scholarly journals Alkylresorcinols in rye (Secale cereale L.) grains. V. Chromatographic analysis of 5-n-alk(en)ylresorcinols during their preparation

2014 ◽  
Vol 50 (4) ◽  
pp. 637-643 ◽  
Author(s):  
Arkadiusz Kozubek ◽  
Franciszek Tłuścik ◽  
Wanda Mejbaum-Katzenellenebogen
Keyword(s):  
Silica Gel ◽  
Secale Cereale ◽  
Chromatographic Analysis ◽  
Saturated Hydrocarbon ◽  
Unsaturated Hydrocarbon ◽  
Hydrocarbon Chains ◽  
Secale Cereale L ◽  
Unsaturated Hydrocarbon Chains

Analysis of 5-n-alk(en)ylresorcinols during the coarse of their preparation from rye grains showed that changes of the composition of 5-n-alkylresorcinol homologues in acetone oil; raw preparation, and alkylresorcinol fraiction obtained after chromatography on silica gel, were insignificant. About 20% of alk(en)-ylresorcinals were washed out from acetone oil with pentane. Over 50% of alk(en)ylresorcinols eluted by pentane constituted homologues with unsaturated hydrocarbon chains (5-n-alkenylresorcinols). Preparation obtained after chromatagraphic separation constituted a mixtureof 5-n-alk(en)ylresorcinols width saturated hydrocarbon chains (5-n-alkylresorcinols).

Ethyl-, vinyl- and ethynylcyanoborates: Room temperature borate ionic liquids with saturated and unsaturated hydrocarbon chains

2022 ◽  
Author(s):  
Nils Schopper ◽  
Ludwig Zapf ◽  
Jan Arke Peter Sprenger ◽  
Nikolai Ignat'ev ◽  
Maik Finze
Keyword(s):  
Ionic Liquids ◽  
Room Temperature ◽  
Unsaturated Hydrocarbon ◽  
Ethyl Vinyl ◽  
Hydrocarbon Chains ◽  
Unsaturated Hydrocarbon Chains ◽  
Potassium Trifluoroborates

Ethyl-, vinyl- and ethynyltricyano and dicyanofluoroborates were prepared on gram scale from commercially available potassium trifluoroborates and trimethylsilylcyanide. Salt metathesis resulted in the corresponding EMIm-salts that are hydrophobic room-temperature ionic...

Toward Quantitative Sequencing of Deuteration of Unsaturated Hydrocarbon Chains in Fatty Acids

2021 ◽  
Author(s):  
Dong Hao Wang ◽  
Hui Gyu Park ◽  
Zhen Wang ◽  
R. J. Scott Lacombe ◽  
Vadim V. Shmanai ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Unsaturated Hydrocarbon ◽  
Hydrocarbon Chains ◽  
Unsaturated Hydrocarbon Chains

Effet antioxydant et antihyperglycémiant du seigle (Secale cereale L.) et du sorgho (Sorghum bicolor L.) chez le rat Wistar rendu diabétique

2018 ◽  
Vol 16 (S1) ◽  
pp. S273-S283
Author(s):  
Z. Mami-Soualem ◽  
N. Brixi ◽  
C. Beghdad ◽  
M. Belarbi
Keyword(s):  
Sorghum Bicolor ◽  
Secale Cereale ◽  
Stress Oxydant ◽  
Habitudes Alimentaires ◽  
Diabète Sucré ◽  
Secale Cereale L ◽  
Vitamine C ◽  
Fibres Alimentaires ◽  
Peroxydation Lipidique ◽  
Sorghum Bicolor L

Le changement des habitudes alimentaires au cours de ces dernières années a abouti à l’apparition des maladies dites de civilisation, parmi elles le diabète sucré. Des approches diétothérapeutiques privilégient la consommation des produits céréaliers sous la forme la plus complète possible. Ce travail a pour but de tester l’efficacité des régimes expérimentaux préparés à base des grains complets des deux céréales, le sorgho (Sorghum bicolor L.) et le seigle (Secale cereale L.), sur la correction de l’hyperglycémie et des marqueurs du stress oxydant associés au diabète chez le rat mâle Wistar. Les résultats montrent que les rats diabétiques, soumis au régime seigle pendant quatre semaines, présentent une diminution significative de la glycémie qui atteint les 53,95 % à la fin de l’expérimentation, ce qui fait que leur taux en glycémie se rapproche de celui des normoglycémiques. Le sorgho blanc présente, d’une part, une diminution significative de la peroxydation lipidique intracellulaire et, d’autre part, une augmentation de l’activité de la glutathion peroxydase, la glutathion réductase ainsi que la vitamine C. Ces approches méthodologiques peuvent, en améliorant la connaissance de l’importance des céréales (fibres alimentaires solubles et des polyphénols) dans l’évolution du diabète, aboutir à des recommandations et à une éducation nutritionnelle du diabétique.

