scholarly journals A selective colorimetric chemosensor for detection of Cu(II) ions in aqueous samples

2021 ◽  
Vol 24 (3) ◽  
pp. 385-396
Author(s):  
Cristián Alejandro Ferretti ◽  
Leandro Gabriel Gutierrez ◽  
Vanina Alejandra Guntero ◽  
Pablo Javier Noriega ◽  
María Nelida Kneeteman
Keyword(s):  
Aqueous Samples ◽  
Colorimetric Chemosensor

scholarly journals A Deferasirox Derivative That Acts as a Multifaceted Platform for the Detection and Quantification of Fe3+

Chemosensors ◽  
2021 ◽  
Vol 9 (4) ◽  
pp. 68
Author(s):  
Axel Steinbrueck ◽  
Adam C. Sedgwick ◽  
Suh-Mi Hwang ◽  
Sajal Sen ◽  
Michael Y. Zhao ◽  
...  
Keyword(s):  
Human Serum Albumin ◽  
Serum Albumin ◽  
Human Serum ◽  
Metal Cation ◽  
Iron Chelator ◽  
Water Soluble ◽  
Aqueous Samples ◽  
Colorimetric Chemosensor ◽  
Turn On ◽  
Detection And Quantification

Here, we report that ExSO3H, a synthetically accessible, water-soluble, non-toxic derivative of the clinical iron chelator deferasirox, acts as a colorimetric chemosensor that permits the detection and quantification of Fe3+ in aqueous samples at pH 2–5. In addition, we observed that a fluorescent turn-on response was produced when this chelator was allowed to interact with human serum albumin (HSA). This fluorescence was quenched in the presence of Fe3+, thus allowing us to monitor the presence of this biologically important metal cation via two independent methods.

Preliminary study on removal of nitrate nitrogen in aqueous samples by microbial nano-silica ball

2014 ◽  
Author(s):  
Jia Lu ◽  
Xiaohou Shao ◽  
Chao Yin ◽  
Xinyu Mao ◽  
Long Wang ◽  
...  
Keyword(s):  
Nitrate Nitrogen ◽  
Aqueous Samples ◽  
Nano Silica ◽  
Preliminary Study

Development of Synchrotron Footprinting at NSLS and NSLS-II

2019 ◽  
Vol 26 (1) ◽  
pp. 55-60 ◽  
Author(s):  
Jen Bohon
Keyword(s):  
Solvent Accessibility ◽  
Biological Systems ◽  
In Vivo Studies ◽  
Aqueous Samples ◽  
Biological Mechanisms ◽  
Macromolecular Assembly ◽  
Structure And Dynamics ◽  
Synchrotron Light ◽  
Ideal Technique

Background: First developed in the 1990’s at the National Synchrotron Light Source, xray synchrotron footprinting is an ideal technique for the analysis of solution-state structure and dynamics of macromolecules. Hydroxyl radicals generated in aqueous samples by intense x-ray beams serve as fine probes of solvent accessibility, rapidly and irreversibly reacting with solvent exposed residues to provide a “snapshot” of the sample state at the time of exposure. Over the last few decades, improvements in instrumentation to expand the technology have continuously pushed the boundaries of biological systems that can be studied using the technique. Conclusion: Dedicated synchrotron beamlines provide important resources for examining fundamental biological mechanisms of folding, ligand binding, catalysis, transcription, translation, and macromolecular assembly. The legacy of synchrotron footprinting at NSLS has led to significant improvement in our understanding of many biological systems, from identifying key structural components in enzymes and transporters to in vivo studies of ribosome assembly. This work continues at the XFP (17-BM) beamline at NSLS-II and facilities at ALS, which are currently accepting proposals for use.

Novel palladium(II) selective membrane electrode based on 4-[(5-mercapto-1,3,4-thiadiazol-2-ylimino)methyl]benzene-1,3-diol

2010 ◽  
Vol 75 (5) ◽  
pp. 563-575 ◽  
Author(s):  
Moslem Mohammadi ◽  
Mehdi Khodadadian ◽  
Mohammad K. Rofouei
Keyword(s):  
Limit Of Detection ◽  
Membrane Electrode ◽  
Aqueous Samples ◽  
Selective Determination ◽  
Poly Vinyl Chloride ◽  
Selective Membrane ◽  
Ph Range ◽  
Palladium Content ◽  
Methyl Benzene

