scholarly journals Design of Experiments Applied to Antibiotics Degradation by Fenton’s Reagent

10.5772/68097 ◽  
2018 ◽  
Author(s):  
André Luís de Castro Peixoto ◽  
Ademir Geraldo Cavallari Costalonga ◽  
Mateus Nordi Esperança ◽  
Rodrigo Fernando dos Santos Salazar
Keyword(s):  
Design Of Experiments ◽  
Fenton’S Reagent ◽  
Fenton's Reagent

Use of Fenton's Reagent for the Degradation of TCE in Aqueous Systems and Soil Slurries

2000 ◽  
Vol 9 (4) ◽  
pp. 331-345 ◽  
Author(s):  
Katherine R. Weeks ◽  
Clifford J. Bruell ◽  
Nihar R. Mohanty
Keyword(s):  
Fenton’S Reagent ◽  
Aqueous Systems ◽  
Fenton's Reagent

The action of fenton's reagent on carbohydrates

Tetrahedron ◽  
1963 ◽  
Vol 19 (11) ◽  
pp. 1705-1710 ◽  
Author(s):  
G.J. Moody
Keyword(s):  
Fenton’S Reagent ◽  
Fenton's Reagent

Additions and Corrections - Oxidation of Mandelic Acid by Fenton's Reagent

1982 ◽  
Vol 104 (13) ◽  
pp. 3783-3783
Author(s):  
Cheves Walling ◽  
Kalyani Amarnath ◽  
Curt Campbell
Keyword(s):  
Mandelic Acid ◽  
Fenton’S Reagent ◽  
Fenton's Reagent

Kinetics and mechanism of oxidative decomposition of Congo red by Fenton’s reagent and its synergic effects on exposure to UV radiation

2021 ◽  
Vol 25 (7) ◽  
pp. 8-12
Author(s):  
P. Rajendran ◽  
K. Geethu ◽  
P. Bashpa ◽  
K. Bijudas
Keyword(s):  
Congo Red ◽  
Homogeneous Medium ◽  
Ultra Violet ◽  
Kinetics And Mechanism ◽  
Fenton’S Reagent ◽  
Fenton Reagent ◽  
Fenton's Reagent ◽  
Oxidative Decomposition ◽  
Ultra Violet Radiation ◽  
Thermodynamic Variables

Congo red is a toxic azo dye which is used extensively in industries like textile, paper, pulp and paper. Very high amount of Congo red from these industrial sources is discharged into natural water bodies resulting environmental pollution. The present work reports the kinetics and mechanism of oxidative decomposition of Congo red by Fenton’s reagent in homogeneous medium and also under ultra violet light irradiation. Kinetic parameters like effect of [Fe2+], [H2O2], [Congo red] and temperature on the decomposition of Congo red were studied. The reaction is found to be fractional order with [Fe2+] and first order with [H2O2] and [Congo red]. The rate of oxidative decomposition of Congo red by Fenton’ reagent showed a rapid increase of three times when irradiated with ultra violet radiation and completion of reaction occurred within 5-6 minute. Various thermodynamic variables were determined and the presence of isosbestic points on sequential scanning of oxidation kinetics proves that the reaction is very smooth, spontaneous and endothermic. A suitable mechanism is suggested based on the experimental results obtained.

Coagulation of textile secondary effluents with Fenton's reagent

1997 ◽  
Vol 36 (12) ◽  
pp. 215-222 ◽  
Author(s):  
Shyh-Fang Kang ◽  
Huey-Min Chang
Keyword(s):  
Hydrogen Peroxide ◽  
Cod Removal ◽  
Color Removal ◽  
Fenton’S Reagent ◽  
Fenton's Reagent ◽  
Effluent Standards ◽  
Secondary Effluents ◽  
Removal Efficiencies

