scholarly journals Thermodynamic of the Interactions Between Gas-Solidand Solid-Liquid on Carbonaceous Materials

Author(s):  
Vanessa Garcia-Cuello ◽  
Diana Vargas-Delgadillo ◽  
Yesid Murillo-Acevedo ◽  
Melina Yara ◽  
Paola Rodriguez-Estupinan ◽  
...  
2020 ◽  
Vol 27 (10) ◽  
pp. 1153-1162
Author(s):  
Hamideh Kaffash ◽  
Merete Tangstad

Abstract Carbon dissolution from four types of metallurgical cokes and graphite was investigated by using immersion rods in a resistance furnace to clarify the influence of factors governing the rate of carbon dissolution from carbonaceous materials into Fe–Mn melts at 1550 °C. The factors studied were the microstructure of carbonaceous materials, roughness, porosity and the wettability between carbonaceous materials and the melt. Carbon/metal interface was characterised by scanning electron microscopy accompanied with energy-dispersive X-ray spectrometry to investigate the formation of an ash layer. The results showed that coke E had the highest dissolution rate. Surface roughness and porosity of the carbonaceous materials seemed to be dominant factors affecting the dissolution rates. Further, crystallite size did not have a significant effect on the dissolution rates. Solid/liquid wettability seemed to affect the initial stage of dissolution reaction. The dissolution mechanism was found to be both mass transfer and interfacial reactions.


Author(s):  
J.A. Panitz

The first few atomic layers of a solid can form a barrier between its interior and an often hostile environment. Although adsorption at the vacuum-solid interface has been studied in great detail, little is known about adsorption at the liquid-solid interface. Adsorption at a liquid-solid interface is of intrinsic interest, and is of technological importance because it provides a way to coat a surface with monolayer or multilayer structures. A pinhole free monolayer (with a reasonable dielectric constant) could lead to the development of nanoscale capacitors with unique characteristics and lithographic resists that surpass the resolution of their conventional counterparts. Chemically selective adsorption is of particular interest because it can be used to passivate a surface from external modification or change the wear and the lubrication properties of a surface to reflect new and useful properties. Immunochemical adsorption could be used to fabricate novel molecular electronic devices or to construct small, “smart”, unobtrusive sensors with the potential to detect a wide variety of preselected species at the molecular level. These might include a particular carcinogen in the environment, a specific type of explosive, a chemical agent, a virus, or even a tumor in the human body.


2003 ◽  
Vol 16 (1) ◽  
pp. 66-70 ◽  
Author(s):  
Irena Vovk ◽  
Breda Simonovska ◽  
Samo Andrenšek ◽  
Teijo Yrjönen ◽  
Pia Vuorela ◽  
...  

2002 ◽  
Author(s):  
Julaporn Kaenton ◽  
Victoria Timchenko ◽  
Mohammed El Ganaoui ◽  
Graham de Vahl Davis ◽  
Eddie Leonardi ◽  
...  

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