scholarly journals UV Irradiation Chlorine Dioxide Photocatalytic Oxidation of Simulated Fuchsine Wastewater by UV-Vis and Online FTIR Spectrophotometric Method

2012 ◽  
Vol 2012 ◽  
pp. 1-7 ◽  
Author(s):  
Laishun Shi ◽  
Xiaomei Wang ◽  
Na Li ◽  
Chunlei Huai ◽  
Jie Liu
Keyword(s):  
Uv Irradiation ◽  
Chlorine Dioxide ◽  
Photocatalytic Oxidation ◽  
Oxidation Process ◽  
Degradation Process ◽  
Chemical Oxidation ◽  
Ftir Analysis ◽  
Analysis Technique ◽  
Degradation Reaction ◽  
Online Ftir

The photocatalyst TiO2/SiO2 was prepared and used for chlorine dioxide photocatalytic oxidation of simulated fuchsine wastewater under UV irradiation. The removal efficiency of fuchsine treated by photocatalytic oxidation process is higher than that of chemical oxidation process. By using UV-Vis and online FTIR analysis technique, the intermediates during the degradation process were obtained. The benzene ring in fuchsine was degraded into quinone and carboxylic acid and finally changed into carbon dioxide and water during the photocatalytic oxidation. The degradation reaction mechanism of fuchsine by UV irradiation chlorine dioxide photocatalytic oxidation was proposed based upon the experiment evidence.

scholarly journals One-step Oxidation of Total Organic Carbon, Total Nitrogen, and Total Phosphorous using Wet Chemical Oxidation

2020 ◽  
Vol 42 (12) ◽  
pp. 603-609
Author(s):  
Jeong-Hwan Choi ◽  
Dong-Hun Shin ◽  
Hye-Bin Kim ◽  
Jong-Gook Kim ◽  
Kitae Baek
Keyword(s):  
Organic Carbon ◽  
Total Organic Carbon ◽  
Total Nitrogen ◽  
Uv Irradiation ◽  
Oxidation Process ◽  
Irradiation Time ◽  
Suitable Condition ◽  
Chemical Oxidation ◽  
Total Phosphorous ◽  
Wet Chemical

Objective:This study proposed the simultaneous multi-oxidation of total organic carbon, total nitrogen, and total phosphorous using modified wet chemical oxidation method.Methods:The multi oxidation process was based on the dual radical system with sulfate and hydroxyl radicals. The sodium persulfate (Na2S2O8) and sodium hydroxide (NaOH) were activated at 40℃ and UV irradiation with 254 nm to generate the sulfate radical and hydroxyl radical. The organic matters were oxidized by the dual radicals, and TOC, TN, and TP values were compared with the control group.Results and Discussion:The dual radical system oxidized organic carbon to carbon dioxide effectively, and the TOC values were similar to the value obtained from the high-temperature combustion technique. However, the residual persulfate after oxidation process interfered the absorbance for TN and inhibit the complexation in TP measurement. The residual persulfate was effectively converted to sulfate by longer heating and UV irradiation, and the interferences were more sensitive to reaction temperature than UV irradiation time. As a result, a higher temperature condition was more effective and enhanced the applicability of multi-oxidation.Conclusions:The multi oxidation of TOC, TN, and TP was demonstrated by wet chemical oxidation, and the proposed method is expected to secure the sample and reduce the analytic time. However, the more suitable condition to enhance the accuracy of TOC, TN, and TP in the multi-oxidation system should be studied further.

Synthesis, characterization, and application of polyanisidines as efficient photostabilizers for poly(vinyl chloride) films

2019 ◽  
Vol 52 (6) ◽  
pp. 537-547
Author(s):  
Magdy W. Sabaa ◽  
Mohamed A Sanad ◽  
Mahmoud A Abd El-Ghaffar ◽  
Nourelhoda A Abdelwahab ◽  
Soha MA Sayed ◽  
...  
Keyword(s):  
Vinyl Chloride ◽  
Uv Irradiation ◽  
Oxidation Process ◽  
Irradiation Time ◽  
Chemical Oxidation ◽  
Polymeric Chain ◽  
Conductivity Measurements ◽  
Uv Absorber ◽  
Poly Vinyl Chloride ◽  
Pvc Film

