scholarly journals Particle Deposition in Microfluidic Devices at Elevated Temperatures

Author(s):  
Zhibin Yan ◽  
Xiaoyang Huang ◽  
Chun Yang ◽  
Mingliang Jin ◽  
Lingling Shui
Membranes ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 316
Author(s):  
Izabella Bouhid de Aguiar ◽  
Karin Schroën

Membrane filtration processes are best known for their application in the water, oil, and gas sectors, but also in food production they play an eminent role. Filtration processes are known to suffer from a decrease in efficiency in time due to e.g., particle deposition, also known as fouling and pore blocking. Although these processes are not very well understood at a small scale, smart engineering approaches have been used to keep membrane processes running. Microfluidic devices have been increasingly applied to study membrane filtration processes and accommodate observation and understanding of the filtration process at different scales, from nanometer to millimeter and more. In combination with microscopes and high-speed imaging, microfluidic devices allow real time observation of filtration processes. In this review we will give a general introduction on microfluidic devices used to study membrane filtration behavior, followed by a discussion of how microfluidic devices can be used to understand current challenges. We will then discuss how increased knowledge on fundamental aspects of membrane filtration can help optimize existing processes, before wrapping up with an outlook on future prospects on the use of microfluidics within the field of membrane separation.


Author(s):  
J. S. Marshall

A multiple-time step discrete-element approach is presented for efficient computational modeling of the transport, collision and adhesion of small particles in microchannel flows. Adhesive particulates have been identified as a leading cause of failure in many different microfluidic devices, including those currently being developed by different research groups for rapid biological and chemical contaminant sensing, fluid drag reduction, etc. As these microfluidic devices enter into the marketplace and become more extensively used in field conditions, the importance of particle adhesion and clogging will increasingly limit the reliability of such systems. At a larger scale, clogging of vehicle radiators by small adhesive particles is currently a major problem for construction vehicles operating in certain environmental conditions and certain soil types. Cooling system fouling leads to the need for frequent maintenance and machine down time. Dust fouling of equipment is also of concern for potential human occupation on dusty planets, such as Mars. The discrete-element method presented in this paper is developed to enable efficient prediction of aggregate structure and breakup, for prediction of the effect of aggregate formation on the bulk fluid flow, and for prediction of the effects of small-scale flow features (e.g., due to surface roughness or lithographic patterning) on the aggregate formation and particle deposition. We present an overview of the computational structure and modeling assumptions, including models for various forces and torques present during particle-particle collisions. We then utilize the computational method to examine the physical processes involved in aggregate formation and capture of particulate aggregates by walls in microchannel flows.


2017 ◽  
Vol 140 (1) ◽  
Author(s):  
Zhibin Yan ◽  
Xiaoyang Huang ◽  
Chun Yang

Particulate fouling and particle deposition at elevated temperature are crucial issues in microchannel heat exchangers. In this work, a microfluidic system was designed to examine the hydrodynamic effects on the deposition of microparticles in a microchannel flow, which simulate particle deposits in microscale heat exchangers. The deposition rates of microparticles were measured in two typical types of flow, a steady flow and a pulsatile flow. Under a given elevated solution temperature and electrolyte concentration of the particle dispersion in the tested flow rate range, the dimensionless particle deposition rate (Sherwood number) was found to decrease with the Reynolds number of the steady flow and reach a plateau for the Reynolds number beyond 0.091. Based on the Derjaguin–Landau–Verwey–Overbeek (DLVO) theory, a mass transport model was developed with considering temperature dependence of the particle deposition at elevated temperatures. The modeling results can reasonably capture our experimental observations. Moreover, the experimental results of the pulsatile flow revealed that the particle deposition rate in the microchannel can be mitigated by increasing the frequency of pulsation within a low-frequency region. Our findings are expected to provide a better understanding of thermally driven particulate fouling as well as to provide useful information for design and operation of microchannel heat exchangers.


