Effective Reaction Monitoring of Intermediates by ATR-IR Spectroscopy Utilizing Fibre Optic Probes

Fibre optic ATR-IR spectroscopy at cryogenic temperatures: in-line reaction monitoring on organolithium compounds

Chemical Communications ◽

10.1039/c2cc16016a ◽

2012 ◽

Vol 48 (18) ◽

pp. 2451 ◽

Cited By ~ 20

Author(s):

Daniel Lumpi ◽

Christoph Wagner ◽

Matthias Schöpf ◽

Ernst Horkel ◽

Georg Ramer ◽

...

Keyword(s):

Ir Spectroscopy ◽

Reaction Monitoring ◽

Cryogenic Temperatures ◽

Fibre Optic ◽

Organolithium Compounds

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Convenient multigram synthesis of monodisperse oligo(ethylene glycols): effective reaction monitoring by infrared spectroscopy using an attenuated total reflection fibre optic probe

Tetrahedron Letters ◽

10.1016/j.tetlet.2009.09.010 ◽

2009 ◽

Vol 50 (47) ◽

pp. 6469-6471 ◽

Cited By ~ 12

Author(s):

Daniel Lumpi ◽

Christian Braunshier ◽

Christian Hametner ◽

Ernst Horkel ◽

Bernhard Zachhuber ◽

...

Keyword(s):

Infrared Spectroscopy ◽

Total Reflection ◽

Attenuated Total Reflection ◽

Reaction Monitoring ◽

Fibre Optic ◽

Ethylene Glycols ◽

Fibre Optic Probe ◽

Optic Probe ◽

Effective Reaction

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Study of the synthesis mechanism of 4-amino-3,5-dimethyl pyrazole by fibre optic in-line FT-IR spectroscopy combined with independent component analysis

Analytical Methods ◽

10.1039/c4ay00334a ◽

2014 ◽

Vol 6 (12) ◽

pp. 4305-4311 ◽

Cited By ~ 7

Author(s):

Jiguang Li ◽

Jun Gao ◽

Hua Li ◽

Xiaofeng Yang ◽

Yu Liu

Keyword(s):

Ir Spectroscopy ◽

Independent Component Analysis ◽

Component Analysis ◽

Independent Component ◽

Fibre Optic ◽

Synthesis Mechanism ◽

Ft Ir ◽

Ica Algorithm ◽

Ft Ir Spectroscopy

The synthesis mechanism of 4-amino-3,5-dimethyl pyrazole was investigated using in-line FT-IR spectroscopy combined with a Fast-ICA algorithm.

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Highly Flexible Fibre-Optic ATR-IR Probe for Inline Reaction Monitoring

Organic Process Research & Development ◽

10.1021/op0601767 ◽

2007 ◽

Vol 11 (1) ◽

pp. 94-97 ◽

Cited By ~ 43

Author(s):

Clemens B. Minnich ◽

Pascal Buskens ◽

H. Christian Steffens ◽

Patrick S. Bäuerlein ◽

Leonid N. Butvina ◽

...

Keyword(s):

Reaction Monitoring ◽

Fibre Optic

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In situ reaction monitoring of microwave-mediated reactions using IR spectroscopy

Chemical Communications ◽

10.1039/c0cc01921f ◽

2010 ◽

Vol 46 (36) ◽

pp. 6693 ◽

Cited By ~ 22

Author(s):

Nicholas E. Leadbeater

Keyword(s):

Ir Spectroscopy ◽

Reaction Monitoring ◽

In Situ Reaction

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Investigating the synthetic mechanism of 3,5-diamino-1,2,4-triazole by using fibre optic ATR-IR spectroscopy combined with kernel independent component analysis

Analytical Methods ◽

10.1039/c4ay02956a ◽

2015 ◽

Vol 7 (10) ◽

pp. 4152-4158 ◽

Cited By ~ 3

Author(s):

Hua Li ◽

Jun Gao ◽

Hongsheng Tang ◽

Jiguang Li ◽

Tianlong Zhang ◽

...

Keyword(s):

Ir Spectroscopy ◽

Independent Component Analysis ◽

Component Analysis ◽

Independent Component ◽

Fibre Optic ◽

Kernel Independent Component Analysis

Investigating the synthetic mechanism of 3,5-diamino-1,2,4-triazole by using fibre optic ATR-IR spectroscopy combined with kernel independent component analysis.

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FIBRE-OPTIC INFRARED (FT-IR) SPECTROSCOPY AS A TOOL FOR DISCRIMINATION BETWEEN NORMAL UROTHELIUM AND TRANSITIONAL CARCINOMA CELLS (TCC) OF DIFFERENT GRADE: PILOT STUDY

European Urology Supplements ◽

10.1016/s1569-9056(06)60923-8 ◽

2006 ◽

Vol 5 (2) ◽

pp. 252

Author(s):

S. Kravchick ◽

Y. Raichlin ◽

Y. Kravchenko ◽

D. Ben Dor ◽

A. Katzir ◽

...

Keyword(s):

Pilot Study ◽

Ir Spectroscopy ◽

Carcinoma Cells ◽

Fibre Optic ◽

Ft Ir ◽

Normal Urothelium ◽

Ft Ir Spectroscopy

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Solvent-assisted osmium staining of butyl acrylate and ethylene-propylene-diene in a styrene acrylonitrile matrix

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100150332 ◽

1993 ◽

Vol 51 ◽

pp. 900-901 ◽

Cited By ~ 1

Author(s):

Gudrun A. Hutchins

Keyword(s):

Butyl Acrylate ◽

Room Temperature ◽

Osmium Tetroxide ◽

Staining Procedure ◽

Reactive Site ◽

Ethylene Propylene ◽

Minimal Distortion ◽

Styrene Acrylonitrile ◽

Engineering Polymers ◽

Effective Reaction

In order to optimize the toughening effect of elastomers in engineering polymers, it is necessary to characterize the size, morphology and dispersion of the specific elastomer within the polymer matrix. For unsaturated elastomers such as butadiene or isoprene, staining with osmium tetroxide is a well established procedure. The residual carbon-carbon double bond in these materials is the reactive site and forms a 1,2-dilato complex with the OsO4. Incorporation of osmium tetroxide into the elastomer not only produces sufficient contrast for TEM, but also crosslinks the elastomer sufficiently so that ultramicrotomy can be accomplished at room temperature with minimal distortion.Blends containing saturated elastomers such as butyl acrylate (BA) and ethylene propylene diene monomer (EPDM) cannot be stained directly with OsO4 because effective reaction sites such as C=C or -NH2 are not available in sufficient number. If additional reaction sites can be introduced selectively into the elastomer by a chemical reaction or the absorption of a solvent, a modified, two-step osmium staining procedure is possible.

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