scholarly journals Production of Methane, Hydrogen and Ethanol from Secale cereale L. Straw Pretreated with Sulfuric Acid

Molecules ◽  
2020 ◽  
Vol 25 (4) ◽  
pp. 1013 ◽  
Author(s):  
Jarosław Domański ◽  
Olga Marchut-Mikołajczyk ◽  
Weronika Cieciura-Włoch ◽  
Piotr Patelski ◽  
Urszula Dziekońska-Kubczak ◽  
...  
Keyword(s):  
Sulfuric Acid ◽  
Secale Cereale ◽  
Treatment Time ◽  
Ethanol Yield ◽  
Biofuel Production ◽  
Enzyme Treatment ◽  
Electricity Production ◽  
The European Union ◽  
Rye Straw ◽  
Secale Cereale L

The study describes sulfuric acid pretreatment of straw from Secale cereale L. (rye straw) to evaluate the effect of acid concentration and treatment time on the efficiency of biofuel production. The highest ethanol yield occurred after the enzyme treatment at a dose of 15 filter paper unit (FPU) per gram of rye straw (subjected to chemical hydrolysis with 2% sulfuric acid (SA) at 121 °C for 1 h) during 120 h. Anaerobic digestion of rye straw treated with 10% SA at 121 °C during 1 h allowed to obtain 347.42 L methane/kg volatile solids (VS). Most hydrogen was released during dark fermentation of rye straw after pretreatment of 2% SA, 121 °C, 1 h and 1% SA, 121 °C, 2 h—131.99 and 134.71 L hydrogen/kg VS, respectively. If the rye straw produced in the European Union were processed into methane, hydrogen, ethanol, the annual electricity production in 2018 could reach 9.87 TWh (terawatt-hours), 1.16 TWh, and 0.60 TWh, respectively.

Meiotic mutants of rye Secale cereale L.

1992 ◽  
Vol 84-84 (7-8) ◽  
pp. 979-985 ◽  
Author(s):  
S. P. Sosnikhina ◽  
Yu S. Fedotova ◽  
V. G. Smirnov ◽  
E. I. Mikhailova ◽  
O. L. Kolomiets ◽  
...  
Keyword(s):  
Secale Cereale ◽  
Meiotic Mutants ◽  
Secale Cereale L

A fluorescence enhancement assay of cell fusion

1977 ◽  
Vol 28 (1) ◽  
pp. 167-177
Author(s):  
P.M. Keller ◽  
S. Person ◽  
W. Snipes
Keyword(s):  
Absorption Spectrum ◽  
Energy Transfer ◽  
Emission Spectrum ◽  
Cell Fusion ◽  
Saturated Hydrocarbon ◽  
Photon Emission ◽  
Resonance Energy Transfer ◽  
Resonance Energy ◽  
Hydrocarbon Chains ◽  
Fluorescent Molecules

Two probes were synthesized which consist of fluorescent molecules conjugated to saturated hydrocarbon chains, 18 carbons long, to ensure their localization into cellular membranes. There is an overlap between the emission spectrum of one probe (donor) and the absorption spectrum of the other probe (acceptor). By the use of appropriate wavelengths it is possible to specifically excite the donor probe and record the fluorescence of the acceptor probe. Two cell populations, each labelled with one of the probes, were infected with a virus that causes cell fusion, mixed in equal proportions, and the fluorescence of the acceptor probe measured as a function of time after infection. An increase in fluorescence was observed beginning at the time of onset of cell fusion indicating a mixing of the fluorescent membrane molecules. An investigation of the distance dependence indicated that the increase in fluorescence was mainly due to resonance energy transfer and not to photon emission and reabsorption. Resonance energy transfer requires that the 2 probes be close together and that there be an overlap of the emission spectrum of the donor probe and the absorption spectrum of the acceptor probe. The possible application of this assay to other types of membrane fusion is noted.

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