scholarly journals Effects on eating and rumination behaviour in sheep of formic acid and formaldehyde treatment and methionine-supplementation to ladino clover fibrous residue silage

1995 ◽  
Vol 8 (5) ◽  
pp. 477-480
Author(s):  
T. Fujihara ◽  
T. Ichicohe ◽  
T. Nakao
Keyword(s):  
Formic Acid ◽  
Formaldehyde Treatment ◽  
Methionine Supplementation ◽  
Fibrous Residue

8.3 The Digestion of a Wilted Silage made with and without an Additive

1982 ◽  
Vol 6 ◽  
pp. 162-163 ◽  
Author(s):  
M. A. Overend ◽  
D. G. Armstrong
Keyword(s):  
Small Intestine ◽  
Amino Acid ◽  
Formic Acid ◽  
Perennial Ryegrass ◽  
Terminal Ileum ◽  
Red Clover ◽  
Food Protein ◽  
Jersey Cattle ◽  
Second Growth ◽  
Formaldehyde Treatment

It has been shown by Beever, Thomson, Cammell and Harrison (1977) that formaldehyde treatment of silage increased amino acid absorption from the small intestine of sheep by 13% and increased the amount of food protein passing through the rumen undegraded by 66% compared to sheep receiving untreated silage. This paper details the digestion of N and apparent uptake of N, non-ammonia N and amino acid N from the small intestine of Jersey cattle fed a silage made from a second growth, mixed S24 perennial ryegrass/red clover sward which was wilted for 24h and then ensiled either without an additive or with a 50/50 mixture of formic acid and formaldehyde (formalin), each at the rate of 2.2 litres/tonne of grass ensiled. The method of ensiling was by use of an Eberhardt Silopresse (Benedict Agricultural Ltd., London). Each of the three cows fed each diet was equipped with a rumen fistula and re-entrant cannulae into the proximal duodenum and terminal ileum.

The influence of formaldehyde application at ensiling and of supplementation with urea or maize starch on the utilization by calves of ryegrass and red clover silages

1983 ◽  
Vol 36 (3) ◽  
pp. 371-381 ◽  
Author(s):  
A. G. Kaiser ◽  
D. F. Osbourn ◽  
P. England
Keyword(s):  
Organic Matter ◽  
Weight Gain ◽  
Formic Acid ◽  
Dry Matter ◽  
Nitrogen Retention ◽  
Live Weight ◽  
Red Clover ◽  
Carcass Weight ◽  
Live Weight Gain ◽  
Formaldehyde Treatment

ABSTRACTPrimary growths of perennial ryegrass and red clover were ensiled with formic acid (2 1/t fresh crop), o an equal quantity of formic acid together with formaldehyde (46 or 49 g/kg crude protein in the ryegrass or red clover respectively). The four silages were offered ad libitum to 12 groups, each of five British Friesian steer calves, either alone or with urea or maize starch supplements at 18·4 or 185·2 g/kg total dry-matter intake respectively.Digestible organic matter and digestible energy intake, live-weight gain, carcass weight, nitrogen retention and all digestibility measurements were higher on the ryegrass silages than on the red clover silages. However, dry-matter intake was higher on the red clover silages.Formaldehyde treatment reduced lactic and total acid content, and protein degradation in the silages. It also increased intake, live-weight gain and nitrogen retention on ryegrass but not on red clover, the effect being greater when the urea supplement was given. Digestibility measurements were depressed by formaldehyde treatment, although cellulose digestibility was only depressed in the ryegrass silage.Supplementation with starch depressed silage intake and nitrogen and cellulose digestibility, but increased dry matter, organic matter and energy digestibilities, digestible organic matter and digestible energy intakes, live-weight gain and carcass weight. The positive intake, live-weight gain and carcass weight responses were greater on the silages treated with formic acid, while the digestibility and the live-weight gain responses were greater on the red clover silages. Starch supplementation did not improve nitrogen retention.The different animal production responses to formaldehyde treatment on the ryegrass and red clover silages are discussed.

