scholarly journals Interactions between Organic Compounds and Ionic Liquids. Selectivity and Capacity Characteristics of Ionic Liquids

10.5772/14291 ◽  
2011 ◽  
Author(s):  
Fabrice Mutelet ◽  
Jean-Nol Jaubert
Keyword(s):  
Ionic Liquids ◽  
Organic Compounds ◽  
Selectivity And Capacity

Ionic liquids based fluorination of organic compounds using electrochemical method

2015 ◽  
Vol 31 ◽  
pp. 26-38 ◽  
Author(s):  
Zia Ul Haq Khan ◽  
Dondan Kong ◽  
Yongmei Chen ◽  
Nawshad Muhammad ◽  
Arif Ullah Khan ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Organic Compounds ◽  
Electrochemical Method

ChemInform Abstract: Characterization of Hydrophilic and Hydrophobic Ionic Liquids: Alternatives to Volatile Organic Compounds for Liquid-Liquid Separations

ChemInform ◽  
2010 ◽  
Vol 33 (50) ◽  
pp. no-no
Author(s):  
Ann E. Visser ◽  
W. Matthew Reichert ◽  
Richard P. Swatloski ◽  
Heather D. Willauer ◽  
Jonathan G. Huddleston ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Abstract Characterization ◽  
Volatile Organic ◽  
Hydrophobic Ionic Liquids ◽  
Liquid Separations

scholarly journals Measurements of Activity Coefficients at Infinite Dilution for Organic Solutes in the Ionic Liquids N-Ethyl- and N-Octyl-N-methylmorpholinium Bis(trifluoromethanesulfonyl)imide. A Useful Tool for Solvent Selection

Molecules ◽  
2020 ◽  
Vol 25 (3) ◽  
pp. 634 ◽  
Author(s):  
Łukasz Marcinkowski ◽  
Joachim Eichenlaub ◽  
Elham Ghasemi ◽  
Żaneta Polkowska ◽  
Adam Kloskowski
Keyword(s):  
Ionic Liquids ◽  
Organic Compounds ◽  
Activity Coefficients ◽  
Infinite Dilution ◽  
Retention Data ◽  
Separation Processes ◽  
Study Results ◽  
Conscious Choice ◽  
Potential Applications ◽  
Partial Molar Enthalpies

In recent years, many papers describing ionic liquids (IL) as promising solvents in separation techniques have been published. The conscious choice of appropriate ionic liquid as absorption media in effective extraction of selected types of analytes requires deeper understanding of the analyte−IL interactions. Therefore, intensive research is conducted to determine the values of activity coefficient at infinite dilution, which allows us to characterize the nature of these interactions. Based on the inverse gas chromatography retention data, activity coefficients at infinite dilution γ 13 ∞ of 48 different organic compounds in the ionic liquids N-ethyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide [C2C1Mor][TFSI] and N-octyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide [C8C1Mor][TFSI] were determined. The measurements covered a broad range of volatile organic compounds, including n-alkanes, n-alkenes, n-alkynes, alcohols, aldehydes, ketones, aromatic compounds and common polar solvents, representing different types of interactions. Activity coefficients at infinite dilution were measured in the temperature range from 313.15 to 363.15 K. The excess partial molar enthalpies and entropies at infinite dilution were determined. Selectivity at infinite dilution was also calculated for exemplary separation processes in the hexane/benzene system. The obtained results were analyzed and compared with literature data for ionic liquids containing the same anion [TFSI]¯ and different cations. The study results indicate that some potential applications of the investigated ionic liquids in separation problems exist.

scholarly journals Ionic Liquids as Antifungal Agents for Wood Preservation

Molecules ◽  
2020 ◽  
Vol 25 (18) ◽  
pp. 4289
Author(s):  
Catalin Croitoru ◽  
Ionut Claudiu Roata
Keyword(s):  
Ionic Liquids ◽  
Organic Compounds ◽  
Antifungal Agents ◽  
Wood Preservation ◽  
Wood Preservatives ◽  
Wood Material ◽  
Biomass Fractionation ◽  
Penetration Ability ◽  
Lignocellulose Biomass ◽  
Over Time

Ionic liquids represent a class of highly versatile organic compounds used extensively in the last decade for lignocellulose biomass fractionation and dissolution, as well as property modifiers for wood materials. This review is dedicated to the use of ionic liquids as antifungal agents for wood preservation. Wood preservation against fungal attack represents a relatively new domain of application for ionic liquids, emerging in the late 1990s. Comparing to other application domains of ionic liquids, this particular one has been relatively little researched. Ionic liquids may be promising as wood preservatives due to their ability to swell wood, which translates into better penetration ability and fixation into the bulk of the wood material than other conventional antifungal agents, avoiding leaching over time. The antifungal character of ionic liquids depends on the nature of their alkyl-substituted cation, on the size and position of their substituents, and of their anion. It pertains to a large variety of wood-colonizing fungi, both Basidiomycetes and Fungiimperfecti.

Ionic liquids versus amine solutions in biogas upgrading: the level of volatile organic compounds

Biofuels ◽  
2013 ◽  
Vol 4 (3) ◽  
pp. 295-311 ◽  
Author(s):  
E Privalova ◽  
S Rasi ◽  
K Eränen ◽  
D Yu Murzin ◽  
J-P Mikkola
Keyword(s):  
Ionic Liquids ◽  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Biogas Upgrading ◽  
Volatile Organic ◽  
Amine Solutions

Absorption and Biodegradation of Hydrophobic Volatile Organic Compounds in Ionic Liquids

2013 ◽  
Vol 224 (5) ◽  
Author(s):  
G. Quijano ◽  
A. Couvert ◽  
A. Amrane ◽  
G. Darracq ◽  
C. Couriol ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Volatile Organic
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