Vapor Associated with Mafic Magma and Controls on Its Composition

1989 ◽  
pp. 21-31
Keyword(s):  
2021 ◽  
Author(s):  
Barbara Cserép ◽  
Zoltán Kovács ◽  
Kristóf Fehér ◽  
Szabolcs Harangi

<p>Identification of trans-crustal magma reservoir processes beneath volcanoes is a crucial task to better understand the behaviour and possible future activities of volcanic systems. Detailed petrological investigations have a fundamental role in such studies. Dacitic magmas are usually formed in an upper crustal magma reservoir by complex open-system processes including crystal fractionation and magma mixing following recharge events. Conditions of such processes are usually constrained by crystal-scale studies, whereas there is much less information about the petrogenetic processes occurring in the lower crustal hot zone. Here we provide insight into such processes by new results on amphibole crystal clots found in dacitic pumices from an explosive volcanic suite of the Ciomadul volcano, the youngest one in eastern-central Europe.</p><p>Amphibole is a common mineral phase of the Ciomadul dacites, occuring as phenocrysts and antecrysts, but occasionally they also form crystal clots with an inner core of either pyroxene or olivine with high Mg-numbers. Olivine is observed mostly in the 160-130 ka lava dome rocks, whereas the younger explosive eruption products are characterised by orthopyroxene and clinopyroxene. Such mafic crystal clots are most common in the pumices of the earliest explosive eruptions, which occurred after long quiescence at 56-45 ka. The most common appearance has high-Mg pyroxene core (mg#: 0.76-0.92) rimmed by amphibole. Two types of amphibole are found in such clots: irregular zone of actinolite to magnesio-hornblende directly around orthopyroxene and high Mg-Al pargasitic amphibole as the outer zone. Several crystal clots contain smaller amphibole crystals with diffuse transition to clinopyroxene at the inner part and complexly zoned amphibole with biotite inclusions in the outer part. These amphibole and pyroxene have lower Mg-number (< 0.80), and higher MnO content (up to 0.52 wt%) than the most common type. In both cases, amphibole could be a peritectic product of earlier-formed pyroxenes, which reacted with water-rich melt at higher and lower temperatures, respectively. Actinolite to magnesio-hornblende at the contact represents a transitional phase between pyroxene and the newly formed amphibole. In a few cases, crystal clots contain amphibole inclusions in pyroxene macrocrysts. These amphiboles have a particular composition not yet reproduced by experiments: they have high mg# (>0.86), but low tetrahedral Al (0.9-1.0 apfu) and usually high Cr content (Cr<sub>2</sub>O<sub>3</sub> is up to 0.9 wt%), similar to the orthopyroxene and clinopyroxene hosts (0.26-0.71 and 0.78-0.89 wt%, respectively). We interpret these amphiboles as an early formed liquidus phase crystallized along with pyroxene from an ultra-hydrous mafic magma. Occasionally, crystal clots are complexly zoned amphibole macrocrysts with dispersed clinopyroxene inclusions. The amphibole has a wide compositional range, usually with high Mg-Al pargasitic core. These amphiboles could have formed by peritectic reaction between clinopyroxene and a water-rich melt.</p><p>The observed mafic crystal clots in the dacites indicate the presence of strongly hydrous mafic magmas accumulated probably at the crust-mantle boundary. During mafic recharge, volatile transfer may contribute to the crystal mush rejuvenation at shallow depth and triggering explosive eruptions.</p><p>This research was financed by the Hungarian National Research, Development and Innovation Fund (NKFIH) within K135179 project.</p>


Geosphere ◽  
2021 ◽  
Author(s):  
S.J. Seaman ◽  
M.L. Williams ◽  
K.E. Karlstrom ◽  
P.C. Low