Author(s):  
N. M. P. Low ◽  
L. E. Brosselard

There has been considerable interest over the past several years in materials capable of converting infrared radiation to visible light by means of sequential excitation in two or more steps. Several rare-earth trifluorides (LaF3, YF3, GdF3, and LuF3) containing a small amount of other trivalent rare-earth ions (Yb3+ and Er3+, or Ho3+, or Tm3+) have been found to exhibit such phenomenon. The methods of preparation of these rare-earth fluorides in the crystalline solid form generally involve a co-precipitation process and a subsequent solid state reaction at elevated temperatures. This investigation was undertaken to examine the morphological features of both the precipitated and the thermally treated fluoride powders by both transmission and scanning electron microscopy.Rare-earth oxides of stoichiometric composition were dissolved in nitric acid and the mixed rare-earth fluoride was then coprecipitated out as fine granules by the addition of excess hydrofluoric acid. The precipitated rare-earth fluorides were washed with water, separated from the aqueous solution, and oven-dried.


Author(s):  
J. L. Brimhall ◽  
H. E. Kissinger ◽  
B. Mastel

Some information on the size and density of voids that develop in several high purity metals and alloys during irradiation with neutrons at elevated temperatures has been reported as a function of irradiation parameters. An area of particular interest is the nucleation and early growth stage of voids. It is the purpose of this paper to describe the microstructure in high purity nickel after irradiation to a very low but constant neutron exposure at three different temperatures.Annealed specimens of 99-997% pure nickel in the form of foils 75μ thick were irradiated in a capsule to a total fluence of 2.2 × 1019 n/cm2 (E > 1.0 MeV). The capsule consisted of three temperature zones maintained by heaters and monitored by thermocouples at 350, 400, and 450°C, respectively. The temperature was automatically dropped to 60°C while the reactor was down.


Author(s):  
Robert C. Rau ◽  
Robert L. Ladd

Recent studies have shown the presence of voids in several face-centered cubic metals after neutron irradiation at elevated temperatures. These voids were found when the irradiation temperature was above 0.3 Tm where Tm is the absolute melting point, and were ascribed to the agglomeration of lattice vacancies resulting from fast neutron generated displacement cascades. The present paper reports the existence of similar voids in the body-centered cubic metals tungsten and molybdenum.


Author(s):  
Ernest L. Hall ◽  
J. B. Vander Sande

The present paper describes research on the mechanical properties and related dislocation structure of CdTe, a II-VI semiconductor compound with a wide range of uses in electrical and optical devices. At room temperature CdTe exhibits little plasticity and at the same time relatively low strength and hardness. The mechanical behavior of CdTe was examined at elevated temperatures with the goal of understanding plastic flow in this material and eventually improving the room temperature properties. Several samples of single crystal CdTe of identical size and crystallographic orientation were deformed in compression at 300°C to various levels of total strain. A resolved shear stress vs. compressive glide strain curve (Figure la) was derived from the results of the tests and the knowledge of the sample orientation.


Author(s):  
Afzana Anwer ◽  
S. Eilidh Bedford ◽  
Richard J. Spontak ◽  
Alan H. Windle

Random copolyesters composed of wholly aromatic monomers such as p-oxybenzoate (B) and 2,6-oxynaphthoate (N) are known to exhibit liquid crystalline characteristics at elevated temperatures and over a broad composition range. Previous studies employing techniques such as X-ray diffractometry (XRD) and differential scanning calorimetry (DSC) have conclusively proven that these thermotropic copolymers can possess a significant crystalline fraction, depending on molecular characteristics and processing history, despite the fact that the copolymer chains possess random intramolecular sequencing. Consequently, the nature of the crystalline structure that develops when these materials are processed in their mesophases and subsequently annealed has recently received considerable attention. A model that has been consistent with all experimental observations involves the Non-Periodic Layer (NPL) crystallite, which occurs when identical monomer sequences enter into register between adjacent chains. The objective of this work is to employ electron microscopy to identify and characterize these crystallites.


Author(s):  
C. W. Allen ◽  
D. L. Kuruzar

The rare earth/transition element intermetallics R2T17 are essentially topologically close packed phases for which layer structure models have already been presented. Many of these compounds are known to undergo allotropic transformation of the type at elevated temperatures. It is not unexpected that shear transformation mechanisms are involved in view of the layering character of the structures. The transformations are evidently quite sluggish, illustrated in furnace cooled Dy2Co17 by the fact that only rarely has the low temperature rhombohedral form been seen. The more usual structures observed so far in furnace cooled alloys include 4H and 6H in Dy2Co17 (Figs. 1 and 2) . In any event it is quite clear that the general microstructure is very complicated as a consequence of the allotropy, illustrated in Fig. 3. Numerous planar defects in the layer plane orientation are evident as are non-layer plane defects inherited from a high temperature structure.


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