scholarly journals Design of Velocity Map Imaging Spectrometer Equipped with a Mass Gate Discriminating Particular Photofragments

2012 ◽  
Vol 2012 ◽  
pp. 1-9
Author(s):  
Koichiro Mitsuke ◽  
Hideki Katayanagi ◽  
Bhim P. Kafle ◽  
Md. Serajul I. Prodhan

A photoionization spectrometer for velocity map imaging has been developed for measuring the scattering distribution of fragment ions from polyatomic molecules. The spectrometer contains a mass gate and an ion reflector which are able to discriminate ions with a particular mass-to-charge ratio m/z. The basic functions and feasibility of these devices were tested experimentally and theoretically. First, the photoions from Kr and C60 were extracted into a time-of-flight (TOF) mass spectrometer by a transient or continuous electrostatic field. When the pulse application on the mass gate was tuned to the arrival timing of ions with a specific m/z, the peak of the selected ions alone was present on a TOF spectrum. Second, compatibility between velocity map imaging and ion discrimination was investigated by the computer simulations of the ion trajectories of photofragments from C60. A pulsed voltage was applied to the mass gate synchronously with the arrival timing of C58+ ions. The initial three-dimensional velocity distribution of C58+ was projected onto the image plane with an energy resolution better than 10 meV. The C58+ image was free from the contamination of other ions such as C60+ and C56+.

Author(s):  
John C. Russ

Three-dimensional (3D) images consisting of arrays of voxels can now be routinely obtained from several different types of microscopes. These include both the transmission and emission modes of the confocal scanning laser microscope (but not its most common reflection mode), the secondary ion mass spectrometer, and computed tomography using electrons, X-rays or other signals. Compared to the traditional use of serial sectioning (which includes sequential polishing of hard materials), these newer techniques eliminate difficulties of alignment of slices, and maintain uniform resolution in the depth direction. However, the resolution in the z-direction may be different from that within each image plane, which makes the voxels non-cubic and creates some difficulties for subsequent analysis.


2008 ◽  
Vol 67 (1) ◽  
pp. 51-60 ◽  
Author(s):  
Stefano Passini

The relation between authoritarianism and social dominance orientation was analyzed, with authoritarianism measured using a three-dimensional scale. The implicit multidimensional structure (authoritarian submission, conventionalism, authoritarian aggression) of Altemeyer’s (1981, 1988) conceptualization of authoritarianism is inconsistent with its one-dimensional methodological operationalization. The dimensionality of authoritarianism was investigated using confirmatory factor analysis in a sample of 713 university students. As hypothesized, the three-factor model fit the data significantly better than the one-factor model. Regression analyses revealed that only authoritarian aggression was related to social dominance orientation. That is, only intolerance of deviance was related to high social dominance, whereas submissiveness was not.


2020 ◽  
Author(s):  
Junxia Ren ◽  
Yaozu Liu ◽  
Xin Zhu ◽  
Yangyang Pan ◽  
Yujie Wang ◽  
...  

<p><a></a><a></a><a></a><a></a><a></a><a></a><a></a><a>The development of highly-sensitive recognition of </a><a></a><a></a><a></a><a></a><a>hazardous </a>chemicals, such as volatile organic compounds (VOCs) and polycyclic aromatic hydrocarbons (PAHs), is of significant importance because of their widespread social concerns related to environment and human health. Here, we report a three-dimensional (3D) covalent organic framework (COF, termed JUC-555) bearing tetraphenylethylene (TPE) side chains as an aggregation-induced emission (AIE) fluorescence probe for sensitive molecular recognition.<a></a><a> </a>Due to the rotational restriction of TPE rotors in highly interpenetrated framework after inclusion of dimethylformamide (DMF), JUC-555 shows impressive AIE-based strong fluorescence. Meanwhile, owing to the large pore size (11.4 Å) and suitable intermolecular distance of aligned TPE (7.2 Å) in JUC-555, the obtained material demonstrates an excellent performance in the molecular recognition of hazardous chemicals, e.g., nitroaromatic explosives, PAHs, and even thiophene compounds, via a fluorescent quenching mechanism. The quenching constant (<i>K</i><sub>SV</sub>) is two orders of magnitude better than those of other fluorescence-based porous materials reported to date. This research thus opens 3D functionalized COFs as a promising identification tool for environmentally hazardous substances.</p>


