scholarly journals Acid-base equilibrium constant and dipole moment of tribenzylammonium picrate in benzene from measurements of dielectric constant

1948 ◽  
Vol 41 (1) ◽  
pp. 7 ◽  
Author(s):  
Arthur A. Maryott
1965 ◽  
Vol 18 (6) ◽  
pp. 801 ◽  
Author(s):  
RJL Martin

In acetic acid at 105.7� acetamidium perchlorate has an ionic association constant KA = 0.0491 x 106 l. mole-1, a limiting equivalent conductivity A, = 79.4 cm2 Ω-1 equiv.-1, and a centre-to-centre distance between the ions � = 4.67 Ǻ. The acid-base equilibrium constant for acetamidium acetate KB = [ΣNH3Ac+ OAc-]/ [NH2Ac] increases slightly with increasing dielectric constant.


1965 ◽  
Vol 18 (3) ◽  
pp. 321 ◽  
Author(s):  
RJL Martin

In aqueous acetic acid, 0.114-0.152M H2O, at 105.7�, oxonium perchlorate has limiting equivalent conductivity Λ0 90.7, ionic association constant KA = [H3O+ClO4-]/[H3O+][ClO4]f2 = 0.0310 x 106 and centre-to-centre distance between the ions (� = 4.84 Ǻ. The acid-base equilibrium constant for oxonium acetate KB = [ΣH3O+ OAc-]/[H2O] increases with the dielectric constant so that -log KB = 1.532+29.44/D. The autoprotolysis of acetic acid also increases with the dielectric constant.


2000 ◽  
Vol 11 (12) ◽  
pp. 25 ◽  
Author(s):  
Anderson S. L. Gomes ◽  
Cid B. de Araújo ◽  
Renato E. de Araujo ◽  
Arandi G. Bezerra, Jr. ◽  
Iouri E. Borissevitch.

1942 ◽  
Vol 144 (2) ◽  
pp. 529-535
Author(s):  
Frank C. d'Elseaux ◽  
Frances C. Blackwood ◽  
Lucille E. Palmer ◽  
Katherine G. Sloman

1931 ◽  
Vol 90 (2) ◽  
pp. 607-617
Author(s):  
Edward Muntwyler ◽  
Natalie Limbach ◽  
Arthur H. Bill ◽  
Victor C. Myers

1926 ◽  
Vol 67 (1) ◽  
pp. 175-218
Author(s):  
John P. Peters ◽  
Harold A. Bulger ◽  
Anna J. Eisenman ◽  
Carter Lee

1926 ◽  
Vol 67 (1) ◽  
pp. 165-173 ◽  
Author(s):  
John P. Peters ◽  
Harold A. Bulger ◽  
Anna J. Eisenman

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