scholarly journals Thermodynamic property values for gaseous and liquid carbon monoxide from 70 to 300* K with pressures to 300 atmospheres

Author(s):  
J G Hust
1986 ◽  
Vol 33 (5) ◽  
pp. 3441-3447 ◽  
Author(s):  
Pier Francesco Fracassi ◽  
Gianni Cardini ◽  
Séamus O’Shea ◽  
Roger W. Impey ◽  
Michael L. Klein

1988 ◽  
Vol 66 (5) ◽  
pp. 1304-1312
Author(s):  
G. Ramanan ◽  
Gordon R. Freeman

Electron thermalization in X irradiated liquid CO is truncated by electron capture to form an anion, as it is in liquid N2. The thermalization distance distribution in these two liquids is a modified exponential, rather than the modified Gaussian obtained in liquid hydrocarbons where electron capture does not occur. The density normalized distance parameter bEPd in CO was constant, 2.8 × 10−6 kg/m2, at densities [Formula: see text], but increased somewhat at lower densities, reaching 3.3 × 10−6 kg/m2 at d/dc = 1.4. The thermalization distances in CO are about two thirds those in N2 at the same density. Electrons are captured more readily by CO than by N2.


1967 ◽  
Vol 22 (6) ◽  
pp. 954-960
Author(s):  
H. W. Buschmann ◽  
W. Groth

The radiation chemistry of liquid carbon monoxide at —196°C and mixtures of CO with various gases has been investigated. In the γ-radiolysis of pure CO CO2 is formed with G(CO2) =0.18. The addition of CH4, C2H4, O2, and NO leads to the formation of C3O2 which is not observed in the γ-radiolysis of pure CO.In the case of CO—CH4 mixtures the following reacting products were identified: C2H6, C2H2, H2CO, H2C2O (Ketene), CO2 and C3O2. Results of experiments with CO —CH4 —13CH4 and CO—CH4—CD4 mixtures and measurements of the dependence of G(CO2), G(C3O2), G(C2H2) and G (C2H6) on the concentration of CH4 have shown that ethane is formed by energy transfer from CO to CH4 or by reaction of CH4 with excited CO and that C3O2 and C2H2 are formed by reaction of free carbon atoms which are formed in the presence of methane.


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