scholarly journals Properties and Catalytic Effects of Nanoparticles Synthesized by Levitational Gas Condensation

Author(s):  
Young Rang Uhm
1995 ◽  
Vol 10 (5) ◽  
pp. 1115-1119 ◽  
Author(s):  
Hong-Ming Lin ◽  
Chiun-Yen Tung ◽  
Chi-Ming Hsu ◽  
Pee-Yew Lee

The gas-condensation technique is used to produce the nanocrystalline (NC) WO3−x, Pt/WO3−x, and Pd/WO3−x powders under different atmosphere and pressure. HRTEM images show that a coherently bonded interface exists between Pt or Pd and WO3−x. The nanocrystal WO3−x, Pt/WO3−x, and Pd/WO3−x grow into a needle shape with a plate inside when these as-evaporated powders are compacted and sintered at 900 °C for 2 h. The plate grows preferentially in {220} plane along the 〈0011〉 direction. However, the mean particle size of nanophase Pt and Pd increases only from <10 nm to 30 nm and 50 nm, respectively. The results of CO oxidation show that nanophase Pt/WO3−x powders have better catalytic effects on converting CO to CO2 than nanophase WO3−x and Pd/WO3−x powders.


1994 ◽  
Vol 351 ◽  
Author(s):  
Chiun-Yen Tung ◽  
Hong-Ming Lin ◽  
Chi-Ming Hsu ◽  
Chao-Cheng Yang

ABSTRACTThe gas-condensation technique is used to produce the nanocrystalline WO3−C, Pt/WO3−X and Pd/WO3−X powders under different atmospheres and pressures. High resolution electron microscope shows there exists well bonded interface between Pt or Pd and WO3−X The WO3−X, Pt/WO3−X and Pd/WO3−x nanocrystals grow into needle shape with plate inside when these asevaporated powders are compacted and sintered at 900 °C for two hours. The plate grows preferentially in {220) plane along < 001 > direction. However, the mean particle size of nanophase Pt and Pd only increases from less than 10 nm to 30 nm and 50 nm, respectively. The gas chromatography results show that nanophase Pt/VO3−X powders have better catalytic effects in converting CO to CO2 than nanophase WO3−X and Pd/WO3−X powders.


1984 ◽  
Vol 49 (3) ◽  
pp. 673-679 ◽  
Author(s):  
Pavel Lederer ◽  
Eva Mácová ◽  
Josef Vepřek-Šiška

The decomposition of peroxobenzoic acid in benzene was studied, and catalytic effects of Fe(III), Mn(III), Co(II), Co(III), and Cr(III) on the reaction rate and the composition of the reaction mixture were investigated. An analogous experiment carried out in perdeuterobenzene and determination of the distribution of deuterium in the reaction products provided evidence for the participation of the solvent in peroxobenzoic acid decomposition.


2021 ◽  
Vol 502 (1) ◽  
pp. 1263-1278
Author(s):  
Richard Kooij ◽  
Asger Grønnow ◽  
Filippo Fraternali

ABSTRACT The large temperature difference between cold gas clouds around galaxies and the hot haloes that they are moving through suggests that thermal conduction could play an important role in the circumgalactic medium. However, thermal conduction in the presence of a magnetic field is highly anisotropic, being strongly suppressed in the direction perpendicular to the magnetic field lines. This is commonly modelled by using a simple prescription that assumes that thermal conduction is isotropic at a certain efficiency f &lt; 1, but its precise value is largely unconstrained. We investigate the efficiency of thermal conduction by comparing the evolution of 3D hydrodynamical (HD) simulations of cold clouds moving through a hot medium, using artificially suppressed isotropic thermal conduction (with f), against 3D magnetohydrodynamical (MHD) simulations with (true) anisotropic thermal conduction. Our main diagnostic is the time evolution of the amount of cold gas in conditions representative of the lower (close to the disc) circumgalactic medium of a Milky-Way-like galaxy. We find that in almost every HD and MHD run, the amount of cold gas increases with time, indicating that hot gas condensation is an important phenomenon that can contribute to gas accretion on to galaxies. For the most realistic orientations of the magnetic field with respect to the cloud motion we find that f is in the range 0.03–0.15. Thermal conduction is thus always highly suppressed, but its effect on the cloud evolution is generally not negligible.


Langmuir ◽  
1995 ◽  
Vol 11 (5) ◽  
pp. 1477-1481
Author(s):  
Teruyo Yamashita ◽  
Miyuki Yamasaki ◽  
Takayuki Sano ◽  
Shoji Harada ◽  
Hiroshige Yano

2008 ◽  
Vol 22 (4) ◽  
pp. 2341-2345 ◽  
Author(s):  
Hongcang Zhou ◽  
Yan Cao ◽  
Houyin Zhao ◽  
Hongying Liu ◽  
Wei-Ping Pan

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