Conducting polymers have great attention due to their electrical activity in π-electrons conjugation over backbone of the polymeric chain. These properties make them attractive for enormous applications. On that account, we prepared polyanisidines (PAs) derivatives ( ortho, meta, and para) by chemical oxidation process using ammonium peroxydisulfate as an initiator. The prepared PAs were characterized using various techniques. Moreover, conductivity measurements of PA derivatives showed that the ortho-derivative gave the highest value. The prepared PAs were investigated as photostabilizers for poly(vinyl chloride) (PVC) films. Different PVC films were prepared in the absence and the presence of PA derivatives and they were exposed to ultraviolet (UV) irradiation for 30 days. The gel weight % for irradiated PVC films was followed as a function of irradiation time. The results revealed that the blank PVC film (free PA derivatives) was completely degraded reaching 100% gel content. PVC films contain PA derivatives showed higher photostability than PVC blank film. A comparison between the investigated PA derivatives as UV stabilizers and Chimassorb commercial UV absorber was also investigated. PA derivatives showed better efficiency as UV stabilizers than the commercial one till 288 h of UV irradiation.

EFFICIENT DEGRADATION OF CLOFIBRIC ACID BY HETEROGENEOUS PHOTOCATALYTIC OXIDATION PROCESS

2019 ◽  
Vol 18 (8) ◽  
pp. 1683-1692 ◽  
Author(s):  
Lidia Favier ◽  
Lacramioara Rusu ◽  
Andrei Ionut Simion ◽  
Raluca Maria Hlihor ◽  
Mariana Liliana Pacala ◽  
...  
Keyword(s):  
Photocatalytic Oxidation ◽  
Oxidation Process ◽  
Clofibric Acid

scholarly journals Magnetic iron oxide/clay nanocomposites for adsorption and catalytic oxidation in water treatment applications

2020 ◽  
Vol 18 (1) ◽  
pp. 1148-1166
Author(s):  
Ganjar Fadillah ◽  
Septian Perwira Yudha ◽  
Suresh Sagadevan ◽  
Is Fatimah ◽  
Oki Muraza
Keyword(s):  
Iron Oxide ◽  
Water Treatment ◽  
Photocatalytic Oxidation ◽  
Low Cost ◽  
Synthesis Method ◽  
Chemical Oxidation ◽  
Magnetic Iron Oxide ◽  
Oxidation Processes ◽  
Recent Developments ◽  
Physical And Chemical

AbstractPhysical and chemical methods have been developed for water and wastewater treatments. Adsorption is an attractive method due to its simplicity and low cost, and it has been widely employed in industrial treatment. In advanced schemes, chemical oxidation and photocatalytic oxidation have been recognized as effective methods for wastewater-containing organic compounds. The use of magnetic iron oxide in these methods has received much attention. Magnetic iron oxide nanocomposite adsorbents have been recognized as favorable materials due to their stability, high adsorption capacities, and recoverability, compared to conventional sorbents. Magnetic iron oxide nanocomposites have also been reported to be effective in photocatalytic and chemical oxidation processes. The current review has presented recent developments in techniques using magnetic iron oxide nanocomposites for water treatment applications. The review highlights the synthesis method and compares modifications for adsorbent, photocatalytic oxidation, and chemical oxidation processes. Future prospects for the use of nanocomposites have been presented.

A review on TiO2-based composites for superior photocatalytic activity

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Wail Al Zoubi ◽  
Abbas Ali Salih Al-Hamdani ◽  
Baek Sunghun ◽  
Young Gun Ko
Keyword(s):  
Photocatalytic Activity ◽  
Organic Pollutants ◽  
Cost Efficiency ◽  
High Stability ◽  
Photocatalytic Oxidation ◽  
Oxidation Process ◽  
Ambient Conditions ◽  
Photoelectrochemical Activity ◽  
As Doping ◽  
Degradation Of Pollutants

Abstract Heterogeneous photocatalysts was a promising material for removing organic pollutants. Titanium dioxide (TiO2) was a suitable photocatalyst for its cost efficiency and high stability to reduce various pollutants. Enhancing TiO2 photocatalyst performance by doping with changed metals or non-metal ions and organic compounds have been reviewed. These methods could enhance photoelectrochemical activity via: (i) by a donor of electrons via electron-donor agents that would produce particular defects in TiO2 structure and capture transporters of charge; (ii) by reducing recombination rate of the charge transporters and increasing degradation of pollutants. This study investigates the modification approaches of TiO2 that comprise methods for overcoming the essential TiO2 restrictions and enhancing the photocatalytic degradation of organic pollutants. Consequently, it emphasized on the current progress of modified-TiO2 used for different pollutants in ambient conditions. Amendment techniques, such as inorganic and organic parts as doping, are studied. The reported experimental results obtained with the photocatalytic oxidation process for degrading organic pollutants were also collected and assessed.