The influence of formic acid and formaldehyde additives and type of harvesting machine on the utilization of nitrogen in lucerne silages: 2. Changes in amino-acid composition during ensiling and their influence on nutritive value

1978 ◽  
Vol 91 (3) ◽  
pp. 717-725 ◽  
Author(s):  
T. N. Barry ◽  
D. N. Mundell ◽  
R. J. Wilkins ◽  
D. E. Beever
Keyword(s):  
Amino Acids ◽  
Amino Acid ◽  
Formic Acid ◽  
Glutamic Acid ◽  
Amino Acid Composition ◽  
Aspartic Acid ◽  
Nutritive Value ◽  
Formaldehyde Treatment ◽  
Amino Acid Degradation ◽  
Voluntary Intake

SummaryLucerne was made into ten silages using either a flail or a precision-chop harvester with application of formaldehyde or a range of rates of formic acid during harvesting. Amino-acid analyses were done on the silages and on samples taken from the herbage at ensiling.In excess of 70% of aspartic acid, serine, glutamic acid, tyrosine, threonine, lysine, histidine and arginine were destroyed in untreated silages when a flail harvester was used and in excess of 50% when a precision-chop harvester was used. Glycine, leucine, iso-leucine, valine and methionine showed little change, with net losses or increases of up to 10%, whilst proline, cystine + cysteine and phenylalanine were intermediate between these two categories. Net synthesis of alanine and α and γ amino-butyric acids occurred in the untreated silages. Increasing rates of formic acid addition, and the use of the precision-chop harvester, reduced the loss of the amino acids which were extensively degraded in the untreated silages and minimized the increases in alanine and α and γ amino-butyric acids. Formaldehyde treatment also reduced amino-acid degradation, apart from apparently high losses of lysine, histidine and tyrosine. It was concluded, however, that these losses arose through problems of estimation in formaldehyde-treated silages following HCl hydrolysis.It is suggested that the most probable precursors for alanine and α and γ aminobutyric acids were respectively aspartic acid, threonine and glutamic acid. Voluntary intake and the utilization of silage nitrogen by young sheep were related to the net changes in amino acids involved in decarboxylation reactions, the best measures of this being the interconversions involving the formation of alanine and α and γ aminobutyric acids. Deamination reactions appeared to be of much less importance in limiting silage nutritive value than those involving decarboxylation.

The influence of formic acid and formaldehyde additives and type of harvesting machine on the utilization of nitrogen in lucerne silages: 1. The voluntary intake and nitrogen rerention of young sheep consuming the silages with and without intraperitoneal supplements of DL-methionine

1978 ◽  
Vol 91 (3) ◽  
pp. 701-715 ◽  
Author(s):  
T. N. Barry ◽  
J. E. Cook ◽  
R. J. Wilkins
Keyword(s):  
Amino Acids ◽  
Acetic Acid ◽  
Formic Acid ◽  
Protein Degradation ◽  
Nitrogen Retention ◽  
Nitrogen Utilization ◽  
Separate Experiment ◽  
Carbohydrate Fermentation ◽  
Methionine Supplementation ◽  
Voluntary Intake

