scholarly journals Simultaneous nitrate and organic matter removal from a dairy effluent by biodenitrification

2018 ◽  
Vol 31 (2) ◽  
pp. 97-107
Author(s):  
Ahmed Hamdani ◽  
Mohammed Mountadar ◽  
Omar Assobhei

In order to study the simultaneous removal of nitrate and organic matter from a dairy effluent containing 670 mg∙L-1 of nitrate (NO3--N) and 5 760 mg∙L-1 of dissolved chemical oxygen demand (CODd), denitrification in a laboratory scale bioreactor consisting of an immersed bacterial bed colonized by an heterotrophic denitrifying flora (HDF) selected for NO3- reduction, COD consumption and adapted to grow on an effluent produced by a dairy industry was investigated. The obtained results indicated that at the optimal conditions of temperature (30°C), pH (7), COD/NO3--N ratio (5), the operation lasted 108h with total reduction of nitrate in 72h, no nitrite accumulation, and 92% of soluble COD removal in 96h. This indicates that the biodenitrification was accompanied with a high efficiency of matter organic removal as an electron donor, and thereby satisfies the applicable standards.

2018 ◽  
Vol 78 (6) ◽  
pp. 1260-1267 ◽  
Author(s):  
Mohammad Malakootian ◽  
Mohammad Reza Heidari

Abstract Phenol and its derivatives are available in various industries such as refineries, coking plants, steel mills, drugs, pesticides, paints, plastics, explosives and herbicides industries. This substance is carcinogenic and highly toxic to humans. The purpose of the study was to investigate the removal of phenol from wastewater of the steel industry using the electrocoagulation–photo-Fenton (EC-PF) process. Phenol and chemical oxygen demand (COD) removal efficiency were investigated using the parameters pH, Fe2+/H2O2, reaction time and current density. The highest removal efficiency rates of phenol and COD were 100 and 98%, respectively, for real wastewater under optimal conditions of pH = 4, current density = 1.5 mA/cm2, Fe2+/H2O2 = 1.5 and reaction time of 25 min. Combination of the two effective methods for the removal of phenol and COD, photocatalytic electrocoagulation photo-Fenton process is a suitable alternative for the removal of organic pollutants in industry wastewater because of the low consumption of chemicals, absence of sludge and other side products, and its high efficiency.


2021 ◽  
Vol 10 (3) ◽  
pp. 299-306
Author(s):  
Erick Samuel Frederico Hasibuan ◽  
Endang Supriyantini ◽  
Sunaryo Sunaryo

Perairan Silugonggo merupakan area pemukiman warga dengan banyak aktivitas perikanan dan kelautan seperti: pertambakan, industri perikanan dan merupakan alur pelayaran. Tingginya aktivitas pemukiman dan industri akan menghasilkan limbah organik dalam jumlah besar. Bahan organik yang melimpah dapat menimbulkan pencemaran lingkungan. Penelitian ini bertujuan untuk mengetahui kandungan bahan organik di perairan sungai Silugonggo, Kecamatan Juwana, Kabupaten Pati. Kandungan bahan organik diketahui melalui analisis parameter TOM (Total Organic Matter), BOD5 (Biochemical Oxygen Demand) dan COD (Chemical Oxygen Demand). Pengambilan sampel dilaksanakan pada tanggal 20 Desember 2019 dan 20 Januari 2020. Metode yang digunakan pada penelitian ini menggunakan metode kasus dengan pengamatan secara langsung di lapangan dan penentuan lokasi penelitian menggunakan metode purposive sampling. Hasil pengukuran parameter penelitian dianalisis menggunakan analisis ragam. Hasil penelitian menunjukkan bahwa nilai TOM sebesar 8,11 – 11,9 mg/L. Hasil pengukuran parameter (a) BOD5 sebesar 8,07 – 24,66 mg/L dan (b) COD sebesar 26,04 – 79,21 mg/L, hasil tersebut berada di bawah baku mutu yang ditetapkan menurut Keputusan Menteri Lingkungan Hidup No. 51 Tahun 2004 tentang Baku Mutu Air Limbah. Tingginya nilai TOM dikarenakan banyaknya masukan limbah bahan organik dari aktivitas di perairan sungai Silugonggo, seperti: pertambakan, industri perikanan, dan alur pelayaran. Silugonggo waters is a residential area with many fishery and marine activities such as: aquaculture, fishing industry and shipping lanes. High residential and industrial activities will produce large amounts of organic waste. Abundant organic matter can cause environmental pollution. This study aims to determine the content of organic matter in the waters of the Silugonggo River, Juwana District, Pati Regency. The content of organic matter is known through parameter analysis of TOM (Total Organic Matter), BOD5 (Biochemical Oxygen Demand) and COD (Chemical Oxygen Demand). Sampling was carried out on December 20, 2019 and January 20, 2020. The method used in this study used the method of direct observation in the field and the date of the research location using the purposive sampling method. The results of the measurement of research parameters were analyzed using analysis of variance. The results showed that the TOM value was 8.11–11.9 mg/L. Parameter measurement results (a) BOD5 of 8.07–24.66 mg/L and (b) COD of 26.04–79.21 mg/L, these results are below the quality standard stipulated according to the Decree of the Minister of the Environment No. 51 of 2004 concerning Wastewater Quality Standards. The high value of TOM is due to the large number of inputs of organic matter from activities in the waters of the Silugonggo river, such as: aquaculture, fishing industry, and shipping lanes.