This study was designed to use both artificial and real textile secondary effluents to evaluate (1) the COD and color removal efficiencies for ferrous coagulation and Fenton's coagulation, and (2) the feasibility of using hydrogen peroxide to improve ferrous coagulation to meet more stringent effluent standards. The results indicate that the optimum pHs for both ferrous coagulation and Fenton's preoxidation processes range between 8.0–10 and 3.0–5.0, respectively. The rate for color removal is faster than that for COD removal in the Fenton's preoxidation process. The removals of COD and color are mainly accomplished during Fenton's preoxidation step. The ratio of COD removal for Fenton's coagulation versus ferrous coagulation, given the same ferrous dosage, ranges from 1.4 to 2.3, and it ranges from 1.1 to 1.9 for color removal, using two effluent samples. Therefore, using hydrogen peroxide can enhance the ferrous coagulation, and this ensures more stringent effluent standards of COD and color are met.

Electro-Fenton as a feasible advanced treatment process to produce reclaimed water

2004 ◽  
Vol 50 (2) ◽  
pp. 83-90 ◽  
Author(s):  
A. Durán Moreno ◽  
B.A. Frontana-Uribe ◽  
R.M. Ramírez Zamora
Keyword(s):  
Reclaimed Water ◽  
Electrical Current ◽  
Primary Treatment ◽  
Operating Conditions ◽  
Treatment System ◽  
Continuous Reactor ◽  
Fenton’S Reagent ◽  
Fenton's Reagent ◽  
Fenton’S Reaction ◽  
The Cost

The feasibility of the electro-Fenton process to generate simultaneously both of the Fenton's reagent species (Fe2+/H2O2), was assessed as a potentially more economical alternative to the classical Fenton's reaction to produce reclaimed water. An air-saturated combined wastewater (mixture of municipal and laboratory effluents) was treated in discontinuous and continuous reactors at pH = 3.5. The discontinuous reactor was a 2 L electrochemical laboratory cell fitted with concentric graphite and iron electrodes. The continuous reactor tests used a pilot treatment system comprising the aforementioned electrochemical cell, two clarifiers and one sand filter. Several tests were carried out at different conditions of reaction time (0-60 min) and electrical current values (0.2-1.0 A) in the discontinuous reactor. The best operating conditions were 60 min and 1 A without filtration of effluents. At these conditions, in discontinuous and continuous reactors with filtration, the COD, turbidity and color removal were 65-74.8%, 77-92.3% and 80-100%, respectively. Fecal and total coliforms, Escherichia coli, Shigella and Salmonella sp. were not detected at the end of the pilot treatment system. Electrogeneration of the Fenton's reagent is also economical; its cost is one-fifth the cost reported for Advanced Primary Treatment.

Advanced oxidation processes: flowsheet options for bulk natural organic matter removal

2004 ◽  
Vol 4 (4) ◽  
pp. 113-119 ◽  
Author(s):  
C.A. Murray ◽  
S.A. Parsons
Keyword(s):  
Molecular Weight ◽  
Organic Matter ◽  
Organic Carbon ◽  
Dissolved Organic Carbon ◽  
Natural Organic Matter ◽  
Advanced Oxidation Processes ◽  
Advanced Oxidation ◽  
Fenton’S Reagent ◽  
Fenton's Reagent ◽  
Oxidation Processes

Advanced oxidation processes have been reported to have the potential to remove natural organic matter from source waters. Of these Fenton's reagent, photo-Fenton's reagent and titanium dioxide photocatalysis are the three most promising processes. Compared to conventional coagulation/flocculation processes they have higher removal efficiencies in terms of both dissolved organic carbon and UV254 absorbance. Under optimum reaction conditions all three remove over 80% dissolved organic carbon and 0% UV254 absorbance. In addition the enhanced removal of natural organic matter leads to a corresponding reduction in the formation of disinfection by-products following chlorination of the treated water. Advanced oxidation processes give enhanced removal of organic species ranging from low to high molecular weight while coagulation/flocculation is inefficient at removing low molecular weight species. One additional benefit is all three processes produce less residuals compared to conventional coagulation, which is advantageous as the disposal of such residuals normally contributes a large proportion of the costs at water treatment works.

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