scholarly journals Gluconates as Corrosion Inhibitor of Aluminum in Various Corrosive Media

Author(s):  
Omotayo Sanni ◽  
Abimbola Patricia Popoola
2020 ◽  
Vol 4 (1) ◽  
pp. 7
Author(s):  
Ayu Ratna Permanasari ◽  
Tri Reksa Saputra ◽  
Aprillia Nurul’Aina ◽  
Salma Liska

Peralatan industri dari baja karbon yang berkontak langsung dengan lingkungan lama kelamaan akan terkorosi. Laju korosi dapat diperlambat menggunakan inhibitor organik senyawa tanin dari pohon akasia. Tanin diperoleh dari proses ekstraksi menggunakan metanol dan etanol. Tujuan dari penelitian ini adalah menentukan pelarut terbaik dalam proses ekstraksi kulit kayu akasia berdasarkan kandungan tanin terbesar serta mempelajari pengaruh tanin sebagai inhibitor korosi pada baja karbon dalam media korosif melalui metode pengurangan berat. Proses ekstraksi menggunakan metode maserasi pada suhu ruang selama dua jam dengan perbandingan padatan:pelarut adalah 1:10. Pelarut yang digunakan adalah etanol dan metanol. Ekstrak dievaporasi dalam rotary evaporator pada suhu 50 oC, tekanan 100 mbar hingga membentuk pasta. Ekstrak kulit kayu ditambahkan sebagai inhibitor dalam media korosif H2SO4 0,5 M; HCl 0,5 M; air laut, dan air tanah dengan penambahan konsentrasi inhibitor sebesar 4%, 6% dan 8% (b/v). Perendaman dilakukan selama 12, 24, 36, 48, 60 dan 72 jam. Metanol merupakan pelarut yang lebih baik daripada etanol dengan perolehan yield 4,57% dan konsentrasi tanin sebesar 2,768 ppm. Tanin dalam ekstrak kulit kayu akasia cocok digunakan sebagai inhibitor korosi pada media asam seperti H2SO4 0,5 M dan HCl 0,5 M dengan perolehan efisiensi tertinggi secara berturut-turut adalah 81,20 % dan 53,06%.Carbon steel in industrial equipment which direct contact with the environment will eventually be corroded. The rate of corrosion could be slowed by organic inhibitors of tannin compounds contained from acacia trees. Tannins were obtained from the extraction process using methanol and ethanol. The aims of this research were to determine the best solvent in the extraction process of acacia bark based on the largest tannin content and to study the effect of tannin as a corrosion inhibitor on carbon steel in the corrosive media through weight reduction methods. The extraction process used maceration at room temperature for two hours with a solid:solvent ratio of 1:10. The solvents were ethanol and methanol. The extract was evaporated in a rotary evaporator at 50 oC, 100 mbar became a paste form. Bark extract was added as an inhibitor in 0.5 M H2SO4 corrosive media; HCl 0.5 M; sea water, and tap water with the addition of inhibitor concentrations of 4%, 6% and 8% (w /v). Immersion was carried out for 12, 24, 36, 48, 60 and 72 hours. Methanol was a better solvent than ethanol with a yield of 4.57% and tannin concentration of 2.768 ppm. Tannin in acacia bark extract is suitable to be used as a corrosion inhibitor in acidic media such as H2SO4 0.5 M and 0.5 M HCl with the highest efficiency gains are 81.20% and 53.06%, respectively.


2008 ◽  
Vol 62 (1) ◽  
pp. 113-116 ◽  
Author(s):  
Pandian Bothi Raja ◽  
Mathur Gopalakrishnan Sethuraman

2016 ◽  
Vol 2016 ◽  
pp. 1-6 ◽  
Author(s):  
Atria Pradityana ◽  
Sulistijono ◽  
Abdullah Shahab ◽  
Lukman Noerochim ◽  
Diah Susanti

Inhibitor is a substance that is added to the corrosive media to inhibit corrosion rate. Organic inhibitors are preferred to inorganic ones since they are environmentally friendly. One of the organic compounds which is rarely reported as a corrosion inhibitor isMyrmecodia Pendans. The organic compounds can be adsorbed on the metal surface and block the active surface to reduce the rate of corrosion. In this study, the used pipe was carbon steel API 5L Grade B with 3.5% NaCl solution as the corrosion medium. The objective of this research was to analyze the inhibition mechanismMyrmecodia Pendanstowards carbon steel in a corrosion medium. Concentration variations of extractMyrmecodia Pendanswere 0–500 ppm. Fourier Transform Infrared (FTIR) was used for chemical characterization ofMyrmecodia Pendans. Polarization and Electrochemical Impedance Spectroscopy (EIS) were used to measure the corrosion rate and behaviour. From the electrochemical measurements, it was found that the addition of 400 mg/L inhibitor gave the highest inhibition efficiency.Myrmecodia Pendansacted as a corrosion inhibitor by forming a thin layer on the metal surface.