2021 ◽  
Vol 7 (3) ◽  
pp. 209-219
Author(s):  
Iris J Holzleitner ◽  
Alex L Jones ◽  
Kieran J O’Shea ◽  
Rachel Cassar ◽  
Vanessa Fasolt ◽  
...  

Abstract Objectives A large literature exists investigating the extent to which physical characteristics (e.g., strength, weight, and height) can be accurately assessed from face images. While most of these studies have employed two-dimensional (2D) face images as stimuli, some recent studies have used three-dimensional (3D) face images because they may contain cues not visible in 2D face images. As equipment required for 3D face images is considerably more expensive than that required for 2D face images, we here investigated how perceptual ratings of physical characteristics from 2D and 3D face images compare. Methods We tested whether 3D face images capture cues of strength, weight, and height better than 2D face images do by directly comparing the accuracy of strength, weight, and height ratings of 182 2D and 3D face images taken simultaneously. Strength, height and weight were rated by 66, 59 and 52 raters respectively, who viewed both 2D and 3D images. Results In line with previous studies, we found that weight and height can be judged somewhat accurately from faces; contrary to previous research, we found that people were relatively inaccurate at assessing strength. We found no evidence that physical characteristics could be judged more accurately from 3D than 2D images. Conclusion Our results suggest physical characteristics are perceived with similar accuracy from 2D and 3D face images. They also suggest that the substantial costs associated with collecting 3D face scans may not be justified for research on the accuracy of facial judgments of physical characteristics.


e-Polymers ◽  
2021 ◽  
Vol 21 (1) ◽  
pp. 346-354
Author(s):  
Guoquan Qi ◽  
Hongxia Yan ◽  
Dongtao Qi ◽  
Houbu Li ◽  
Lushi Kong ◽  
...  

Abstract The chapter deals with the performance evaluation of the polyethylene of raised temperature resistance (PE-RT) and polyethylene (PE) using autoclave test under sour oil and gas medium conditions. The analyses of performance changes showed that PE-RT has good media resistance at 60°C. As the temperature increases, its mechanical properties decrease, accompanied by an increase in weight. Comparative analyses showed that no matter what temperature conditions are, PE-RT media resistance is better than PE80. The better media resistance of PE-RT depends on its higher degree of branching. Short branches are distributed between the crystals to form a connection between the crystals, thereby improving its heat resistance and stress under high-temperature conditions. PE-RT forms an excellent three-dimensional network structure through copolymerization, ensuring that it has better media resistance than PE80. However, the mechanical performance will be attenuated due to the high service temperature.


2021 ◽  
Vol 3 (2) ◽  
Author(s):  
Yangyang Gu ◽  
Peng Dai ◽  
Wen Zhang ◽  
Zhanwen Su

AbstractIn this work, we demonstrated a simple method for preparing three-dimensional interconnected carbon nanofibers (ICNF) derived from fish bone as an efficient and lightweight microwave absorber. The as-obtained ICNF exhibits excellent microwave absorption performance with a maximum reflection loss of –59.2 dB at the filler content of 15 wt%. In addition, the effective absorption bandwidth can reach 4.96 GHz at the thickness of 2 mm. The outstanding microwave absorption properties can be mainly ascribed to its well-defined interconnected nanofibers architecture and the doping of nitrogen atoms, which are also better than most of the reported carbon-based absorbents. This work paves an attractive way for the design and fabrication of highly efficient and lightweight electromagnetic wave absorbers.