A plasticized poly(vinyl chloride) membrane electrode based on 4-[(5-mercapto-1,3,4-thiadiazol-2-ylimino)methyl]benzene-1,3-diol (L) for highly selective determination of palladium(II) (in PdCl42– form) is developed. The electrode showed a good Nernstian response (29.6 ± 0.4 mV per decade) over a wide concentration range (3.1 × 10–7 to 1.0 × 10–2 mol l–1). The limit of detection was 1.5 × 10–7 mol l–1. The electrode has a response time of about 20 s, and it can be used for at least 2 months without observing any considerable deviation from Nernstian response. The proposed electrode could be used in the pH range of 2.5–5.5. The practical utility of the electrode has been demonstrated by its use for the estimation of palladium content in aqueous samples.

scholarly journals Postprocedural Endophthalmitis or Postprocedural Intraocular Inflammation: A Diagnostic Conundrum

2021 ◽  
pp. 418-424
Author(s):  
Aisha Al Busaidi ◽  
Ahmed Al-Hinai
Keyword(s):  
Pars Plana Vitrectomy ◽  
Povidone Iodine ◽  
Complete Recovery ◽  
Neovascular Glaucoma ◽  
Intraocular Inflammation ◽  
Aqueous Samples ◽  
Patient Counseling ◽  
Pars Plana ◽  
Culture Negative ◽  
Office Procedures

We experienced an atypical endophthalmitis occurring post consecutively performed in-office procedures; an intravitreal injection (IVI) of ranibizumab followed by an anterior chamber (AC) paracentesis performed twice in an eye with neovascular glaucoma (NVG). A 52-year-old diabetic male who was asymptomatic developed signs of endophthalmitis and decreased vision without pain in his left eye a few days post-IVI and AC paracentesis. The condition worsened after an initial vitreous tap and injection of antibiotics. Cultures of vitreous and aqueous samples were negative. Complete resolution occurred after a pars plana vitrectomy with IVI of antibiotics and steroid with removal of a dense “yellowish-brown” fibrinous plaque. The absence of pain, presence of a peculiar colored fibrin, mild-to-moderate vitritis without retinitis, negative cultures, and complete recovery despite the fulminant presentation; favor a diagnosis of inflammation over infection. We hypothesize that a micro-leak from a 26-gauge AC tap tract might have served as an entry port for 5% povidone-iodine from the ocular surface thus inciting inflammation. However, an exuberant inflammatory response that can be typically seen in NVG eyes after intraocular procedures cannot be excluded. Various causes of inflammation post-procedures, both toxic and nontoxic should be considered in atypical culture-negative fulminant endophthalmitis cases with good outcome posttreatment. Any minor ocular procedure may carry a risk of such complication. Patient counseling and care must be exercised in performing these procedures.

Benzothiazole-based semisquaraine as colorimetric chemosensor for Hg2+

2009 ◽  
Vol 10 (3) ◽  
pp. 403-405 ◽  
Author(s):  
Jin-Seok Bae ◽  
Young-A Son ◽  
Sung-Hoon Kim
Keyword(s):  
Colorimetric Chemosensor

scholarly journals Modified Exfoliated Carbon Nanoplatelets as Sorbents for Ammonium from Natural Mineral Waters

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3541
Author(s):  
Ion Ion ◽  
Daniela Bogdan ◽  
Monica Maria Mincu ◽  
Alina Catrinel Ion
Keyword(s):  
Natural Waters ◽  
Mineral Waters ◽  
Aqueous Samples ◽  
Sorption Mechanism ◽  
Characteristic Parameters ◽  
Sorption Characteristic ◽  
Natural Mineral ◽  
Maximum Sorption Capacity ◽  
Ammonium Removal ◽  
Maximum Sorption

In this manuscript an improved sorbent based on modified exfoliated carbon nanoplatelets, applied in the removal of ammonium from aqueous samples, is presented. This sorbent showed better efficiency in comparison with the previous one obtained in our group for ammonium removal, the values of the maximum sorption capacity being improved from 10 to 12.04 mg/g. In terms of kinetics and sorption characteristic parameters, their values were also improved. Based on these results, a sorption mechanism was proposed, taking into account ion-exchange and chemisorption processes at the surface of the oxidized exfoliated carbon nanoplatelets. Future applications for simultaneous removal of other positive charged contaminants from natural waters might be possible.

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