2012 ◽  
Vol 5 (2) ◽  
pp. 165
Author(s):  
Rozanna Sri Irianty ◽  
Maria Peratenta Sembiring

The important properties to overcome the corrosion are safe, available, biodegradable, low cost, and environmental friendly. Gambier leaves extract is one of the inhibitor that have environmental friendly properties. This study aims to determine the effectiveness of extract using ethanol-water to reduce the corrosion rate. Soaking of ferrous iron plate samples in seawater media have done for corrosion test. Agitator and aerator motors at turn-on and conducted a series of immersion with varying contact time 5, 10, 15, and 20 days. After the time up next ferrous iron plate samples were cleaned, dried, and weighed. Experiment was repeated by adding a inhibitor heavy leaves gambier extract with varying leaves gambier extract, 1000, 3000, and 5000 ppm. Soaking iron plate samples performed at varying pH at 3(acid), 6 (netral), and 9 (alkaline). Calculation is then performed and the rate of corrosion inhibition efficiency gambier leaves extract with ethanol-water solvent. On the immersion of iron plate without inhibitor, the result that the longer the contact time, the weight of the iron plate was reduced. The results showed the addition of inhibitors of leaves extract gambier with ethanol-water solvent into the corrosive media can reduce the rate of corrosion. Inhibitor of leaves extract gambier using ethanol-water solvent effective to reduce the rate of corrosion inhibitor at a concentration of 5000 ppm and contact time of 20 days with the lowest value of the corrosion rate is 0.000503 g/cm2 days in seawater media at initial pH 7.9. Gambier extracts gave greatest inhibition efficiency about 60.345% obtained at a concentration of 5000 ppm inhibitor and 20 days contact time.


2018 ◽  
Vol 27 ◽  
pp. 74-82
Author(s):  
Delia Andrada Duca ◽  
Mircea Laurentiu Dan ◽  
Nicolae Vaszilcsin

In this paper, the possibility of using ceftriaxone (CEFTR) active substance from expired cefort drug as corrosion inhibitor for nickel in acid solutions has been investigated. 0.5 M sulfuric acid and 1 M hydrochloric acid were used as corrosive media in experimental studies. The electrochemical behavior of ceftriaxone and its stability in test solutions have been examined by cyclic voltammetry. Further, the inhibitory effect has been studied by several methods: weight loss measurements, linear polarization and electrochemical impedance spectroscopy. As well, Tafel plots method was used in order to determine the kinetic parameters. Surface morphology of corroded samples has been characterized by scanning electron microscopy.


2018 ◽  
Vol 18 (4) ◽  
pp. 755
Author(s):  
Noor Syafiqah Habdul Latif ◽  
Sheikh Ahmad Izaddin Sheikh Mohd Ghazali ◽  
Erna Normaya Abdullah ◽  
Azizul Hakim Lahuri ◽  
Mohammad Fadzlee Ngatiman ◽  
...  

Corrosion of metal is a serious issue across many industries and is considered costly. Acids used during the cleaning process in industries may contribute to metal erosion. Dithiocarbamate is a ligand that can act as a corrosion inhibitor due to the presence of sulfur and nitrogen as electronegative atoms. Zn(II) N-isopropylbenzyldithiocarbamate (Zn[N-isopbenzdtc]2) complex was synthesized through direct synthetic method of < 4 °C and characterized using Fourier Transform Infrared-Attenuated Total Reflectance (FTIR-ATR), Ultraviolet-Visible (UV-Vis), Nuclear Magnetic Resonance (NMR), X-ray crystallography study, molar conductivity, melting point, and gravimetric analysis. Corrosion inhibition of mild steel was studied for different corrosive media (1 M HCl and 1 M H2SO4). The synthesized inhibitor was studied at different concentrations of 1, 2, 3, 4, and 5 mM at 40 °C. As a conclusion, as the inhibitor concentration decreased, the efficiency of the corrosion inhibitor also decreased at a constant temperature. In this study, it showed that the corrosion activity of mild steel in 1 M H2SO4 was higher compared to 1 M HCl due to the higher concentration of H+, which makes H2SO4 more corrosive than HCl.


2020 ◽  
Vol 4 (2) ◽  
Author(s):  
Puji Astuti Ibrahim

Carbon Steel 1018 is a low carbon steel having a carbon content (C) of 0.14-0.20% (<0.30% C). Low carbon steel is commercially known as mild steel. Corrosion is one way to prevent corrosion caused by the environment. Corrosion inhibitor are taken between the Crude Corrosion Inhibitor and Gas Corrosion inhibitor on Carbon Steel 1018 using the polarization method. Corrosion inhibitors work by making passive layers in the form of thin films or films on the surface of the material used as a barrier between metals and corrosive media. The analysis method used is polarization. Inhibition Efficiency Results obtained for Gas Corrosion Inhibitors (1A) at 10 ppm 96.86%, 20 ppm 59.74%, 30 ppm 74.48%. The Crude Corrosion Inhibitor (2A) results obtained inhibition efficiency for 10 ppm 99.57%, 20 ppm 77.69%, and 30 ppm 12.63%. The optimum value for the Gas Corrosion Inhibitor and Crude Corrosion Inhibitor is at 10 ppm at 96.86% and 99.57%. Keywords: carbon steel,crude corrosion inhibitor, corrosion , gas corrosion inhibitor, inhibitor


Sign in / Sign up

Export Citation Format

Share Document