Recognition of fundamental tectonic boundaries has been extremely difficult in the (>1000-km-wide) Proterozoic accretionary orogen of southwestern North America, where the main rock types are similar over large areas, and where the region has experienced multiple postaccretionary deformation events. Discrete ultramafic bodies are present in a number of areas that may mark important boundaries, especially if they can be shown to represent tectonic fragments of ophiolite complexes. However, most ultramafic bodies are small and intensely altered, precluding petrogenetic analysis. The 91-Mile peridotite in the Grand Canyon is the largest and best preserved ultramafic body known in the southwest United States. It presents a special opportunity for tectonic analysis that may illuminate the significance of ultramafic rocks in other parts of the orogen. The 91-Mile peridotite exhibits spectacular cumulate layering. Contacts with the surrounding Vishnu Schist are interpreted to be tectonic, except along one margin, where intrusive relations have been interpreted. Assemblages include olivine, clinopyroxene, orthopyroxene, magnetite, and phlogopite, with very rare plagioclase. Textures suggest that phlogopite is the result of late intercumulus crystallization. Whole-rock compositions and especially mineral modes and compositions support derivation from an arc-related mafic magma. K-enriched subduction-related fluid in the mantle wedge is interpreted to have given rise to a K-rich, hydrous, high-pressure partial melt that produced early magnetite, Al-rich diopside, and primary phlogopite. The modes of silicate minerals, all with high Mg#, the sequence of crystallization, and the lack of early plagioclase are all consistent with crystallization at relatively high pressures. Thus, the 91-Mile peridotite body is not an ophiolite fragment that represents the closure of a former ocean basin. It does, however, mark a significant tectonic boundary where lower-crustal arc cumulates have been juxtaposed against middle-crustal schists and granitoids.


2013 ◽  
Vol 29 ◽  
pp. 1-24 ◽  
Author(s):  
Brian G.J. Upton

The 1300–1140 Ma Gardar period in South Greenland involved continental rifting, sedimentation and alkaline magmatism. The latest magmatism was located along two parallel rift zones, Isortoq–Nunarsuit in the north and the Tuttutooq–Ilimmaasaq–Narsarsuaq zone in the south addressed here. The intrusive rocks crystallised at a depth of troctolitic gabbros. These relatively reduced magmas evolved through marked iron enrichment to alkaline salic differentiates. In the Older giant dyke complex, undersaturated augite syenites grade into sodalite foyaite. The larger, c . 1163 Ma Younger giant dyke complex (YGDC) mainly consists of structureless troctolite with localised developments of layered cumulates. A layered pluton (Klokken) is considered to be coeval and presumably comagmatic with the YGDC. At the unconformity between the Ketilidian basement and Gardar rift deposits, the YGDC expanded into a gabbroic lopolith. Its magma may represent a sample from a great, underplated mafic magma reservoir, parental to all the salic alkaline rocks in the southern rift. The bulk of these are silica undersaturated; oversaturated differentiates are probably products of combined fractional crystallisation and crustal assimilation. A major dyke swarm 1–15 km broad was intruded during declining crustal extension, with decreasing dyke widths and increasing differentiation over time. Intersection of the dyke swarm and E–W-trending sinistral faults controlled the emplacement of at least three central complexes (Narssaq, South Qôroq and early Igdlerfigssalik). Three post-extensional complexes (Tugtutôq, Ilímaussaq and late Igdlerfigssalik) along the former rift mark the end of magmatism at c . 1140 Ma. The latter two complexes have oblate plans reflecting ductile, fault-related strain. The Tugtutôq complex comprises quartz syenites and alkali granites. The Ilímaussaq complex mainly consists of nepheline syenite crystallised from highly reduced, Fe-rich phonolitic peralkaline (agpaitic) magma, and resulted in rocks with very high incompatible element concentrations. Abundant anorthositic xenoliths in the mafic and intermediate intrusions point to a large anorthosite protolith at depth which is considered of critical importance in the petrogenesis of the salic rocks. Small intrusions of aillikite and carbonatite may represent remobilised mantle metasomites. The petrological similarity between Older and Younger Gardar suites implies strong lithospheric control of their petrogenesis. The parental magmas are inferred to have been derived from restitic Ketilidian lithospheric mantle, metasomatised by melts from subducting Ketilidian oceanic crust and by small-scale melt fractions associated with Gardar rifting. There are numerous analogies between the southern Gardar rift and the Palaeogene East African rift.