2020 ◽  
Vol 9 (6) ◽  
pp. e183963748
Author(s):  
Rafael Souza Leopoldino Nascimento ◽  
Ludymyla Marcelle Lima Silva ◽  
Lucas Periard ◽  
Anibal da Fonseca Santiago

The technology of microalgae photobioreactors and illuminated by LEDs has been widely studied for the treatment of wastewater. However, sunlight is a free resource and should be taken advantage of. But the question remains whether photobioreactors illuminated by natural (sunlight) light in combination with artificial light can have greater operational stability or greater performance when compared to systems illuminated only by artificial light. In this context, continuous flow photobioreactors illuminated by Light Emitting Diodes (LEDs) combined, or not, with sunlight were operated and had their performance evaluated. The variables analyzed were pH, OD, chemical oxygen demand (COD), chlorophyll - a and total suspended solids. The photobioreactors were effective for removing organic matter, with 75 ± 15% in the photobioreactor illuminated by LED and 65 ± 10% in the photobioreactor illuminated by sunlight and LED. The results showed that the use of combined lighting favors the production of dissolved oxygen and ensures greater operational stability in the removal of carbonaceous organic matter.


Water ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 2538 ◽  
Author(s):  
Artur Mielcarek ◽  
Joanna Rodziewicz ◽  
Wojciech Janczukowicz ◽  
Artur Dobrowolski

Soilless plantations under cover constitute a significant part of horticulture. This study aimed at determining the qualitative composition of wastewater generated from the soilless cultivation of tomato under cover. This is important for managing the wastewater, which may be recirculated to allow the or employ a partial or complete recovery of minerals. Two plantations located in north-eastern Poland, which differed in the type of substratum (coconut fiber or rockwool), were studied. The generated wastewater was characterized by a low content of organic matter and a high concentration of total nitrogen (TN), total phosphorus (TP), and salinity (EC). Over 99% of the TN was constituted by nitrates. The chemical oxygen demand (COD) changed from 50.07 to 75.82 mgO2·L−1 (greenhouse 1), and from 37.35 to 78.12 mgO2·L−1 (greenhouse 2); the content of TN changed from 403.59 to 614.89 mgN·L−1 (greenhouse 1), and from 270.00 to 577.40 mgN·L−1 (greenhouse 2); that of TP changed from 35.44 to 78.00 mgP·L−1 (greenhouse 1), and from 54.10 to 104.00 mgP·L−1 (greenhouse 2); and the EC changed from 3.53 to 6.93 mS·cm−1 (greenhouse 1), and from 4.94 to 6.94 mS·cm−1 (greenhouse 2). No statistically significant correlations were noted between TN and TP, or between TP and EC.


2014 ◽  
Vol 69 (8) ◽  
pp. 1669-1675 ◽  
Author(s):  
Rogerio Silveira Vilela ◽  
Márcia Helena Rissato Zamariolli Damianovic ◽  
Eugenio Foresti

The simultaneous organic matter removal and sulfate reduction in synthetic sulfate-rich wastewater was evaluated for various chemical oxygen demand (COD)/sulfate ratios applied in a horizontal-flow anaerobic immobilized sludge (HAIS) reactor. At higher COD/sulfate ratios (12.5 and 7.5), the removal of organic matter was stable, likely due to methanogenesis. A combination of sulfate reduction and methanogenesis was clearly established at COD/sulfate ratios of 3.0 and 1.9. At a COD/sulfate ratio of 1.0, the organic matter removal was likely influenced by methanogenesis inhibition. The quantity of sulfate removed at a COD/sulfate ratio of 1.0 was identical to that obtained at a ratio of 1.9, indicating a lack of available electron donors for sulfidogenesis. The sulfate reduction and organic matter removal were not maximized at the same COD/sulfate ratio; therefore, competitive inhibition must be the predominant mechanism in establishing an electron flow.


