scholarly journals Akbari-Ganjis method AGM to chemical reactor design for non-isothermal and non-adiabatic of mixed flow reactors

2020 ◽  
Vol 11 (1) ◽  
pp. 1-9
Author(s):  
R. Akbari M. ◽  
Akbari Sara ◽  
Kalantari Esmaeil ◽  
D. Ganji D.
Keyword(s):  
Chemical Reactor ◽  
Reactor Design ◽  
Mixed Flow ◽  
Flow Reactors

Reactor Design for Complex Reactions

2001 ◽  
Author(s):  
L. K. Doraiswamy
Keyword(s):  
Batch Reactor ◽  
Plug Flow ◽  
Reaction Network ◽  
Reactor Design ◽  
Batch Reactors ◽  
Complex Reaction ◽  
Mixed Flow ◽  
Flow Reactors ◽  
Design Procedures ◽  
Reactor Types

Procedures were formulated in Chapter 5 for treating complex reactions. We now turn to the design of reactors for such reactions. Continuing with the ethylation reaction, we consider the following reactor types for which design procedures were formulated earlier in Chapter 4 for simple reactions: batch reactors, continuous stirred reactors (or mixed-flow reactors), and plug-flow reactors. However, we use the following less formal nomenclature: A = aniline, B = ethanol, C = monoethyaniline, D = water, E = diethylaniline, F = diethyl ether, and G = ethylene. The four independent reactions then become Using this set of equations as the basis, we now formulate design equations for various reactor types. Detailed expositions of the theory are presented in a number of books, in particular Aris (1965, 1969) and Nauman (1987). Consider a reaction network consisting of N components and M reactions. A set of N ordinary differential equations, one for each component, would be necessary to mathematically describe this system. They may be concisely expressed in the form of Equation 5.5 (Chapter 5), or . . . d(cV)/dt = vrV (11.1) . . . The use of this equation in developing batch reactor equations for a typical complex reaction is illustrated in Example 11.1.

The effect of aqueous sulphate on basaltic glass dissolution rates

2008 ◽  
Vol 72 (1) ◽  
pp. 39-41 ◽  
Author(s):  
T. K. Flaathen ◽  
E. H. Oelkers ◽  
S. Gislason
Keyword(s):  
Steady State ◽  
Rate Equation ◽  
Rate Increase ◽  
Basaltic Glass ◽  
Mixed Flow ◽  
Dissolution Rates ◽  
Flow Reactors ◽  
Glass Dissolution ◽  
Sulphate Concentration

AbstractSteady-state dissolution rates of basaltic glass were measured in mixed-flow reactors at 50ºC at pH 3 and 4 as a function of aqueous sulphate concentration. Dissolution rates in the presence of 0.1 moles/kg SO42- were found to be ~3 times greater than those in corresponding SO42- free solutions. This rate increase is found to be approximately consistent with that calculated using a rate equation previously proposed by Gislason and Oelkers (2003). These results suggest that the addition of sulphate to injected CO2 may facilitate CO2 sequestration in basalts by accelerating basaltic glass dissolution rates thus more rapidly releasing aqueous Ca and Mg to solution.

Chemical reactor design

1988 ◽  
Vol 43 (10) ◽  
pp. 2911
Author(s):  
L.G. Gibilaro
Keyword(s):  
Chemical Reactor ◽  
Reactor Design

Macro- to nanoscale study of the effect of aqueous sulphate on calcite growth

2008 ◽  
Vol 72 (1) ◽  
pp. 141-144 ◽  
Author(s):  
A. I. Vavouraki ◽  
C. V. Putnis ◽  
A. Putnis ◽  
E. H. Oelkers ◽  
P. G. Koutsoukos
Keyword(s):  
Atomic Force Microscopy ◽  
Growth Rates ◽  
Kinetics And Mechanism ◽  
Two Dimensional ◽  
Mixed Flow ◽  
Flow Reactors ◽  
Force Microscopy ◽  
Atomic Force

AbstractCalcite growth rates were measured in the presence of sulphate using mixed-flow reactors and in situ Atomic Force Microscopy. Preliminary observations reveal that the kinetics and mechanism of the calcite growth was altered by the presence of sulphate. Calcite growth rates in the presence of sulphate (≥ mM) were decreased and two-dimensional nuclei tend to grow on top of existing nuclei, rather than spreading. The height of new nuclei was ~4 Å, 1 Å greater than that of pure calcite growth. This difference reflects the incorporation of tetrahedral SO2-4 anions into the calcite lattice.

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