scholarly journals The Teena Zn-Pb Deposit (McArthur Basin, Australia). Part I: Syndiagenetic Base Metal Sulfide Mineralization Related to Dynamic Subbasin Evolution

2021 ◽  
Author(s):  
N. Hayward ◽  
J. M. Magnall ◽  
M. Taylor ◽  
R. King ◽  
N. McMillan ◽  
...  

Abstract Divergent genetic models have been proposed for clastic dominant (CD-type) massive sulfide Zn-Pb mineralization in the Proterozoic Carpentaria Zn Province. Due to varying degrees of tectonic overprint, it has been difficult to accurately constrain structural and paragenetic timing aspects of the CD-type genetic model, and the most basic timing constraints (syngenetic vs. epigenetic, synextension vs. syninversion) remain debated. The recently discovered Teena Zn-Pb deposit is hosted by an exceptionally well preserved subbasin that permits relative timing relationships to be well defined. Using a combination of geophysical, structural, sedimentological, and petrographic datasets, a new model for subbasin development and syndiagenetic hydrothermal replacement mineralization is developed for the Teena mineral system. At Teena, sulfide mineralization was deposited from lateral fluid flow beneath an impermeable seal several hundred meters below the paleosurface and maximum flood surface, after formation of fine-grained diagenetic pyrite (py1) and dolomite nodules. Sulfide mineralization resulted from syndiagenetic carbonate replacement and pore space cementation where thermochemical sulfate reduction took place. The sulfide mineralization is therefore partly cospatial but not cogenetic with its thick pyritic hanging wall, and its lateral alteration footprint is much smaller than predicted by sedimentary exhalative (SEDEX) models. An additional zone of low-grade Zn-Pb mineralization in the footwall W-Fold Shale Member represents a different style of mineralization not previously reported for Carpentaria CD-type Zn deposits: it is associated with strata-bound lenses of hydrothermal dolomite (HTD) that formed by both replacement and carbonate dissolution and infill, which yielded diverse cavity-infill textures that include coarse-bladed dolomite fans cemented by interstitial sphalerite, dolomite, and quartz. Volumetrically minor Zn mineralization is also present in a fault conduit hydrothermal breccia and in hanging-wall synorogenic vein sets derived by hydrothermal leaching and remobilization of Zn from the underlying mineralized zones. Whereas both the Teena and nearby McArthur River Zn-Pb deposits are located along the northern margin of the 3rd-order Hot Spring-Emu subbasin, they formed in separate 4th-order subbasins in association with local extensional growth faults. Growth fault movement in the Teena subbasin was initiated during deposition of the W-Fold Shale Member and persisted episodically until a weak structural disconformity associated with sedimentary facies regression developed in the Upper HYC unit. Shifting patterns in depocenter location, sedimentary facies development, mineralization, and alteration zonation are attributed to progressive growth and linkage of segments of a regionally anomalous ENE-trending, synsedimentary fault zone. Similar patterns of extensional subbasin development were repeated in other Zn-mineralized subbasins throughout the River supersequence across the northern Carpentaria Zn Province, and formed in response to a short-lived episode of north-northwest–south-southeast regional extension around ca 1640 ± 5 Ma, triggered by far-field subduction events.

Minerals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 254
Author(s):  
Steven P. Hollis ◽  
Sabri Foury ◽  
Stefano Caruso ◽  
Sean Johnson ◽  
Vitor Barrote ◽  
...  

