scholarly journals Syntheses of Carbon Nanotube-Metal Oxides Composites; Adsorption and Photo-degradation

Author(s):  
Vinod Gupta ◽  
Tawfik A. Saleh
2019 ◽  
Vol 10 ◽  
pp. 1923-1932 ◽  
Author(s):  
Shengming Zhang ◽  
Xuhui Wang ◽  
Yan Li ◽  
Xuemei Mu ◽  
Yaxiong Zhang ◽  
...  

We have successfully prepared iron oxide and nickel oxide on carbon nanotubes on carbon cloth for the use in supercapacitors via a simple aqueous reduction method. The obtained carbon cloth–carbon nanotube@metal oxide (CC-CNT@MO) three-dimensional structures combine the high specific capacitance and rich redox sites of metal oxides with the large specific area and high electrical conductivity of carbon nanotubes. The prepared CC-CNT@Fe2O3 anode reaches a high capacity of 226 mAh·g−1 at 2 A·g−1 with a capacitance retention of 40% at 40 A·g−1. The obtained CC-CNT@NiO cathode exhibits a high capacity of 527 mAh·g−1 at 2 A·g−1 and an excellent rate capability with a capacitance retention of 78% even at 40 A·g−1. The all-solid-state asymmetric supercapacitor fabricated with these two electrodes delivers a high energy density of 63.3 Wh·kg−1 at 1.6 kW·kg−1 and retains 83% of its initial capacitance after 5000 cycles. These results demonstrate that our simple aqueous reduction method to combine CNT and metal oxides reveals an exciting future in constructing high-performance supercapacitors.


Carbon ◽  
2012 ◽  
Vol 50 (12) ◽  
pp. 4432-4440 ◽  
Author(s):  
Jordan R. Raney ◽  
Hong-Li Zhang ◽  
Daniel E. Morse ◽  
Chiara Daraio

Nano Letters ◽  
2014 ◽  
Vol 14 (4) ◽  
pp. 1884-1890 ◽  
Author(s):  
Luckshitha Suriyasena Liyanage ◽  
Xiaoqing Xu ◽  
Greg Pitner ◽  
Zhenan Bao ◽  
H.-S. Philip Wong

RSC Advances ◽  
2016 ◽  
Vol 6 (109) ◽  
pp. 107463-107474 ◽  
Author(s):  
Swati Nikam ◽  
Satyawati Joshi

Structure and bonding in metal oxides has been studied extensively using Raman vibrational spectroscopy and is found to provide complementary information to the crystallographic observations.


RSC Advances ◽  
2016 ◽  
Vol 6 (32) ◽  
pp. 26495-26504 ◽  
Author(s):  
Shanshan Yang ◽  
Pingxiao Wu ◽  
Meiqing Chen ◽  
Zhujian Huang ◽  
Wen Li ◽  
...  

In the present study, the mixed metal oxides (rGO-ZnTi-MMO-x, x presents weight percentage of GO) were obtained by thermal treatment of a Zn–Ti layered double hydroxides-graphene oxide (GO-ZnTi-LDHs) composite.


2010 ◽  
Vol 93-94 ◽  
pp. 505-508 ◽  
Author(s):  
Sarinya Shawaphun ◽  
Thara Manangan ◽  
Sirirat Wacharawichanant

Degradation of LDPE and PP films using the photo sensitive metal oxides or pro-oxidants (e.g. Fe2O3, CuxO, ZnO, and TiO2 at various particle sizes) as the catalysts in both thermo- and photo-oxidation of plastic films with oxygen followed by photolytic process to give free radicals has been studied. Our preliminary study in hexane solution found that the carbonyl index (CI) increased under the shortwave ultraviolet (254nm) significantly greater than under the longer wave (366nm) due to its greater energy and highly absorbed by the pro-oxidants generating more free radical concentration which could then be photolysed into carbonyl compounds. The pro-oxidant blended PE and PP films under ultraviolet (254nm) irradiation showed the carbonyl index elevation at the beginning and then reducing to a constant level similarly in most cases. This probably suggested that the carbonyl primarily formed and degraded into other free radicals. Under shortwave ultraviolet irradiation for 72 hours, the LDPE films containing nano-sized rutile-TiO2 and nano-sized anatase-TiO2 (1%w/w) were able to reduce the film tensile strength by 32% and 55%, respectively. The film containing micron-sized commercial TiO2 lower the film tensile strength only by 7-10%. However, the tensile strength of the TiO2 blended PP films tends to increase possibly because the rate of cross linkage exceeds the rate of scission.


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