Author(s):  
Scott A. Barboza ◽  
George W. Bergantz

ABSTRACT:Dehydration melting of crustal rocks may commonly occur in response to the intrusion of mafic magma in the mid- or lower crust. However, the relative importance of melt buoyancy, shear or dyking in melt generation and extraction under geologically relevant conditions is not well understood. A numerical model of the partial melting of a metapelite is presented and the model results are compared with the Ivrea-Verbano Zone in northern Italy. The numerical model uses the mixture theory approach to modelling simultaneous convection and phase change and includes special ramping and switching functions to accommodate the rheology of crystal-melt mixtures in accordance with the results of deformation experiments. The model explicitly includes both porous media flow and thermally and compositionally driven bulk convection of a restitecharged melt mass. A range of melt viscosity and critical melt fraction models is considered. General agreement was found between predicted positions of isopleths and those from the Ivrea-Verbano Zone. Maximum melt velocities in the region of porous flow are found to be 1 × 10−7 and 1 × 10−1m per year in the region of viscous flow. The results indicate that melt buoyancy alone may not be a sufficient agent for melt extraction and that extensive, vigorous convection of partially molten rocks above mafic bodies is unlikely, in accord with direct geological examples.


2020 ◽  
Vol 177 (5) ◽  
pp. 965-980
Author(s):  
Robert J. Stern ◽  
Kamal Ali ◽  
Paul D. Asimow ◽  
Mokhles K. Azer ◽  
Matthew I. Leybourne ◽  
...  

We analysed gabbroic and dioritic rocks from the Atud igneous complex in the Eastern Desert of Egypt to understand better the formation of juvenile continental crust of the Arabian–Nubian Shield. Our results show that the rocks are the same age (U–Pb zircon ages of 694.5 ± 2.1 Ma for two diorites and 695.3 ± 3.4 Ma for one gabbronorite). These are partial melts of the mantle and related fractionates (εNd690 = +4.2 to +7.3, 87Sr/86Sri = 0.70246–0.70268, zircon δ18O ∼ +5‰). Trace element patterns indicate that Atud magmas formed above a subduction zone as part of a large and long-lived (c. 60 myr) convergent margin. Atud complex igneous rocks belong to a larger metagabbro–epidiorite–diorite complex that formed as a deep crustal mush into which new pulses of mafic magma were periodically emplaced, incorporated and evolved. The petrological evolution can be explained by fractional crystallization of mafic magma plus variable plagioclase accumulation in a mid- to lower crustal MASH zone. The Atud igneous complex shows that mantle partial melting and fractional crystallization and plagioclase accumulation were important for Cryogenian crust formation in this part of the Arabian–Nubian Shield.Supplementary material: Analytical methods and data, calculated equilibrium mineral temperatures, results of petrogenetic modeling, and cathodluminesence images of zircons can be found at https://doi.org/10.6084/m9.figshare.c.4958822


2010 ◽  
Vol 47 (2) ◽  
pp. 103-120 ◽  
Author(s):  
Georgia Pe-Piper ◽  
David J.W. Piper ◽  
Basilios Tsikouras

The late Neoproterozoic Frog Lake pluton, in the Avalon terrane of the Cobequid Highlands, Nova Scotia, consists predominantly of hornblende gabbro. It shows petrographic similarities to water-rich mafic intrusions known as appinites that are present in some collisional orogens. This study aims to further understanding of the origin of appinitic intrusions. In the field, the main hornblende gabbro was intruded between screens of metasedimentary country rock that is of upper greenschist metamorphic grade. The contacts appear to have been pathways for magma of gabbroic, tonalitic–granodioritic, and granitic composition that carried enclaves of gabbroic lithologies. Some of these magmas had a high volatile content, resulting in abundance of hydrous mineral phases, pegmatites, and diffuse felsic segregations. These varied rocks in the contact zones experienced progressive shear resulting in syn-magmatic deformation. Low-Ti hornblende gabbros have trace-element abundances similar to subduction-related low-K mafic rocks, including some enrichment in large-ion lithophile elements and marked relative depletion in Nb and Y. High-Ti hornblende gabbros and pyroxene–mica gabbro show more alkaline characteristics, with higher amounts of Nb, Y, P2O5, and high-field-strength elements. Tonalite and granite veins are geochemically similar to volcanic-arc granite. Comparison with appinites in the literature suggests that the Frog Lake pluton represents a deeper structural level than most appinites. The Frog Lake appinites were part of the feeder system to back-arc volcanic rocks of the Jeffers Group. Comparison with other appinites also leads to the conclusion that there is not a single type of “appinitic magma”: different appinitic plutons range in composition from low-K calc-alkaline to shoshonitic. The essential characteristic is a water-rich mafic magma. Appinites occur in settings undergoing crustal-scale strike-slip shear, where the faults allow rapid rise of mafic magma to shallow crustal levels.


