseed oil produced by cold pressing was carried out. The environmental impact assessment was calculated with the ReCiPe impact assessment method version 1.03, a hierarchical (H) perspective, along with the cumulative energy demand method v1.11. Cultivation of winter rapeseed has a lower environmental impact than cultivation of spring rapeseed due to higher agricultural inputs and higher yield. The greatest impact is on human health. Mineral fertilizers (production and application) and agricultural machinery are responsible for the greatest environmental impact. The results for the mill stage of rapeseed oil demonstrated that the choice of the allocation method has a significant impact on the environmental performance results.


2D Materials ◽  
2021 ◽  
Author(s):  
Jose Munuera ◽  
L. Britnell ◽  
C. Santoro ◽  
R. Cuéllar-Franca ◽  
Cinzia Casiraghi

Abstract Advanced materials such as graphene and the family of 2-dimensional (2D) crystals are very attractive because of the myriad of applications that could be developed based on their outstanding properties. However, as soon as material development reaches enough maturity for production to be scaled up and to enter the market within products, it is crucial to place the technology in the context of possible risks to economic well-being, social equity and environmental harm. This review aims at highlighting the current state of art on sustainable development of graphene-based materials and related environmental impact assessment studies using life cycle assessment. We show that sustainable development has focused mostly on the use of waste or low cost materials as precursors. However, the findings from relevant life cycle assessment studies reveals the limits of this approach, which does not take into account that waste recycling is often very energy intensive. We provide an overview on the life cycle environmental impact assessment, with a focus of global warming potential and energy demand, carried out on different graphene productions methods for specific applications, ranging from composites to electronics. Finally, an outlook is given focussing on the comparison of the different production routes and the results from the life cycle assessment.


2020 ◽  
Vol 14 (3) ◽  
pp. 559-579
Author(s):  
Marwa Dabaieh ◽  
Nargessadat Emami ◽  
Jukka Taneli Heinonen ◽  
Björn Marteinsson

PurposeOver the last eight years, the Middle East has experienced a series of high profile conflicts which have resulted in over 5.6 million Syrians forced to migrate to neighbouring countries within the MENA (Middle East and North Africa) region or to Europe. That have exerted huge pressure on hosting countries trying to accommodate refugees in decent shelters and in quick manner. Temporary shelters normally carry a high environmental burden due to their short lifespan, and the majority are fabricated from industrialised materials. This study assesses the carbon impact for a minus carbon experimental refugee house in Sweden using life cycle assessment (LCA) as tool. SimaPro and GaBi software were used for the calculations and the ReCiPe midpoint method for impact assessment. The results show that using local plant-based materials such as straw, reeds and wood, together with clay dug from close to the construction site, can drastically reduce the carbon footprint of temporary shelters and even attain a negative carbon impact of 226.2 kg CO2 eq/m2. Based on the results of the uncertainty importance analysis, the overall global warming potential impact without and with sequestration potential are mostly sensitive to the variability of the GWP impact of wood fibre insulation.Design/methodology/approachThe methodology is designed to calculate the GWP impact of the refugee house over its entire life cycle (production, operation and maintenance and end of life). Then, the sensitivity analysis was performed to explore the impact of input uncertainties (selection of material from the database and the method) on the total GWP impact of the refugee house with and without sequestration. The ISO standards (International Standard 14040 2006; International Standard 14044 2006) divide the LCA framework into four steps of Goal and scope, inventory analysis, impact assessment, and interpretation.FindingsThis study has shown an example for proof of concept for a low impact refugee house prototype using straw, reeds, clay, lime and wood as the principle raw materials for building construction. Using natural materials, especially plant-based fibres, as the main construction materials, proved to achieve a minus carbon outcome over the life cycle of the building. The GWP of the shelter house without and with sequestration are found to be 254.7 kg CO2 eq/m2 and -226.2 kg CO2 eq/m2, respectively.Originality/valueAs there are still very few studies concerned with the environmental impact of temporary refugee housing, this study contributes to the pool of knowledge by introducing a complete LCA calculation for a physical house prototype as a proof of concept on how using low impact raw materials for construction combined with passive solutions for heating and cooling can reach a minus carbon outcome. The GWP of the shelter house without and with sequestration are found to be 254.7 kg CO2 eq/m2 and -226.2 kg CO2 eq/m2.


