scholarly journals Introducing an Approach to Effective Mass of Activated Complex

2018 ◽  
Author(s):  
Petr Ptáček ◽  
Tomáš Opravil ◽  
František Šoukal
Keyword(s):  
Effective Mass ◽  
Activated Complex

Adiabatic large polarons in anisotropic molecular crystals

2011 ◽  
Vol 35 (1) ◽  
pp. 15-27
Author(s):  
Zoran Ivić ◽  
Željko Pržulj
Keyword(s):  
Energy Transfer ◽  
Effective Mass ◽  
Molecular Crystals ◽  
Single Chain ◽  
Proper Understanding ◽  
One Dimensional ◽  
Interchain Coupling ◽  
Large Polaron ◽  
The One

Adiabatic large polarons in anisotropic molecular crystals We study the large polaron whose motion is confined to a single chain in a system composed of the collection of parallel molecular chains embedded in threedimensional lattice. It is found that the interchain coupling has a significant impact on the large polaron characteristics. In particular, its radius is quite larger while its effective mass is considerably lighter than that estimated within the one-dimensional models. We believe that our findings should be taken into account for the proper understanding of the possible role of large polarons in the charge and energy transfer in quasi-one-dimensional substances.

The Effect of p-Toluidine on the Two-Step Electroreduction of Zn(II) in Water-Methanol and Water-Dimethylformamide

1999 ◽  
Vol 64 (4) ◽  
pp. 585-594 ◽  
Author(s):  
Barbara Marczewska
Keyword(s):  
Electron Transfer ◽  
Binary Mixtures ◽  
Rate Constant ◽  
Rate Constants ◽  
Electrode Surface ◽  
Mercury Electrode ◽  
Forward Rate ◽  
Solvent Molecules ◽  
Activated Complex

The acceleration effect of p-toluidine on the electroreduction of Zn(II) on the mercury electrode surface in binary mixtures water-methanol and water-dimethylformamide is discussed. The obtained apparent and true forward rate constants of Zn(II) reduction indicate that the rate constant of the first electron transfer increases in the presence of p-toluidine. The acceleration effect may probably be accounted for by the concept of the formation on the mercury electrode an activated complex, presumably composed of p-toluidine and solvent molecules.

Bimolecular Reactions, Transition-State Theory

2018 ◽  
Author(s):  
Niels Engholm Henriksen ◽  
Flemming Yssing Hansen
Keyword(s):  
Transition State ◽  
Saddle Point ◽  
Transition State Theory ◽  
Classical Mechanics ◽  
Small Degree ◽  
State Theory ◽  
Reaction Coordinate ◽  
Partition Functions ◽  
Bimolecular Reactions ◽  
Activated Complex

This chapter discusses an approximate approach—transition-state theory—to the calculation of rate constants for bimolecular reactions. A reaction coordinate is identified from a normal-mode coordinate analysis of the activated complex, that is, the supermolecule on the saddle-point of the potential energy surface. Motion along this coordinate is treated by classical mechanics and recrossings of the saddle point from the product to the reactant side are neglected, leading to the result of conventional transition-state theory expressed in terms of relevant partition functions. Various alternative derivations are presented. Corrections that incorporate quantum mechanical tunnelling along the reaction coordinate are described. Tunnelling through an Eckart barrier is discussed and the approximate Wigner tunnelling correction factor is derived in the limit of a small degree of tunnelling. It concludes with applications of transition-state theory to, for example, the F + H2 reaction, and comparisons with results based on quasi-classical mechanics as well as exact quantum mechanics.

Three-terminal bistable switches in effective-mass superlattices

1988 ◽  
Vol 24 (1) ◽  
pp. 64-65 ◽  
Author(s):  
A. Aishima ◽  
Y. Fukushima
Keyword(s):  
Effective Mass

Effective masses in a dense fermion background — Applied to neutrinos, dark matter and dark energy

2014 ◽  
Vol 29 (21) ◽  
pp. 1444010
Author(s):  
Bruce H. J. McKellar ◽  
T. J. Goldman ◽  
G. J. Stephenson
Keyword(s):  
Dark Matter ◽  
Dark Energy ◽  
Scalar Field ◽  
Effective Mass ◽  
Negative Pressure ◽  
Expectation Value ◽  
Effective Masses ◽  
Neutrino Astrophysics

If fermions interact with a scalar field, and there are many fermions present the scalar field may develop an expectation value and generate an effective mass for the fermions. This can lead to the formation of fermion clusters, which could be relevant for neutrino astrophysics and for dark matter astrophysics. Because this system may exhibit negative pressure, it also leads to a model of dark energy.

On the lattice scattering and effective mass of holes in natural diamond

1979 ◽  
Vol 30 (6) ◽  
pp. 333-335 ◽  
Author(s):  
L. Reggiani ◽  
S. Bosi ◽  
C. Canali ◽  
F. Nava ◽  
S.F. Kozlov
Keyword(s):  
Effective Mass ◽  
Natural Diamond
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