Water ◽  
2021 ◽  
Vol 13 (18) ◽  
pp. 2484
Author(s):  
César Huiliñir ◽  
Vivian Fuentes ◽  
Carolina Estuardo ◽  
Christian Antileo ◽  
Ernesto Pino-Cortés

This work aimed to achieve partial nitrification (PN) in a Sequencing Moving Bed Biofilm Reactor SMBBR with zeolite as a biomass carrier by using sulfide pulses in the presence of organic matter as an inhibitor. Two conditions were evaluated: sulfide (HS−) = 5 mg S/L and vvm (air volume per liquid volume per minute, L of air L−1 of liquid min−1) = 0.1 (condition 1); and a HS− = 10 mg S/L and a vvm = 0.5 (condition 2). The simultaneous effect of organic matter and sulfide was evaluated at a Chemical Oxygen Demand (COD) = 350 mg/L and HS− = 5 mg S/L, with a vvm = 0.5. As a result, using the sulfide pulse improved the nitrite accumulation in both systems. However, Total Ammonia Nitrogen (TAN) oxidation in both processes decreased by up to 60%. The simultaneous presence of COD and sulfide significantly reduced the TAN and nitrite oxidation, with a COD removal yield of 80% and sulfide oxidation close to 20%. Thus, the use of a sulfide pulse enabled PN in a SMBBR with zeolite. Organic matter, together with the sulfide pulse, almost completely inhibited the nitrification process despite using zeolite.


1994 ◽  
Vol 30 (10) ◽  
pp. 179-187 ◽  
Author(s):  
I. T. Miettinen ◽  
P. J. Martikainen ◽  
T. Vartiainen

Transformations in the amount and quality of organic matter (humus) during bank filtration of surface water were studied by analyzing the changes in total organic carbon (TOC), non-purgeable organic carbon (NPOC), chemical oxygen demand (COD), color of water, and UV absorbing humus fractions. The amount of organic matter expressed as TOC, NPOC, and COD depended on temperature and filtration distance from lake water. The color of water and the UV absorbing humus peaks presenting different humus molecule fractions decreased more effectively than other parameters measuring the amount of organic matter in water. The ratio of COD to TOC decreased when the filtration distance of water increased. Our observations indicated that bank filtration of humus-rich lake water changed more the quality of organic matter than its total amount.


1988 ◽  
Vol 20 (1) ◽  
pp. 161-170 ◽  
Author(s):  
O. Milstein ◽  
A. Haars ◽  
A. Majcherczyk ◽  
J. Trojanowski ◽  
D. Tautz ◽  
...  

Organic matter from spent bleaching effluents (from chlorination (C) or extraction (E) stages, or a mixture of both) was effectively precipitated as a water insoluble complex with polyethyleneimine (polyimine). Precipitation was performed in a pilot unit operating automatically. The colour, chemical oxygen demand (COD), and adsorbable organic halogens (AOX) were reduced in the C-effluent by up to 92%, 65%, and 84%, respectively. Regarding the E-stage effluent, reduction was up to 76% for colour, 70% for COD, and 73% for AOX. No significant reduction of BOD5 was observed in the supernatant of the treated effluent. Fish toxicity was greatly reduced. Laccase increased the molecular weight of the effluent constituents, thus facilitating subsequent precipitation. After treatment with laccase, the bulk of mono- and dichlorophenol is coprecipitated with the liquors from the C and E bleaching stages. Fungi (representatives of the genera Aspergillus and Penicillium) achieved an appreciable level of degradation of chlorophenols and other chloroorganic compounds from the bleaching effluent.


2000 ◽  
Vol 42 (12) ◽  
pp. 65-72 ◽  
Author(s):  
H.-S. Shin ◽  
S.-Y. Nam

A separate sludge system incorporating sequencing batch reactor (SBR) for sequestered denitrification and an immobilized fixed-film reactor for nitrification was investigated in this study. Emphases were placed on the preservation of organic matter as an electron donor for denitrification and the improvement of nitrification efficiency by using an immobilization technique with alginate coating. To preserve organic materials in the sludge required for denitrification, a study was made with a contact process. The contactor, when operated with a short detention time, gave incomplete metabolism of organic matter. With 64% of the influent soluble chemical oxygen demand (SCOD) was adsorbed to activated sludge within 30 min. The specific mass of organic matter uptaken was 55 mg SCOD/g mixed liquor suspended solids (MLSS), which enhanced the denitrification efficiency up to 63% in the following denitrification step. Thus, the required COD in the proposed system can be saved up to 63% as an available electron donor for the conventional aerobic process. The immobilized nitrification unit showed over 90% of nitrate production rate up to 50 mg/l of influent ammonia load.


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