SummarySilages were made from lucerne using either a flail or a precision-chop harvester without additive, with 8 1 formaldehyde (35% w/w/)/t or with 1·5, 3·0 or 6·01 formic acid (85% w/w)/t. The silages were deep frozen and later offered to young sheep with and without intraperitoneal injections of DL-methionine. Fresh lucerne, cut with both machines from the same crop, was deep frozen and offered to sheep with and without methionine injections in a separate experiment.The untreated silages were characterized by extensive protein degradation, high contents of ammonia and acetic acid and low contents of lactic acid. Formaldehyde markedly reduced protein degradation and carbohydrate fermentation in the silo and caused a large reduction in nitrogen digestibility; these effects were of greater magnitude with precision-chopped than with flail-harvested silage. Voluntary intake and nitrogen retention were increased by formaldehyde application.Increased rate of addition of formic acid reduced the overall extent of carbohydrate fermentation, decreased the proportion of fermentation products Which could be attributed to clostridial activity, and decreased protein degradation, though not by the same extent as did formaldehyde. With the precision-chop harvester, formic acid addition increased both voluntary intake and nitrogen retention. Intakes were low on the three flail-harvested silages made with formic acid, as these were heavily contaminated with soil. However, the additive improved nitrogen utilization and within this group of treatments intake increased with increasing rate of formic acid application. The increases in nitrogen retention with additive treatment resulted from increases in the quantity of nitrogen truly retained per unit of nitrogen intake as well as from increases in intake.Methionine supplementation had no effect on voluntary intake, but caused a small and consistent improvement in nitrogen utilization except with the soil-contaminated silages. There was no effect of methionine supplementation on utilization of nitrogen in the fresh lucerne.Voluntary intake, apparent biological value and nitrogen retention all decreased linearly with increasing protein degradation and formation of acetic acid and ammonia. Separate regression equations were calculated for the prediction of organic-matter intake for silages made with the two types of harvester. These were parallel, but with intakes from the precision-chopped silages higher by ca. 20 g D.M./kg W0·75 per day. Precision chopping produced a similar advantage with the fresh lucerne. Data from silages made by the two harvesting methods fitted the same regressions for nitrogen retention, which decreased by 0·3 g/day for each 1% increase in ammonia-N (% total N). It was deduced that to produce silage with high nutritive value it is particularly important that the degradation of amino acids by proteolytic clostridia is prevented; restriction of the degradation in the silo of true protein to amino acids is apparently less important.

The effects of the quantity of formaldehyde applied at ensiling and of urea supplementation at feeding on the utilization of red clover silages by young growing cattle

1981 ◽  
Vol 97 (1) ◽  
pp. 1-11 ◽  
Author(s):  
A. G. Kaiser ◽  
J. C. Tayler ◽  
B. G. Gibbs ◽  
P. England
Keyword(s):  
Weight Gain ◽  
Formic Acid ◽  
Live Weight ◽  
Red Clover ◽  
Carcass Composition ◽  
Limiting Factor ◽  
Feed Conversion ◽  
N Retention ◽  
Live Weight Gain ◽  
Formaldehyde Treatment

SUMMARYSix silages were prepared from a primary growth of red clover using additives of 21 formic acid/t fresh crop together with formaldehyde at 0, 16, 34, 52, 77 or 117 g/kg crude protein (CP) in the crop. These silages were offered to appetite, either alone or with a urea supplement at 19·4 g/kg total dietary dry matter (D.M.), to 60 British Friesian steer calves with an initial mean live weight of 106 kg.Formaldehyde treatment restricted silage fermentation, the effect increasing with level of application. However, butyric acid and 2, 3-butanediol content increased at intermediate levels of application. Protein degradation in the silages was reduced by formaldehyde treatment, as evidenced by a decline in ammonia-N and an increase in insoluble-N content with increasing level of formaldehyde application. The recovery of applied formaldehyde in the silages was low (less than 13%) but increased with level of application.Intake, live-weight gain and feed conversion ratio followed quadratic trends, with formaldehyde having a deleterious effect at high levels of application. The decline in these production measurements was associated with declines in the apparent digestibility of D.M., organic matter (OM), N and energy with increasing level of formaldehyde application, although there was no effect of formaldehyde on cellulose digestibility. Urea supplementation tended to increase intake and live-weight gain at formaldehyde levels greater than 34 g/kg CP, and apart from the expected increase in N digestibility, did not affect the digestibility of other dietary components. As urea supplementation did not overcome the adverse effects of high levels of formaldehyde application on intake, live-weight gain and digestibility, it appears that the supply of rumen-degradable N was not the major limiting factor on these diets.N retention followed a quadratic trend with level of formaldehyde application, increasing at intermediate levels (30–50 g/kg CP) and then declining markedly at the highest level of application. A similar trend was evident when N retention was expressed as a proportion of live-weight gain, suggesting possible formaldehyde effects on carcass composition. However, carcass composition data did not confirm any formaldehyde effect. Urea supplementation did not affect N retention, and N balance data indicated poor utilization of the supplementary urea N.When considering the use of formaldehyde, relative to a formic acid control, in additives applied to red olover at ensiling, these data demonstrate little advantage in favour of formaldehyde and serious disadvantages when large quantities of formaldehyde are applied.

