scholarly journals Metal Hydride-Based Materials as Negative Electrode for All- Solid-State Lithium-Ion Batteries

10.5772/62866 ◽  
2016 ◽  
Author(s):  
Liang Zeng ◽  
Koji Kawahito ◽  
Takayuki Ichikawa
RSC Advances ◽  
2017 ◽  
Vol 7 (82) ◽  
pp. 52151-52164 ◽  
Author(s):  
Michal Krajewski ◽  
Bartosz Hamankiewicz ◽  
Monika Michalska ◽  
Mariusz Andrzejczuk ◽  
Ludwika Lipinska ◽  
...  

Composites of Li4Ti5O12 with Ag–Cu particles were successfully synthesized by solid-state reaction followed by thermal decomposition of the metal substrates.


2015 ◽  
Vol 51 (48) ◽  
pp. 9773-9776 ◽  
Author(s):  
Liang Zeng ◽  
Koji Kawahito ◽  
Suguru Ikeda ◽  
Takayuki Ichikawa ◽  
Hiroki Miyaoka ◽  
...  

Electrode performances of MgH2–LiBH4 composite materials are investigated for all-solid-state lithium-ion batteries.


2019 ◽  
Vol 7 (16) ◽  
pp. 9432-9446 ◽  
Author(s):  
Zhixin Xu ◽  
Jun Yang ◽  
Hongping Li ◽  
Yanna Nuli ◽  
Jiulin Wang

Recent progress in electrolytes from the liquid to the solid state for Si-based anodes is comprehensively summarized in this review article.


2019 ◽  
Vol 21 (41) ◽  
pp. 22740-22755 ◽  
Author(s):  
Mei-Chin Pang ◽  
Yucang Hao ◽  
Monica Marinescu ◽  
Huizhi Wang ◽  
Mu Chen ◽  
...  

Solid-state lithium batteries could reduce the safety concern due to thermal runaway while improving the gravimetric and volumetric energy density beyond the existing practical limits of lithium-ion batteries.


Author(s):  
Xinyue Li ◽  
Marco Fortunato ◽  
Anna Maria Cardinale ◽  
Angelina Sarapulova ◽  
Christian Njel ◽  
...  

AbstractNickel aluminum layered double hydroxide (NiAl LDH) with nitrate in its interlayer is investigated as a negative electrode material for lithium-ion batteries (LIBs). The effect of the potential range (i.e., 0.01–3.0 V and 0.4–3.0 V vs. Li+/Li) and of the binder on the performance of the material is investigated in 1 M LiPF6 in EC/DMC vs. Li. The NiAl LDH electrode based on sodium alginate (SA) binder shows a high initial discharge specific capacity of 2586 mAh g−1 at 0.05 A g−1 and good stability in the potential range of 0.01–3.0 V vs. Li+/Li, which is better than what obtained with a polyvinylidene difluoride (PVDF)-based electrode. The NiAl LDH electrode with SA binder shows, after 400 cycles at 0.5 A g−1, a cycling retention of 42.2% with a capacity of 697 mAh g−1 and at a high current density of 1.0 A g−1 shows a retention of 27.6% with a capacity of 388 mAh g−1 over 1400 cycles. In the same conditions, the PVDF-based electrode retains only 15.6% with a capacity of 182 mAh g−1 and 8.5% with a capacity of 121 mAh g−1, respectively. Ex situ X-ray photoelectron spectroscopy (XPS) and ex situ X-ray absorption spectroscopy (XAS) reveal a conversion reaction mechanism during Li+ insertion into the NiAl LDH material. X-ray diffraction (XRD) and XPS have been combined with the electrochemical study to understand the effect of different cutoff potentials on the Li-ion storage mechanism. Graphical abstract The as-prepared NiAl-NO3−-LDH with the rhombohedral R-3 m space group is investigated as a negative electrode material for lithium-ion batteries (LIBs). The effect of the potential range (i.e., 0.01–3.0 V and 0.4–3.0 V vs. Li+/Li) and of the binder on the material’s performance is investigated in 1 M LiPF6 in EC/DMC vs. Li. Ex situ X-ray photoelectron spectroscopy (XPS) and ex situ X-ray absorption spectroscopy (XAS) reveal a conversion reaction mechanism during Li+ insertion into the NiAl LDH material. X-ray diffraction (XRD) and XPS have been combined with the electrochemical study to understand the effect of different cutoff potentials on the Li-ion storage mechanism. This work highlights the possibility of the direct application of NiAl LDH materials as negative electrodes for LIBs.


2021 ◽  
pp. 2007864
Author(s):  
Woo Jin Hyun ◽  
Cory M. Thomas ◽  
Norman S. Luu ◽  
Mark C. Hersam

Sign in / Sign up

Export Citation Format

Share Document