With new advances in rapid-acquisition geochemical and hyperspectral techniques, exploration companies are now able to detect subtle halos surrounding orebodies at minimal expense. The Nimbus Ag-Zn-(Au) deposit is unique in the Archean Yilgarn Craton of Western Australia. Due to its mineralogy, alteration assemblages, geochemical affinity, and tectonic setting, it is interpreted to represent a shallow water (~650 mbsl) and low-temperature (<250 °C) volcanogenic massive sulfide (VMS) deposit with epithermal characteristics (i.e., a hybrid bimodal felsic deposit). We present a detailed paragenetic account of the Nimbus deposit, and establish lithogeochemical and hyperspectral halos to mineralization to aid exploration. Mineralization at Nimbus is characterized by early units of barren massive pyrite that replace glassy dacitic lavas, and underlying zones of polymetallic sulfides that replace autoclastic monomict dacite breccias. The latter are dominated by pyrite-sphalerite-galena, a diverse suite of Ag-Sb ± Pb ± As ± (Cu)-bearing sulfosalts, minor pyrrhotite, arsenopyrite, and rare chalcopyrite. The main sulfosalt suite is characterized by pyrargyrite, and Ag-rich varieties of boulangerite, tetrahedrite, and bournonite. Zones of sulfide mineralization in quartz-sericite(±carbonate)-altered dacite are marked by significant mass gains in Fe, S, Zn, Pb, Sb, Ag, As, Cd, Ni, Cu, Ba, Co, Cr, Tl, Bi, and Au. Basaltic rocks show reduced mass gains in most elements, with zones of intense quartz-chlorite-carbonate±fuchsite alteration restricted to thick sequences of hyaloclastite, and near contacts with dacitic rocks. Broad zones of intense silica-sericite alteration surround mineralization in dacite, and are marked by high Alteration Index and Chlorite-Carbonate-Pyrite Index (CCPI) values, strong Na-Ca depletion, and an absence of feldspar (albite) in thermal infrared (TIR) data. White mica compositions are predominantly muscovitic in weakly altered sections of the dacitic footwall sequence. More paragonitic compositions are associated with zones of increased sericitization and high-grade polymetallic sulfide mineralization. Chlorite in dacitic rocks often occurs adjacent to zones of sulfide mineralization and is restricted to narrow intervals. Carbonate abundance is sporadic in dacite, but is most abundant outside the main zones of Na-Ca depletion. Basaltic rocks are characterized by strongly paragonitic white mica compositions, and abundant chlorite and carbonate. Shifts from Ca carbonates and Fe-rich chlorites to more Mg-rich compositions of both minerals occur in more intensely hydrothermally altered basaltic hyaloclastite, and near contacts with dacitic rocks. Hanging-wall polymict conglomerates are characterized by minor amounts of muscovitic to phengitic white mica (2205–2220 nm), and an absence of chlorite and carbonate alteration.


2017 ◽  
Vol 39 (4) ◽  
pp. 77-88
Author(s):  
B. SLOBODYAN ◽  
V. PAVLYSHYN ◽  
S. BONDARENKO ◽  
L. STEPANYUK ◽  
V. SYOMKA ◽  
...  

Geophysics ◽  
2001 ◽  
Vol 66 (1) ◽  
pp. 70-77 ◽  
Author(s):  
B. B. Bhattacharya ◽  
Dinesh Gupta ◽  
Buddhadeb Banerjee ◽  
Shalivahan

A mise‐a‐la‐masse survey was carried out in Bhukia area, Banswara district, Rajasthan, India for auriferous sulfide occurrences. This area was originally surveyed for copper mineralization. Exploratory drilling, however, proved it to be economically not viable. The area was reopened for geophysical surveys when grab samples indicated the presence of gold. Initial geophysical surveys for copper mineralization showed electromagnetic, induced polarization, and resistivity anomalies. At first, one borehole was drilled for gold exploration on the basis of initial geophysical surveys. It encountered massive sulfide mineralization in association with gold. Borehole logging and a mise‐a‐la‐masse survey were carried out in this borehole. Three further boreholes drilled on the basis of the mise‐a‐la‐masse results encountered massive sulfide mineralization in association with gold. One of the three boreholes, 100 m from the first borehole along strike, was used for another set of mise‐a‐la‐masse measurements. A composite equipotential map was prepared using the results of mise‐a‐la‐masse results of both the boreholes. The equipotential contours show a north‐northwest‐south‐southeast trend of mineralization. The boreholes drilled on the basis of the mise‐a‐la‐masse results have delineated a strike length of more than 500 m of gold‐bearing sulfide mineralization. The sulfide content ranges from 10 to 40% and gold concentration ranges from 2 to 6 ppm. The dip and plunge of the lode, as anticipated from the mise‐a‐la‐masse results, are toward the west and north, respectively. Mise‐a‐la‐masse surveys are continuing in the adjoining areas.


