scholarly journals Crystal Structures of CH3NH3PbI3 and Related Perovskite Compounds Used for Solar Cells

Author(s):  
Takeo Oku
2020 ◽  
Vol 02 (01) ◽  
pp. 026-032
Author(s):  
Chen Yang ◽  
Liu Yuan ◽  
Ruimin Zhou ◽  
Zhen Wang ◽  
Jianqi Zhang ◽  
...  

The molecular stacking assembly in the active layer plays a significant role in the photovoltaic performance of organic solar cells (OSCs). Here, we report two new small molecular donors with different side chains, FBT-O and FBT-H, and their corresponding fullerene-based OSCs. A slight change in the side chains led to a big difference in the power conversion efficiencies (PCEs). Although the molecular structures of the two donors are similar to each other, PCEs of the devices based on FBT-O were almost three times higher than those of the devices based on FBT-H, with manifold short-circuit current density, fill factor, as well as three orders of magnitude enhancement in the hole mobility. The difference in their single crystal structures was thoroughly investigated, whereby the FBT-O exhibited better planarity leading to appropriate phase separation and domain size. Furthermore, two-dimensional grazing-incidence wide-angle X-ray scattering results of the blend films revealed that the two donors retained a similar stacking structure as compared to the single-crystal structures, thus, establishing a clear relationship between the molecular stacking structure and the device performance.


2013 ◽  
Vol 1 (39) ◽  
pp. 12088 ◽  
Author(s):  
Pablo Docampo ◽  
Aruna Ivaturi ◽  
Robert Gunning ◽  
Sandra Diefenbach ◽  
James Kirkpatrick ◽  
...  

2018 ◽  
Vol 57 (6) ◽  
pp. 060101 ◽  
Author(s):  
Kenji Ishizaki ◽  
Menaka De Zoysa ◽  
Yoshinori Tanaka ◽  
Seung-Woo Jeon ◽  
Susumu Noda

Synlett ◽  
2018 ◽  
Vol 29 (20) ◽  
pp. 2638-2642
Author(s):  
Matthias Bauer ◽  
Maike Tünnermann ◽  
Pia Rehsies ◽  
Ulrich Flörke

We report here a straightforward synthesis for a series of new structures with fused 1,10-phenanthroline-thiophene connection. They are synthesized with a modified Hinsberg thiophene procedure, followed by successive modification to yield several 5,7-disubstituted thieno[3,4-f][1,10]phenanthrolines, most notable thiophene-substituted compounds that could be potentially of use for organic electronics ­applications. For some selected examples, crystal structures were ­obtained, showing a nearly coplanar arrangement around the fused connection, also beneficial for an effective electron transfer in organic electronics or solar cells.


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