scholarly journals Intermolecular Halogen Bonding-Controlled Self-Assembly of Hydrogen Bonded Aromatic Amide Foldamers

2021 ◽  
Vol 41 (7) ◽  
pp. 2848
Author(s):  
Yanyan Xu ◽  
Chuanzhi Liu ◽  
Hui Wang ◽  
Danwei Zhang ◽  
Zhanting Li
Keyword(s):  
Self Assembly ◽  
Halogen Bonding ◽  
Aromatic Amide ◽  
Hydrogen Bonded

Halogen and hydrogen bonding-driven self-assembly of supramolecular macrocycles and double helices from hydrogen-bonded arylamide foldamers

CrystEngComm ◽  
2019 ◽  
Vol 21 (16) ◽  
pp. 2626-2630 ◽  
Author(s):  
Satish Koppireddi ◽  
Chuan-Zhi Liu ◽  
Hui Wang ◽  
Dan-Wei Zhang ◽  
Zhan-Ting Li
Keyword(s):  
Hydrogen Bonding ◽  
Self Assembly ◽  
Halogen Bonding ◽  
Double Helices ◽  
Aromatic Amide ◽  
Arylamide Foldamers ◽  
Hydrogen Bonded

Halogen bonding has been used to hold hydrogen bonded short aromatic amide foldamers to form 2 + 2 or 1 + 1 macrocycles.

scholarly journals Halogen Bonding in Bicomponent Monolayers: Self-Assembly of a Homologous Series of Iodinated Perfluoroalkanes with Bipyridine

Langmuir ◽  
2021 ◽  
Author(s):  
Jonathan A. Davidson ◽  
Marco Sacchi ◽  
Fabrice Gorrec ◽  
Stuart M. Clarke ◽  
Stephen J. Jenkins
Keyword(s):  
Self Assembly ◽  
Homologous Series ◽  
Halogen Bonding

scholarly journals Synthesis of microporous hydrogen-bonded supramolecular organic frameworks through guanosine self-assembly

2021 ◽  
pp. 100519
Author(s):  
Ying He ◽  
Yanbin Zhang ◽  
Mengjia Liu ◽  
Kai Zhao ◽  
Chuan Shan ◽  
...  
Keyword(s):  
Self Assembly ◽  
Hydrogen Bonded

scholarly journals Taming nitroformate through encapsulation with nitrogen-rich hydrogen-bonded organic frameworks

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Jichuan Zhang ◽  
Yongan Feng ◽  
Richard J. Staples ◽  
Jiaheng Zhang ◽  
Jean’ne M. Shreeve
Keyword(s):  
Thermal Stability ◽  
Hydrogen Bonds ◽  
Self Assembly ◽  
Energetic Materials ◽  
Decomposition Temperature ◽  
High Oxygen Content ◽  
The Poor ◽  
Simple Preparation ◽  
First Time ◽  
Hydrogen Bonded

AbstractOwing to its simple preparation and high oxygen content, nitroformate [−C(NO2)3, NF] is an extremely attractive oxidant component for propellants and explosives. However, the poor thermostability of NF-based derivatives has been an unconquerable barrier for more than 150 years, thus hindering its application. In this study, the first example of a nitrogen-rich hydrogen-bonded organic framework (HOF-NF) is designed and constructed through self-assembly in energetic materials, in which NF anions are trapped in pores of the resulting framework via the dual force of ionic and hydrogen bonds from the strengthened framework. These factors lead to the decomposition temperature of the resulting HOF-NF moiety being 200 °C, which exceeds the challenge of thermal stability over 180 °C for the first time among NF-based compounds. A large number of NF-based compounds with high stabilities and excellent properties can be designed and synthesized on the basis of this work.

Effects of the position and number of bromine substituents on the concentration-mediated 2D self-assembly of phenanthrene derivatives

2016 ◽  
Vol 18 (10) ◽  
pp. 7208-7215 ◽  
Author(s):  
Xingyu Hu ◽  
Bao Zha ◽  
Yican Wu ◽  
Xinrui Miao ◽  
Wenli Deng
Keyword(s):  
Self Assembly ◽  
Driving Force ◽  
Halogen Bonding ◽  
The Self

Br⋯Br halogen bonding exists in the self-assembly of 2,7-DBHP, whereas the driving force for the assembly of 3,6-DBHP is Br⋯Br vdWs type interactions.

Chemical and Constitutional Influences in the Self-Assembly of Functional Supramolecular Hydrogen-Bonded Nanoscopic Fibres

2006 ◽  
Vol 12 (36) ◽  
pp. 9161-9175 ◽  
Author(s):  
Josep Puigmartí-Luis ◽  
Andrea Minoia ◽  
Ángel Pérez del Pino ◽  
Gregori Ujaque ◽  
Concepció Rovira ◽  
...  
Keyword(s):  
Self Assembly ◽  
The Self ◽  
Hydrogen Bonded

Controllable Orientation of Ester-Group-Induced Intermolecular Halogen Bonding in a 2D Self-Assembly

2016 ◽  
Vol 7 (16) ◽  
pp. 3164-3170 ◽  
Author(s):  
Bao Zha ◽  
Meiqiu Dong ◽  
Xinrui Miao ◽  
Kai Miao ◽  
Yi Hu ◽  
...  
Keyword(s):  
Self Assembly ◽  
Halogen Bonding ◽  
Ester Group

Halogen Bonding Directed Supramolecular Quadruple and Double Helices from Hydrogen-Bonded Arylamide Foldamers

2018 ◽  
Vol 58 (1) ◽  
pp. 226-230 ◽  
Author(s):  
Chuan-Zhi Liu ◽  
Satish Koppireddi ◽  
Hui Wang ◽  
Dan-Wei Zhang ◽  
Zhan-Ting Li
Keyword(s):  
Halogen Bonding ◽  
Double Helices ◽  
Arylamide Foldamers ◽  
Hydrogen Bonded

Cyclic networks of halogen-bonding interactions in molecular self-assemblies: a theoretical N—X...NversusC—X...N investigation

2017 ◽  
Vol 73 (2) ◽  
pp. 179-187
Author(s):  
Ruben D. Parra ◽  
Álvaro Castillo
Keyword(s):  
Electron Density ◽  
Self Assembly ◽  
Metal Ion ◽  
Halogen Atom ◽  
Halogen Bond ◽  
Halogen Bonding ◽  
Nbo Analysis ◽  
Binding Energies ◽  
Cyclic Network ◽  
Ability To Drive

The geometries and energetics of molecular self-assembly structures that contain a sequential network of cyclic halogen-bonding interactions are investigated theoretically. The strength of the halogen-bonding interactions is assessed by examining binding energies, electron charge transfer (NBO analysis) and electron density at halogen-bond critical points (AIM theory). Specifically, structural motifs having intramolecular N—X...N (X= Cl, Br, or I) interactions and the ability to drive molecular self-assemblyviathe same type of interactions are used to construct larger self-assemblies of up to three unit motifs. N—X...N halogen-bond cooperativity as a function of the self-assembly size, and the nature of the halogen atom is also examined. The cyclic network of the halogen-bonding interactions provides a suitable cavity rich in electron density (from the halogen atom lone pairs not involved in the halogen bonds) that can potentially bind an electron-deficient species such as a metal ion. This possibility is explored by examining the ability of the N—X...N network to bind Na+. Likewise, molecular self-assembly structures driven by the weaker C—X...N halogen-bonding interactions are investigated and the results compared with those of their N—X...N counterparts.

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