Stabilizing Catalytic Pt-OH-Fe(III) Interfaces by Mesoporous TiO2 with Rich Surface Hydroxyl Groups

2018 ◽  
Vol 76 (8) ◽  
pp. 617 ◽  
Author(s):  
Qingyuan Wu ◽  
Ruixuan Qin ◽  
Dandan Zang ◽  
Wuyong Zhang ◽  
Binghui Wu ◽  
...  
CrystEngComm ◽  
2020 ◽  
Vol 22 (5) ◽  
pp. 969-978 ◽  
Author(s):  
Li Li ◽  
Liang Wang ◽  
Xinhong Chen ◽  
Changyuan Tao ◽  
Jun Du ◽  
...  

Bayberry-like mesoporous TiO2 hydrophilic films with high surface roughness and high density of surface hydroxyl groups.


1986 ◽  
Vol 51 (7) ◽  
pp. 1430-1438 ◽  
Author(s):  
Alena Reissová ◽  
Zdeněk Bastl ◽  
Martin Čapka

The title complexes have been obtained by functionalization of silica with cyclopentadienylsilanes of the type Rx(CH3)3 - xSi(CH2)nC5H5 (x = 1-3, n = 0, 1, 3), trimethylsilylation of free surface hydroxyl groups, transformation of the bonded cyclopentadienyl group to the cyclopentadienyl anion, followed by coordination of (h5-cyclopentadienyl)trichlorotitanium. The effects of single steps of the above immobilization on texture of the support, the number of free hydroxyl groups, the coverage of the surface by cyclopentadienyl groups and the degree of their utilization in anchoring the titanium complex have been investigated. ESCA study has shown that the above anchoring leads to formation of the silica-supported bis(h5-cyclopentadienyl)dichlorotitanium(IV) complex.


RSC Advances ◽  
2015 ◽  
Vol 5 (121) ◽  
pp. 99712-99721 ◽  
Author(s):  
Yan Li ◽  
Yawen Wang ◽  
Yu Huang ◽  
Junji Cao ◽  
Wingkei Ho ◽  
...  

Surface modification by phosphate efficiently improves the photocatalytic performance of BiPO4 for the degradation of methylene orange (MO), by enhancing the concentration of surface hydroxyl groups and improving its hydrophilicity.


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