scholarly journals A Semi-Empirical Spectrophotometric (SESp) Method for the Indirect Determination of the Ratio of Cationic Micellar Binding Constants of Counterions X^|^ndash; and Br^|^ndash; (KX/KBr)

2013 ◽  
Vol 62 (9) ◽  
pp. 695-708 ◽  
Author(s):  
Mohammad Niyaz Khan ◽  
Nor Saadah Mohd Yusof ◽  
Norazizah Abdul Razak
Keyword(s):  
Binding Constants ◽  
Indirect Determination ◽  
Semi Empirical

Indirect Determination of Amikacin by Gold Nanoparticles as Redox Probe

2020 ◽  
Vol 17 ◽  
Author(s):  
Mansureh Alizadeh ◽  
Mandana Amiri ◽  
Abolfazl Bezaatpour
Keyword(s):  
Gold Nanoparticles ◽  
Bacterial Infections ◽  
Limit Of Detection ◽  
Pharmaceutical Preparation ◽  
Cathodic Peak ◽  
Easy Method ◽  
Peak Current ◽  
Indirect Determination ◽  
Tract Infections

: Amikacin is an aminoglycoside antibiotic used for many gram-negative bacterial infections like infections in the urinary tract, infections in brain, lungs and abdomen. Electrochemical determination of amikacin is a challenge in electroanalysis because it shows no voltammetric peak at the surface of bare electrodes. In this approach, a very simple and easy method for indirect voltammetric determination of amikacin presented in real samples. Gold nanoparticles were electrodeposited at the surface of glassy carbon electrode in constant potential. The effect of several parameters such as time and potential of deposition, pH and scan rates on signal were studied. The cathodic peak current of Au3+ decreased with increasing amikacin concentration. Quantitative analysis of amikacin was performed using differential pulse voltammetry by following cathodic peak current of gold ions. Two dynamic linear ranges of 1.0 × 10−8–1.0 × 10-7 M and 5.0 × 10−7–1.0 × 10-3 M were obtained and limit of detection was estimated 3.0× 10−9 M. The method was successfully determined amikacin in pharmaceutical preparation and human serum. The effect of several interference in determination of amikacin was also studied.

Determination of Some Nitrophenols by Atomic Absorption Spectrometry (AAS) After Extraction of Ionic Associates Involving the Bipyridylocopper(II) or Phenanthrolinocopper(II) Complex

1994 ◽  
Vol 59 (10) ◽  
pp. 2227-2234 ◽  
Author(s):  
Václav Stužka ◽  
Jaromír Souček
Keyword(s):  
Molecular Weight ◽  
Atomic Absorption Spectrometry ◽  
Atomic Absorption ◽  
Methyl Isobutyl Ketone ◽  
Absorption Spectrometry ◽  
Methyl Isobutyl ◽  
Isobutyl Ketone ◽  
Indirect Determination ◽  
Ionic Associates

A new method has been developed for the indirect determination of nitroso- and nitrophenols by atomic absorption spectrometry (AAS) after extraction of ionic associates involving bipyridylocopper(II) (CuDP) or phenanthrolinocopper(II) (CuPH) complexes. Nitrobenzene and methyl isobutyl ketone appeared to be suitable for the extraction. It was possible to determine several tenths to hundredths of a milligram of nitrophenol in a litre. Extractable associates with CuDP and CuPH are formed by phenols possessing two substituents or by higher molecular weight phenols such as naphthol or hydroxyquinoline. Monosubstituted phenols fail to form associates of this kind.

Determination of Enzyme or Binding Constants Using Generalized Linear Models, with Particular Reference to Michaelis–Menten Models

1989 ◽  
Vol 78 (5) ◽  
pp. 413-416
Author(s):  
Gerald Van Belle ◽  
Sue Leurgans ◽  
Pat Friel ◽  
Sunwei Guo ◽  
Mark Yerby
Keyword(s):  
Generalized Linear Models ◽  
Linear Models ◽  
Binding Constants

Indirect determination of aluminum (III) in water samples by in-electrode coulometric titration

2021 ◽  
Vol 164 ◽  
pp. 106058
Author(s):  
Jakub Masac ◽  
Jan Lovic ◽  
Ernest Beinrohr ◽  
Frantisek Cacho
Keyword(s):  
Water Samples ◽  
Coulometric Titration ◽  
Indirect Determination
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