scholarly journals Selective Hydrogenation and Transfer Hydrogenation for Post-Functional Synthesis of Trifluoromethylphenyl Diazirine Derivatives for Photoaffinity Labeling

Hydrogenation ◽  
10.5772/48730 ◽  
2012 ◽  
Author(s):  
Makoto Hashimoto ◽  
Yuta Murai ◽  
Geoffery D. ◽  
Yasumaru Hatanak
Keyword(s):  
Selective Hydrogenation ◽  
Photoaffinity Labeling ◽  
Transfer Hydrogenation ◽  
Functional Synthesis

scholarly journals Selective Hydrogenation of Phenol to Cyclohexanol over Ni/CNT in the Absence of External Hydrogen

Energies ◽  
2020 ◽  
Vol 13 (4) ◽  
pp. 846 ◽  
Author(s):  
Changzhou Chen ◽  
Peng Liu ◽  
Minghao Zhou ◽  
Brajendra K. Sharma ◽  
Jianchun Jiang
Keyword(s):  
Reaction Time ◽  
Physicochemical Properties ◽  
Efficient Method ◽  
Selective Hydrogenation ◽  
Transfer Hydrogenation ◽  
Impregnation Method ◽  
Complete Conversion ◽  
Phenol Derivatives ◽  
Successive Step ◽  
Icp Analysis

Transfer hydrogenation is a novel and efficient method to realize the hydrogenation in different chemical reactions and exploring a simple heterogeneous catalyst with high activity is crucial. Ni/CNT was synthesized through a traditional impregnation method, and the detailed physicochemical properties were performed by means of XRD, TEM, XPS, BET, and ICP analysis. Through the screening of loading amounts, solvents, reaction temperature, and reaction time, 20% Ni/CNT achieves an almost complete conversion of phenol after 60 min at 220 °C in the absence of external hydrogen. Furthermore, the catalytic system is carried out on a variety of phenol derivatives for the generation of corresponding cyclohexanols with good to excellent results. The mechanism suggests that the hydrogenation of phenol to cyclohexanone is the first step, while the hydrogenation of cyclohexanone for the generation of cyclohexanol takes place in a successive step. Moreover, Ni/CNT catalyst can be magnetically recovered and reused in the next test for succeeding four times.

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