2010 ◽  
Vol 37-38 ◽  
pp. 9-13
Author(s):  
Hong Xin Wang ◽  
Ning Dai

A non-iterative design method about high order intermittent mechanisms is presented. The mathematical principle is that a compound function produced by two basic functions, and then one to three order derivatives of the compound function are all zeroes when one order derivative of each basic function is zero at the same moment. The design method is that a combined mechanism is constructed by six bars; the displacement functions of the front four-bar and back four-bar mechanisms are separately built, let one order derivatives of two displacement functions separately be zero at the same moment, and then get geometrical relationships and solution on the intermittent mechanism. A design example shows that this method is simpler and transmission characteristics are better than optimization method.


2013 ◽  
Vol 13 (1) ◽  
pp. 18-28 ◽  
Author(s):  
Chao-Hung Lin ◽  
Jyun-Yuan Chen ◽  
Shun-Siang Hsu ◽  
Yun-Huan Chung

Tourist maps are designed to direct tourists to tourist attractions in unfamiliar areas. A well-designed tourist map can provide tourists with sufficient and intuitive information about places of interest. Thus, providing up-to-date information on places of interest and selecting their representative icons are fundamental and important in automatic generation of tourist maps. In this article, approaches for determining places of interest and for determining their representative icons are introduced. In contrast to general digital tourist maps that use text, simple shapes, or three-dimensional models, we use photos that offer abundant visual features of places of interest as icons in tourist maps. The photos are automatically extracted from a repository of photos downloaded from photo-sharing communities. Tourist attractions and their corresponding image icons are determined by means of photo voting and photo quality assessment. Qualitative analyses, including a user study and experiments in several areas with numerous tourist attractions, indicated that the proposed method can generate visually pleasant and elaborate tourist maps. In addition, the analyses indicated that the map produced by our method is better than maps generated by related methods and is comparable to hand-designed tourist maps.


Author(s):  
GUANGYI CHEN ◽  
TIEN D. BUI ◽  
ADAM KRZYZAK

The denoising of a natural signal/image corrupted by Gaussian white noise is a classical problem in signal/image processing. However, it is still in its infancy to denoise high dimensional data. In this paper, we extended Sendur and Selesnick's bivariate wavelet thresholding from two-dimensional (2D) image denoising to three-dimensional (3D) data cube denoising. Our study shows that bivariate wavelet thresholding is still valid for 3D data cubes. Experimental results show that bivariate wavelet thresholding on 3D data cube is better than performing 2D bivariate wavelet thresholding on every spectral band separately, VisuShrink, and Chen and Zhu's 3-scale denoising.


Sensors ◽  
2018 ◽  
Vol 18 (9) ◽  
pp. 2824 ◽  
Author(s):  
Kunpeng Feng ◽  
Jiwen Cui ◽  
Xun Sun ◽  
Hong Dang ◽  
Tangjun Shi ◽  
...  

Three-dimensional micro-scale sensors are in high demand in the fields of metrology, precision manufacturing and industry inspection. To extend the minimum measurable dimension and enhance the accuracy, a tapered four-cores fiber Bragg grating (FBG) probe is proposed. The sensing model is built to investigate the micro-scale sensing characteristics of this method and the design of the tapered stylus is found to influence the accuracy. Therefore, a π/2 phase-shift point is introduced into the FBGs comprised in the probe to suppress spectrum distortion and improve accuracy. Then, the manufacturing method based on capillary self-assembly is proposed to form the probe and the critical length to form a square array for four cylindrical fibers is verified to be effective for the tapered fibers. Experimental results indicate that the design of the tapered stylus can extend the minimum measurable dimension by twofold and has nearly no influence on its sensitivity. The three-dimensional measurement repeatability is better than 31.1 nm and the stability is better than 200 nm within once measuring process. Furthermore, the measurement precision of the three-dimensional micro-scale measurement results is less than 150 nm. It would be widely used in measuring micro-scale features for industry inspection or metrology.


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