A comparison of silage-based and dried forage-based diets, and the effect of protein supplementation of a silage-based diet for finishing beef cattle

1989 ◽  
Vol 49 (2) ◽  
pp. 233-240 ◽  
Author(s):  
R. W. J. Steen ◽  
Charlotte A Moore
Keyword(s):  
Beef Cattle ◽  
Formic Acid ◽  
Total Nitrogen ◽  
Live Weight ◽  
Protein Supplementation ◽  
Carcass Composition ◽  
Energy Utilization ◽  
Grass Silage ◽  
Formaldehyde Treatment ◽  
Finishing Beef Cattle

ABSTRACTAn experiment was carried out to compare silage-based and dried forage-based diets for finishing beef cattle and to examine the effects of protein supplementation and formaldehyde treatment of silage on performance and carcass composition. The four diets used consisted, on a dry matter basis, of (1) 700 g/kg formic acid-treated grass silage and 300 g/kg low protein cereal-based concentrate (LPC), (2) 720 g/kg formic acid-treated silage and 280 g/kg high protein cereal/fish meal concentrate, (3) 600 g/kg formaldehyde-treated silage and 400 g/kg LPC, and (4) 480 g/kg artificially dried grass and grass hay and 520 g/kg LPC. The silages were well preserved with 33 to 40 g ammonia N per kg total nitrogen. The diets were offered to 40 British Friesian castrated male cattle which were initially 387 (s.e. 2·9) kg live weight. For diets 1 to 4 respectively metabolizable energy intakes were 91·8, 94·7, 94·9 and 91·8 MJ/day; total nitrogen intakes 192, 234, 189 and 191 g/day; live-weight gains 0/89, 0/93, 0/86 and 0/82 (s.e. 0/045) kg/day; carcass gains 0·51, 0·52, 0·52, 0·52 and 0·50 (s.e. 0·33) kg/day; mean subcutaneous fat depths 5·6, 5·4, 5·3 and 6·0 (s.e. 0·41) mm; marbling scores 3·0, 3·3, 3·2 and 2·6 (s.e. 0·19) and areas of m. longissimus dorsi 65·7, 66·4, 64·7 and 64·3 (s.e. 1·66) cm2. It is concluded that performance, efficiency of energy utilization and carcass fatness were similar for a diet containing 700 g/kg well preserved grass silage and a dried forage-based diet with a similar intake of energy and protein. Protein supplementation of a diet based on formic acid-treated silage or formaldehyde treatment of silage did not affect performance or carcass fatness.

NANOELECTROCATALYSTS BASED PALLADIUM FOR FUEL CELLS WITH DIRECT OXIDATION OF FORMIC ACID

2019 ◽  
Vol 6 (3) ◽  
pp. 104-107
Author(s):  
Marina Vladimirovna Lebedeva ◽  
Alexey Petrovich Antropov ◽  
Alexander Victorovich Ragutkin ◽  
Nicolay Andreevich Yashtulov
Keyword(s):  
Formic Acid ◽  
Palladium Nanoparticles ◽  
Oxidation Reaction ◽  
Electrode Materials ◽  
Formic Acid Oxidation ◽  
Energy Sources ◽  
Acid Oxidation ◽  
Direct Oxidation ◽  
Atomic Force ◽  
Formic Acid Oxidation Reaction

In paper electrode materials with palladium nanoparticles on polymer matrix substrates for energy sources have been formed. Nanocomposites were investigated by atomic force and scanning electron microscopy. The catalytic activity of formed electrodes in the formic acid oxidation reaction was evaluated by voltammetry method.

THE JET-COOLED HIGH-RESOLUTION IR SPECTRUM OF FORMIC ACID CYCLIC DIMER

2017 ◽  
Author(s):  
Manuel Goubet ◽  
Robert Georges ◽  
P. Roy ◽  
Atef Jabri ◽  
Pascale Soulard ◽  
...  
Keyword(s):  
High Resolution ◽  
Formic Acid ◽  
Ir Spectrum ◽  
Cyclic Dimer
Sign in / Sign up

Export Citation Format

Share Document