Assessment of Tandem Venturi on Enhancement of Cavitational Chemical Reaction

2008 ◽  
Vol 131 (1) ◽  
Author(s):  
Hoseyn Sayyaadi
Keyword(s):  
Chemical Reaction ◽  
Oxidation Process ◽  
Flow Characteristics ◽  
Chemical Oxidation ◽  
Cavitation Number ◽  
Cavitating Flow ◽  
Hydrodynamic Cavitation ◽  
Operating Pressure ◽  
Local Pressures ◽  
Second Category

The collapsing phenomenon of cavitation bubbles generates extremely high local pressures and temperatures that can be utilized for the chemical oxidation process. This process is carried out in cavitation reactors. A Venturi tube is one of the most common forms of hydrodynamic cavitation reactors, which is suitable for industrial scale applications. In this work, the hydraulic performance and efficiency in chemical reaction of a new form of hydrodynamic cavitation reactors, which is called “tandem Venturi,” were studied and compared with the conventional type of the single Venturi. The tandem Venturi is used for enhancement of the chemical reaction of hydrodynamic cavitating flow. The reaction enhancement is useful especially for the reaction of aqueous solutions not containing volatile organic compounds (VOCs). The operating pressure, inlet pressure, flow rate, and consequently the cavitation number were controlled and systematically varied for both single and tandem Venturis. Moreover, a specified amount of H2O2 was injected into the flow as required. The effects of operating pressure and the cavitation number on cavitating flow characteristics for single and tandem Venturis were experimentally observed and the results were compared. In addition, the performance of the tandem-Venturi reactor for degradation of non-VOC contaminants (2-chlorophenol) was studied. Its performance was compared with the performance of a conventional Venturi reactor. Two different categories were conducted for the experiments. In the first category, the effect of the net cavitating flow on degradation of non-VOC for the single and tandem Venturis was compared. In the second category, the effect of H2O2 injection into the cavitating flow on degradation of non-VOC (“cavitation-oxidation” process) was studied. The performance of the single and tandem Venturis for the cavitation-oxidation process was compared. Further investigation was performed to assess the advantage of utilizing the tandem Venturi from the viewpoint of efficiency of the oxidation process. The results of the energy efficiency were compared with the corresponding efficiency of the single Venturi. Finally, the relationship between the main parameters of cavitation reaction flow with the chemical performance was discussed.

scholarly journals Photocatalytic Oxidation Process (UV/H2O2/ZnO) in the treatment and sterilization of dairy wastewater

2013 ◽  
Vol 35 (1) ◽  
Author(s):  
Priscila De Abreu ◽  
Erlon Lopes Pereira ◽  
Cláudio Milton Montenegro Campos ◽  
Fabiano Luiz Naves
Keyword(s):  
Photocatalytic Oxidation ◽  
Oxidation Process ◽  
Dairy Wastewater

Characterization and thermal degradation kinetics of thermoplastic polyimide based on BAPP

2017 ◽  
Vol 30 (7) ◽  
pp. 787-793 ◽  
Author(s):  
Xu Su ◽  
Yong Xu ◽  
Linshuang Li ◽  
Chaoran Song
Keyword(s):  
Thermogravimetric Analysis ◽  
Thermal Degradation ◽  
Degradation Kinetics ◽  
Degradation Process ◽  
Thermal Degradation Kinetics ◽  
Heating Rates ◽  
Step Method ◽  
Nitrogen Derivative ◽  
Degradation Reaction ◽  
Kinetics Of

Two kinds of thermoplastic polyimides (PIs) were synthesized via a two-step method with 2,2-bis[4-(4-aminophenoxy)phenyl]propane (BAPP), 4,4′-oxydianiline (ODA) diamine, and 3,3′,4,4′-benzophenonetetracarboxylic dianhydride (BTDA), and their thermal degradation kinetics was studied by thermogravimetric analysis at different heating rates under nitrogen. Derivative thermogravimetric analysis curves indicated a simple, single-stage degradation process in PI BTDA-BAPP and a two-stage degradation process in PI BTDA-ODA-BAPP. The activation energies ( Eas) of the thermal degradation reaction were determined by the Flynn–Wall–Ozawa and Kissinger–Akahira–Sunose methods without a knowledge of the kinetic reaction mechanism. By comparing the values of Ea and weight loss temperatures, it was demonstrated that the thermal stability of PI BTDA-ODA-BAPP was superior to that of PI BTDA-BAPP.

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