Development of Cation Exchange Membranes for Electrochemical Bunsen Reactions by Radiation–Induced Graft Polymerization

MEMBRANE ◽  
2016 ◽  
Vol 41 (3) ◽  
pp. 114-120
Author(s):  
Tetsuya Yamaki ◽  
Takehide Kodaira ◽  
Shin-ichi Sawada ◽  
Nobuyuki Tanaka ◽  
Shinji Kubo ◽  
...  
Keyword(s):  
Cation Exchange ◽  
Graft Polymerization ◽  
Radiation Induced

scholarly journals Effect of Alcohol Solvents for Glycidyl Methacrylate in Radiation-Induced Graft Polymerization on Performance of Cation-Exchange Porous Membranes.

MEMBRANE ◽  
2002 ◽  
Vol 27 (4) ◽  
pp. 196-201 ◽  
Author(s):  
Daisuke Okamura ◽  
Kyoichi Saito ◽  
Kazuyuki Sugita ◽  
Masao Tamada ◽  
Takanobu Sugo
Keyword(s):  
Cation Exchange ◽  
Glycidyl Methacrylate ◽  
Graft Polymerization ◽  
Porous Membranes ◽  
Radiation Induced ◽  
Alcohol Solvents

Highly hydrophilic cation exchange nonwoven with further modifiable epoxy group prepared by radiation-induced graft polymerization

2021 ◽  
Author(s):  
Xiaohan Pan ◽  
Jianhua Zu
Keyword(s):  
Cation Exchange ◽  
Glycidyl Methacrylate ◽  
Graft Polymerization ◽  
Epoxy Group ◽  
Grafting Polymerization ◽  
Radiation Induced

Novel cation exchange nonwoven PP-g-SSS/GMA containing epoxy and sulfonic groups was successfully prepared by radiation-induced simultaneous grafting polymerization attaching glycidyl methacrylate (GMA) and styrene sulfonic sodium (SSS) monomers onto polypropylene...

scholarly journals Preparation of Cation-Exchange Particle Designed for High-Speed Collection of Proteins by Radiation-Induced Graft Polymerization

2010 ◽  
Vol 21 (1) ◽  
pp. 29-34 ◽  
Author(s):  
Yuta SEKIYA ◽  
Yuichi SHIMODA ◽  
Daisuke UMENO ◽  
Kyoichi SAITO ◽  
Goro FURUMOTO ◽  
...  
Keyword(s):  
Cation Exchange ◽  
High Speed ◽  
Graft Polymerization ◽  
Exchange Particle ◽  
Radiation Induced

scholarly journals Radiation-Induced Asymmetric Grafting of Different Monomers into Base Films to Prepare Novel Bipolar Membranes

Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 2028
Author(s):  
Shin-ichi Sawada ◽  
Yasunari Maekawa
Keyword(s):  
Acrylic Acid ◽  
Anion Exchange ◽  
Graft Polymerization ◽  
The Other ◽  
Practical Applications ◽  
Bipolar Membranes ◽  
Graft Polymers ◽  
Grafting Reactions ◽  
Radiation Induced

We prepared novel bipolar membranes (BPMs) consisting of cation and anion exchange layers (CEL and AEL) using radiation-induced asymmetric graft polymerization (RIAGP). In this technique, graft polymers containing cation and anion exchange groups were introduced into a base film from each side. To create a clear CEL/AEL boundary, grafting reactions were performed from each surface side using two graft monomer solutions, which are immiscible in each other. Sodium p-styrenesulfonate (SSS) and acrylic acid (AA) in water were co-grafted from one side of the base ethylene-co-tetrafluoroethylene film, and chloromethyl styrene (CMS) in xylene was simultaneously grafted from the other side, and then the CMS units were quaternized to afford a BPM. The distinct SSS + AA- and CMS-grafted layers were formed owing to the immiscibility of hydrophilic SSS + AA and hydrophobic CMS monomer solutions. This is the first BPM with a clear CEL/AEL boundary prepared by RIAGP. However, in this BPM, the CEL was considerably thinner than the AEL, which may be a problem in practical applications. Then, by using different starting times of the first SSS+AA and second CMS grafting reactions, the CEL and AEL thicknesses was found to be controlled in RIAGP.

scholarly journals Radiation-Induced Graft Polymerization of Acrylonitrile onto Poly(vinyl chbride) Film

1973 ◽  
pp. 1188-1194
Author(s):  
Shoji HASHIMOTO ◽  
Akira UDAGAWA ◽  
Eiichi KAGEYAMA
Keyword(s):  
Graft Polymerization ◽  
Radiation Induced

Design of urea-permeable anion-exchange membrane by radiation-induced graft polymerization

1993 ◽  
Vol 81 (3) ◽  
pp. 295-305 ◽  
Author(s):  
William Lee ◽  
Kyoichi Saito ◽  
Shintaro Furusaki ◽  
Takanobu Sugo ◽  
Keizo Makuuchi
Keyword(s):  
Anion Exchange ◽  
Graft Polymerization ◽  
Anion Exchange Membrane ◽  
Radiation Induced ◽  
Exchange Membrane

scholarly journals Radiation-induced Grafting of Styrene onto Polyethylene Films for Preparation of Cation Exchange Membranes: Effect of Crosslinking+

2017 ◽  
Vol 2 (1) ◽  
Author(s):  
M. M. Nasef ◽  
H. Saidi ◽  
A. H. Yahaya
Keyword(s):  
Cation Exchange ◽  
Chemical Properties ◽  
Exchange Capacity ◽  
Gravimetric Analysis ◽  
Scanning Calorimetry ◽  
Swelling Properties ◽  
Ion Exchange Capacity ◽  
Physico Chemical ◽  
Styrene Divinylbenzene ◽  
Radiation Induced

Crosslinked cation exchange membranes bearing sulfonic acid groups (PE-g-PSSA/DVB) were prepared by radiationinduced grafting of styrene/divinylbenzene (DVB) mixtures onto low density polyethylene (PE) films followed by sulfonation reactions. The effect of addition of DVB (2 and 4%) on the grafting behavior and the physico-chemical properties of the membranes such as ion exchange capacity, swelling and ionic conductivity were evaluated incorrelation with grafting yield (Y%). The structural and thermal properties of the membranes were also studied using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA), respectively. Crosslinking with DVB was found to considerably affect the properties of the membranes in a way that reduces the swelling properties and enhances the chemical stability. The ion conductivity of the crosslinked membranes recorded a level of 10–2 S/cm at sufficient grafting yield (28%) despite the reduction caused by the formation of crosslinking structure. The results of this work suggest that membranes prepared in this study are potential alternatives for various electrochemical applications.

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