Author(s):  
M. von der Thannen ◽  
S. Hoerbinger ◽  
C. Muellebner ◽  
H. Biber ◽  
H. P. Rauch

AbstractRecently, applications of soil and water bioengineering constructions using living plants and supplementary materials have become increasingly popular. Besides technical effects, soil and water bioengineering has the advantage of additionally taking into consideration ecological values and the values of landscape aesthetics. When implementing soil and water bioengineering structures, suitable plants must be selected, and the structures must be given a dimension taking into account potential impact loads. A consideration of energy flows and the potential negative impact of construction in terms of energy and greenhouse gas balance has been neglected until now. The current study closes this gap of knowledge by introducing a method for detecting the possible negative effects of installing soil and water bioengineering measures. For this purpose, an environmental life cycle assessment model has been applied. The impact categories global warming potential and cumulative energy demand are used in this paper to describe the type of impacts which a bioengineering construction site causes. Additionally, the water bioengineering measure is contrasted with a conventional civil engineering structure. The results determine that the bioengineering alternative performs slightly better, in terms of energy demand and global warming potential, than the conventional measure. The most relevant factor is shown to be the impact of the running machines at the water bioengineering construction site. Finally, an integral ecological assessment model for applications of soil and water bioengineering structures should point out the potential negative effects caused during installation and, furthermore, integrate the assessment of potential positive effects due to the development of living plants in the use stage of the structures.


Author(s):  
Ahmed I. Osman ◽  
Neha Mehta ◽  
Ahmed M. Elgarahy ◽  
Amer Al-Hinai ◽  
Ala’a H. Al-Muhtaseb ◽  
...  

AbstractThe global energy demand is projected to rise by almost 28% by 2040 compared to current levels. Biomass is a promising energy source for producing either solid or liquid fuels. Biofuels are alternatives to fossil fuels to reduce anthropogenic greenhouse gas emissions. Nonetheless, policy decisions for biofuels should be based on evidence that biofuels are produced in a sustainable manner. To this end, life cycle assessment (LCA) provides information on environmental impacts associated with biofuel production chains. Here, we review advances in biomass conversion to biofuels and their environmental impact by life cycle assessment. Processes are gasification, combustion, pyrolysis, enzymatic hydrolysis routes and fermentation. Thermochemical processes are classified into low temperature, below 300 °C, and high temperature, higher than 300 °C, i.e. gasification, combustion and pyrolysis. Pyrolysis is promising because it operates at a relatively lower temperature of up to 500 °C, compared to gasification, which operates at 800–1300 °C. We focus on 1) the drawbacks and advantages of the thermochemical and biochemical conversion routes of biomass into various fuels and the possibility of integrating these routes for better process efficiency; 2) methodological approaches and key findings from 40 LCA studies on biomass to biofuel conversion pathways published from 2019 to 2021; and 3) bibliometric trends and knowledge gaps in biomass conversion into biofuels using thermochemical and biochemical routes. The integration of hydrothermal and biochemical routes is promising for the circular economy.


2021 ◽  
Vol 128 ◽  
pp. 1-15
Author(s):  
Navarro Ferronato ◽  
Luca Moresco ◽  
Gabriela Edith Guisbert Lizarazu ◽  
Marcelo Antonio Gorritty Portillo ◽  
Fabio Conti ◽  
...  

Author(s):  
Md.Musharof Hussain Khan ◽  
Ivan Deviatkin ◽  
Jouni Havukainen ◽  
Mika Horttanainen

Abstract Purpose Waste recycling is one of the essential tools for the European Union’s transition towards a circular economy. One of the possibilities for recycling wood and plastic waste is to utilise it to produce composite product. This study analyses the environmental impacts of producing composite pallets made of wood and plastic waste from construction and demolition activities in Finland. It also compares these impacts with conventional wooden and plastic pallets made of virgin materials. Methods Two different life cycle assessment methods were used: attributional life cycle assessment and consequential life cycle assessment. In both of the life cycle assessment studies, 1000 trips were considered as the functional unit. Furthermore, end-of-life allocation formula such as 0:100 with a credit system had been used in this study. This study also used sensitivity analysis and normalisation calculation to determine the best performing pallet. Result and discussion In the attributional cradle-to-grave life cycle assessment, wood-polymer composite pallets had the lowest environmental impact in abiotic depletion potential (fossil), acidification potential, eutrophication potential, global warming potential (including biogenic carbon), global warming potential (including biogenic carbon) with indirect land-use change, and ozone depletion potential. In contrast, wooden pallets showed the lowest impact on global warming potential (excluding biogenic carbon). In the consequential life cycle assessment, wood-polymer composite pallets showed the best environmental impact in all impact categories. In both attributional and consequential life cycle assessments, plastic pallet had the maximum impact. The sensitivity analysis and normalisation calculation showed that wood-polymer composite pallets can be a better choice over plastic and wooden pallet. Conclusions The overall results of the pallets depends on the methodological approach of the LCA. However, it can be concluded that the wood-polymer composite pallet can be a better choice over the plastic pallet and, in most cases, over the wooden pallet. This study will be of use to the pallet industry and relevant stakeholders.


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