scholarly journals Solid Phase (Micro)extraction Tools Based on Carbon Nanotubes and Related Nanostructures

10.5772/39437 ◽  
2010 ◽  
Author(s):  
Juan Manuel ◽  
Rafael Lucena ◽  
Soledad Cardenas ◽  
Miguel Valcarcel
Keyword(s):  
Carbon Nanotubes ◽  
Solid Phase ◽  
Solid Phase Micro Extraction

Green Dispersive Micro Solid-Phase Extraction using Multiwalled Carbon Nanotubes for Preconcentration and Determination of Cadmium and Lead in Food, Water, and Tobacco Samples

2020 ◽  
Vol 16 (4) ◽  
pp. 381-392
Author(s):  
Ayman A. Gouda ◽  
Ali H. Amin ◽  
Ibrahim S. Ali ◽  
Zakia Al Malah
Keyword(s):  
Carbon Nanotubes ◽  
Solid Phase Extraction ◽  
Multiwalled Carbon Nanotubes ◽  
Solid Phase ◽  
Certified Reference Materials ◽  
Phase Extraction ◽  
Multiwalled Carbon ◽  
Flame Atomic Absorption ◽  
Relative Standard ◽  
Separation And Preconcentration

Background: Cadmium (Cd2+) and lead (Pb2+) have acute and chronic effects on humans and other living organisms. In the present work, new, green and accurate dispersive micro solid-phase extraction (DμSPE) method for the separation and preconcentration of trace amounts of cadmium (Cd2+) and lead (Pb2+) ions in various food, water and tobacco samples collected from Saudi Arabia prior to its Flame Atomic Absorption Spectrometric (FAAS) determinations was developed. Methods: The proposed method was based on a combination of oxidized multiwalled carbon nanotubes (O-MWCNTs) with a new chelating agent 5-benzyl-4-[4-methoxybenzylideneamino)-4H- 1,2,4-triazole-3-thiol (BMBATT) to enrich and separate trace levels of Cd2+ and Pb2+. The effect of separation parameters was investigated. The validation of the proposed preconcentration procedure was performed using certified reference materials. Results: Analyte recovery values ranged from 95-102%, indicating that the method is highly accurate. Furthermore, precision was demonstrated by the relative standard deviation (RSD < 3.0%). The limits of detection were 0.08 and 0.1 μg L−1 for Cd2+ and Pb2+ ions, respectively. The preconcentration factor was 200. Conclusion: The proposed method was used for the estimation of Cd2+ and Pb2+ ion content in various real samples, and satisfactory results were obtained. The proposed method has high adsorption capacity, rapid adsorption equilibrium, extremely low LODs, high preconcentration factors and shortens the time of sample preparation in comparison to classical SPE.

scholarly journals Solid-phase extraction cartridges with multi-walled carbon nanotubes and effect of the oxygen functionalities on the recovery efficiency of organic micropollutants

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Marta O. Barbosa ◽  
Rui S. Ribeiro ◽  
Ana R. L. Ribeiro ◽  
M. Fernando R. Pereira ◽  
Adrián M. T. Silva
Keyword(s):  
Carbon Nanotubes ◽  
Solid Phase Extraction ◽  
Solid Phase ◽  
Surface Groups ◽  
Phase Extraction ◽  
Organic Micropollutants ◽  
Oxidation Method ◽  
Hydrothermal Oxidation ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

AbstractPristine and functionalized multi-walled carbon nanotubes (MWCNTs) were investigated as adsorbent materials inside solid-phase extraction (SPE) cartridges for extraction and preconcentration of 8 EU-relevant organic micropollutants (with different pKa and polarity) before chromatographic analysis of surface water. The recoveries obtained were > 60% for 5/8 target pollutants (acetamiprid, atrazine, carbamazepine, diclofenac, and isoproturon) using a low amount of this reusable adsorbent (50 mg) and an eco-friendly solvent (ethanol) for both conditioning and elution steps. The introduction of oxygenated surface groups in the carbon nanotubes by using a controlled HNO3 hydrothermal oxidation method, considerably improved the recoveries obtained for PFOS (perfluorooctanesulfonic acid) and methiocarb, which was ascribed to the hydrogen bond adsorption mechanism, but decreased those observed for the pesticide acetamiprid and for two pharmaceuticals (carbamazepine and diclofenac), suggesting π–π dispersive interactions. Moreover, a good correlation was found between the recovery obtained for methiocarb and the amount of oxygenated surface groups on functionalized MWCNTs, which was mainly attributed to the increase of phenols and carbonyl and quinone groups. Thus, the HNO3 hydrothermal oxidation method can be used to finely tune the surface chemistry (and texture) of MWCNTs according to the specific micropollutants to be extracted and quantified in real water samples.

Solid phase functionalization of MWNTs: an eco-friendly approach for carbon-based conductive ink.

2021 ◽  
Author(s):  
Apostolos Koutsioukis ◽  
Vassiliki Belessi ◽  
Vasilios Georgakilas
Keyword(s):  
Carbon Nanotubes ◽  
Multiwalled Carbon Nanotubes ◽  
Solid Phase ◽  
Conductive Ink ◽  
Multiwalled Carbon ◽  
Green Approach ◽  
Carbon Based

A green approach for the functionalization of multiwalled carbon nanotubes (MWNTs) with hydrophilic groups and their use for the development of an ecofriendly conductive ink is described here. A known...

Development and comparison of direct immersion solid phase micro extraction Arrow-GC-MS for the determination of selected pesticides in water

2021 ◽  
Vol 164 ◽  
pp. 106006
Author(s):  
Seyed Mohammad Seyed Khademi ◽  
Amir Salemi ◽  
Maik Jochmann ◽  
Sasho Joksimoski ◽  
Ursula Telgheder
Keyword(s):  
Solid Phase ◽  
Solid Phase Micro Extraction ◽  
Pesticides In Water ◽  
Direct Immersion
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