scholarly journals Pulp Mill Wastewater: Characteristics and Treatment

10.5772/67537 ◽  
2017 ◽  
Author(s):  
María Noel Cabrera
Keyword(s):  
Pulp Mill

Environmental benefits of magnesium hydroxide-based peroxide bleaching of mechanical pulp – mill results

TAPPI Journal ◽  
2013 ◽  
Vol 12 (6) ◽  
pp. 9-15 ◽  
Author(s):  
TOMI HIETANEN ◽  
JUHA TAMPER ◽  
KAJ BACKFOLK
Keyword(s):  
Sodium Hydroxide ◽  
Magnesium Hydroxide ◽  
Oxygen Demand ◽  
Pulp Mill ◽  
Transition Metal Ions ◽  
Environmental Benefits ◽  
Raw Material ◽  
Paper Machine ◽  
High Brightness ◽  
Peroxide Bleaching

The use of a new, technical, high-purity magnesium hydroxide-based peroxide bleaching additive was evaluated in full mill-scale trial runs on two target brightness levels. Trial runs were conducted at a Finnish paper mill using Norwegian spruce (Picea abies) as the raw material in a conventional pressurized groundwood process, which includes a high-consistency peroxide bleaching stage. On high brightness grades, the use of sodium-based additives cause high environmental load from the peroxide bleaching stage. One proposed solution to this is to replace all or part of the sodium hydroxide with a weaker alkali, such as magnesium hydroxide. The replacement of traditional bleaching additives was carried out stepwise, ranging from 0% to 100%. Sodium silicate was dosed in proportion to sodium hydroxide, but with a minimum dose of 0.5% by weight on dry pulp. The environmental effluent load from bleaching of both low and high brightness pulps was significantly reduced. We observed a 35% to 48% reduction in total organic carbon (TOC), 37% to 40% reduction in chemical oxygen demand (COD), and 34% to 60% reduction in biological oxygen demand (BOD7) in the bleaching effluent. At the same time, the target brightness was attained with all replacement ratios. No interference from transition metal ions in the process was observed. The paper quality and paper machine runnability remained good during the trial. These benefits, in addition to the possibility of increasing production capacity, encourage the implementation of the magnesium hydroxide-based bleaching concept.

Biorefinery implementation for recovery debottlenecking at existing pulp mills- Part II: Techno-economic evaluation

TAPPI Journal ◽  
2012 ◽  
Vol 11 (8) ◽  
pp. 17-24 ◽  
Author(s):  
HAKIM GHEZZAZ ◽  
LUC PELLETIER ◽  
PAUL R. STUART
Keyword(s):  
Cost Estimation ◽  
Process Model ◽  
Black Liquor ◽  
Pulp Mill ◽  
Value Added ◽  
Economic Assessment ◽  
Extraction Process ◽  
Estimation Methods ◽  
Precipitation Process

The evaluation and process risk assessment of (a) lignin precipitation from black liquor, and (b) the near-neutral hemicellulose pre-extraction for recovery boiler debottlenecking in an existing pulp mill is presented in Part I of this paper, which was published in the July 2012 issue of TAPPI Journal. In Part II, the economic assessment of the two biorefinery process options is presented and interpreted. A mill process model was developed using WinGEMS software and used for calculating the mass and energy balances. Investment costs, operating costs, and profitability of the two biorefinery options have been calculated using standard cost estimation methods. The results show that the two biorefinery options are profitable for the case study mill and effective at process debottlenecking. The after-tax internal rate of return (IRR) of the lignin precipitation process option was estimated to be 95%, while that of the hemicellulose pre-extraction process option was 28%. Sensitivity analysis showed that the after tax-IRR of the lignin precipitation process remains higher than that of the hemicellulose pre-extraction process option, for all changes in the selected sensitivity parameters. If we consider the after-tax IRR, as well as capital cost, as selection criteria, the results show that for the case study mill, the lignin precipitation process is more promising than the near-neutral hemicellulose pre-extraction process. However, the comparison between the two biorefinery options should include long-term evaluation criteria. The potential of high value-added products that could be produced from lignin in the case of the lignin precipitation process, or from ethanol and acetic acid in the case of the hemicellulose pre-extraction process, should also be considered in the selection of the most promising process option.