1999 ◽  
Vol 36 (9) ◽  
pp. 1435-1448 ◽  
Author(s):  
CSJ Shaw ◽  
G M Young ◽  
C M Fedo

Sudbury breccias are commonly attributed to meteoritic impact at about 1.85 Ga in the vicinity of the Sudbury Igneous Complex. In the Whitefish Falls area, about 75 km southwest of Sudbury, similar breccias are widely developed in argillites of the ~2.3 Ga Gowganda Formation. There is abundant evidence of "soft sediment" deformation of the Huronian sediments in the form of complex "fault" contacts, clastic dyke intrusions, and chaotic folding. These movements appear to have been penecontemporaneous with intrusion of highly irregular diabase bodies, which are interpreted as being older than the ~2.2 Ga Nipissing diabase. Complex shapes of diabase bodies and highly irregular contact relationships between diabase and argillites, including intrusions of sediment veins into diabase, support intrusion of the diabase into incompletely consolidated sediments. These data, together with chemical evidence of mixing of diabase, argillite, and other materials in the breccia bodies, suggest that the breccias at Whitefish Falls may have formed as a result of interaction between hot mafic magma and semiconsolidated, water-rich mud, more than 350 Ma prior to formation of the Sudbury Igneous Complex and attendant phenomena that are presumed to be impact related.


2006 ◽  
Vol 143 (6) ◽  
pp. 887-903 ◽  
Author(s):  
R. J. ROBERTS ◽  
F. CORFU ◽  
T. H. TORSVIK ◽  
L. D. ASHWAL ◽  
D. M. RAMSAY

The Seiland Igneous Province (SIP) of northern Norway comprises a suite of mainly gabbroic plutons, with subordinate ultramafic, syenitic and felsic intrusions. Several intrusions from the Seiland Igneous Province have been dated by ID-TIMS U–Pb zircon and monazite analyses. The Hasvik Gabbro on the island of Sørøy, previously assigned an age of 700±33 Ma by Sm–Nd, yields a U–Pb zircon age of 562±6 Ma, within error of the Storelv Gabbro (569±5 Ma) and a diorite associated with the Breivikbotn Gabbro (571±4 Ma). Various intrusions on the Øksfjord peninsula give nearly identical ages of 565±9 Ma (gabbro), 566±4 Ma (monzonite), 565±5 Ma (monzodiorite), 570±9 Ma (norite), and 566±1 Ma (orthopyroxenite). These ages overlap with those from Sørøy, and define a single and short-lived period of gabbroic (to felsic) magmatism for the region between 570 and 560 Ma, pre-dating a subordinate episode of alkalic magmatism at 530–520 Ma. The U–Pb ages contradict the previous geochronological interpretation for the Finnmark area, which implied a period of 250 m.y. for the emplacement of the SIP intrusions. The new age data also clearly distinguish the Seiland intrusions, emplaced into the Sørøy Group metasediments of the Kalak Nappe Complex, from several older granitic intrusions (c. 850 to 600 Ma) that cut the Sørøy Group farther east and south. The coincident ages of the different Seiland intrusive bodies also contradict the previous structural model for the area, which posits that the different gabbro bodies were emplaced at intervals, with compressional deformation affecting the gabbros between periods of intrusion. The short time span between the main plutonic phases strongly suggests that the mechanism for the emplacement of mafic magma operated in a single, probably extensional, tectonic regime. The mafic intrusions were later deformed and metamorphosed to at least amphibolite facies, most likely by the Scandian (420 Ma) phase of the Caledonian Orogeny.


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