2021 ◽  
Author(s):  
Lars Rüpke ◽  
Zhikui Guo ◽  
Sven Petersen ◽  
Christopher German ◽  
Benoit Ildefonse ◽  
...  

Abstract Submarine massive sulfide deposits on slow-spreading ridges are larger and longer-lived than deposits at fast-spreading ridges1,2, likely due to more pronounced tectonic faulting creating stable preferential fluid pathways3,4. The TAG hydrothermal mound at 26°N on the Mid-Atlantic Ridge (MAR) is a typical example located on the hanging wall of a detachment fault5-7. It has formed through distinct phases of high-temperature fluid discharge lasting 10s to 100s of years throughout at least the last 50,000 years8 and is one of the largest sulfide accumulations on the MAR. Yet, the mechanisms that control the episodic behavior, keep the fluid pathways intact, and sustain the observed high heat fluxes of up to 1800 MW9 remain poorly understood. Previous concepts involved long-distance channelized high-temperature fluid upflow along the detachment5,10 but that circulation mode is thermodynamically unfavorable11 and incompatible with TAG's high discharge fluxes. Here, based on the joint interpretation of hydrothermal flow observations and 3-D flow modeling, we show that the TAG system can be explained by episodic magmatic intrusions into the footwall of a highly permeable detachment surface. These intrusions drive episodes of hydrothermal activity with sub-vertical discharge and recharge along the detachment. This revised flow regime reconciles problematic aspects of previously inferred circulation patterns and can be used as guidance to one critical combination of parameters that can generate substantive mineral systems.


2021 ◽  
Author(s):  
Filipa Luz ◽  
António Mateus ◽  
Ezequiel Ferreira ◽  
Colombo G. Tassinari ◽  
Jorge Figueiras

Abstract The boundary in the Iberian Pyrite Belt is a world-class metallogenic district developed at the Devonian-Carboniferous boundary the Iberian Variscides that currently has seven active mines: Neves Corvo (Cu-Zn-Sn) and Aljustrel (Cu-Zn) in Portugal, and Riotinto (Cu), Las Cruces (Cu), Aguas Teñidas (Cu-Zn-Pb), Sotiel-Coronada (Cu-Zn-Pb), and La Magdalena (Cu-Zn-Pb) in Spain. The Iberian Pyrite Belt massive sulfide ores are usually hosted in the lower sections of the volcano-sedimentary complex (late Famennian to late Visean), but they also occur in the uppermost levels of the phyllite-quartzite group at the Neves Corvo deposit, stratigraphically below the volcano-sedimentary complex. A Pb-Nd-Sr isotope dataset was obtained for 98 Iberian Pyrite Belt metapelite samples (from Givetian to upper Visean), representing several phyllite-quartzite group and volcano-sedimentary complex sections that include the footwall and hanging-wall domains of ore horizons at the Neves Corvo, Aljustrel, and Lousal mines. The combination of whole-rock Nd and Sr isotopes with Th/Sc ratios shows that the siliciclastic components of Iberian Pyrite Belt metapelites are derived from older quartz-feldspathic basement rocks (–11 ≤ εNdinitial(i) ≤ –8 and (87Sr/86Sr)i up to 0.727). The younger volcano-sedimentary complex metapelites (upper Tournaisian) often comprise volcanic-derived constituents with a juvenile isotopic signature, shifting the εNdi up to +0.2. The Pb isotope data confirm that the phyllite-quartzite group and volcano-sedimentary complex successions are crustal reservoirs for metals found in the deposits. In Neves Corvo, where there is more significant Sn- and Cu-rich mineralization, the higher (206Pb/204Pb)i and (207Pb/204Pb)i values displayed by phyllite-quartzite group and lower volcano-sedimentary complex metapelites (up to 15.66 and 18.33, respectively) suggest additional contributions to the metal budget from a deeper and more radiogenic source. The proximity to Iberian Pyrite Belt massive sulfide ore systems hosted in metapelite successions is observed when (207Pb/204Pb)i &gt;15.60 and Fe2O3/TiO2 or (Cu+Zn+Pb)/Sc &gt;10. These are important criteria that should be considered in geochemical exploration surveys designed for the Iberian Pyrite Belt.


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