Managing total reduced sulfur emissions at a Canadian kraft pulp mill

TAPPI Journal ◽  
2016 ◽  
Vol 15 (4) ◽  
pp. 265-272 ◽  
Author(s):  
ROHAN BANDEKAR ◽  
JIM FREDERICK ◽  
JAROSLAV STAVIK
Keyword(s):  
Direct Contact ◽  
Black Liquor ◽  
Pulp Mill ◽  
Packed Bed ◽  
Average Value ◽  
Emission Limit ◽  
Total Reduced Sulfur ◽  
Reduced Sulfur ◽  
Air Ingress ◽  
Solids Content

This study addresses the challenges a dissolving-grade pulp mill in Canada faced in 2014 in meeting its total reduced sulfur (TRS) gas emission limit. These emissions from the recovery boiler exit are controlled by passing the boiler exit gas through a TRS scrubber system. The mill employs a cyclonic direct contact evaporator to concentrate black liquor to firing solids content. The off-gases from the direct contact evaporator flow to the effluent gas control system that consists of a venturi scrubber, a packed bed scrubber, and a heat recovery unit. Emissions of TRS greater than the regulated limit of 15 ppm were observed for a 4-month period in 2014. The level of emissions measured during this period was significantly higher than about 12 ppm, the expected average value based on historic experience. The problem persisted from mid-June 2014 until the annual mill shutdown in October 2014. The main TRS components detected and the performance of the Teller scrubber in capturing them are examined. Other potential causes for these emissions are identified, including mechanical problems such as broken packing in the TRS packed bed scrubber, broken baffle plates in the scrubber, and cyclone evaporator leaks causing air ingress. Repairs were carried out during the mill shutdown, which eliminated the TRS emissions problem.

A novel approach to white liquor control in a continuous digester using the Box-Jenkins methodology to predict chip bulk density

TAPPI Journal ◽  
2015 ◽  
Vol 14 (6) ◽  
pp. 395-402
Author(s):  
FLÁVIO MARCELO CORREIA ◽  
JOSÉ VICENTE HALLAK D’ANGELO ◽  
SUELI APARECIDA MINGOTI
Keyword(s):  
Bulk Density ◽  
Moving Average ◽  
Pulp Mill ◽  
Statistical Decision ◽  
White Liquor ◽  
Novel Approach ◽  
Cooking Process ◽  
Eucalyptus Kraft Pulp ◽  
Relevant Variables ◽  
Kraft Cooking

Alkali charge is one of the most relevant variables in the continuous kraft cooking process. The white liquor mass flow rate can be determined by analyzing the chip bulk density fed to the process. At the mills, the total time for this analysis usually is greater than the residence time in the digester. This can lead to an increasing error in the mass of white liquor added relative to the specified alkali charge. This paper proposes a new approach using the Box-Jenkins methodology to develop a dynamic model for predicting chip bulk density. Industrial data were gathered on 1948 observations over a period of 12 months from a Kamyr continuous digester at a bleached eucalyptus kraft pulp mill in Brazil. Autoregressive integrated moving average (ARIMA) models were evaluated according to different statistical decision criteria, leading to the choice of ARIMA (2,0,2) as the best forecasting model, which was validated against a new dataset gathered during 2 months of operations. A combination of predictors has shown more accurate results compared to those obtained by laboratory analysis, allowing a reduction of around 25% of the chip bulk density error to the alkali addition amount.

Commissioning brownstock washing controls for an evaporator limited mill

TAPPI Journal ◽  
2016 ◽  
Vol 15 (7) ◽  
pp. 459-464
Author(s):  
RICARDO SANTOS ◽  
PETER HART
Keyword(s):  
Control System ◽  
Negative Impact ◽  
Black Liquor ◽  
Pulp Mill ◽  
Control Program ◽  
Separation Point ◽  
Water Control ◽  
Oxygen Delignification ◽  
Percentage Points

An automated shower water control system has been implemented to reduce the volume and variability of weak black liquor being sent from the pulp mill to the evaporators. The washing controls attempt to balance the need for consistent and low soda carryover to the bleach plant with consistently high weak black liquor solids being sent to the evaporators. The washer controls were implemented on two bleachable grade hardwood lines (one with oxygen delignification, one without oxygen delignification) and one pine line. Implementation of the control program resulted in an increase in black liquor solids of 0.6 percentage points for the hardwood lines. Significant foam reduction was realized on the pine line since the pine black liquor solids were able to be consistently maintained just below the soap separation point. Low black liquor solids excursions to the evaporators were eliminated. Bleach plant carryover was stabilized and no negative impact on chemical consumption was noticed when controlling weak black liquor solids to recovery.

Formation and degradation of mutagens in kraft pulp mill water systems

1990 ◽  
Vol 5 (3) ◽  
pp. 142-147 ◽  
Author(s):  
Annika Smeds ◽  
Bjarne Holmbom ◽  
Åbo Akademi ◽  
Leena Tikkanen
Keyword(s):  
Kraft Pulp ◽  
Pulp Mill ◽  
Water Systems ◽  
Kraft Pulp Mill
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