Semiconducting and electroluminescent cyclometalated platinum (II) complexes : from molecular functional materials to supramolecular architecture and self-assembled nanomaterials

2010 ◽  
Author(s):  
Mai-yan Yuen
Keyword(s):  
Functional Materials ◽  
Supramolecular Architecture ◽  
Self Assembled

Functionalised tetrathiafulvalene- (TTF-) macrocycles: recent trends in applied supramolecular chemistry

2018 ◽  
Vol 47 (15) ◽  
pp. 5614-5645 ◽  
Author(s):  
Atanu Jana ◽  
Steffen Bähring ◽  
Masatoshi Ishida ◽  
Sébastien Goeb ◽  
David Canevet ◽  
...  
Keyword(s):  
Supramolecular Chemistry ◽  
Functional Materials ◽  
Recent Trends ◽  
Self Assembled

Tetrathiafulvalene- (TTF-) based macrocyclic systems, cages and supramolecularly self-assembled 3D constructs have been extensively explored as functional materials for sensing and switching applications.

scholarly journals Functional Materials for Microsystems: Smart Self-Assembled Photochromic Films: Final Report

2001 ◽  
Author(s):  
ALAN R BURNS ◽  
DARRYL Y SASAKI ◽  
R W CARPICK ◽  
JOHN A SHELNUTT ◽  
C JEFFREY BRINKER
Keyword(s):  
Functional Materials ◽  
Final Report ◽  
Self Assembled

scholarly journals Nanostructured Luminescent Micelles: Efficient “Functional Materials” for Sensing Nitroaromatic and Nitramine Explosives

Photochem ◽  
2022 ◽  
Vol 2 (1) ◽  
pp. 32-57
Author(s):  
Shashikana Paria ◽  
Prasenjit Maity ◽  
Rafia Siddiqui ◽  
Ranjan Patra ◽  
Shubhra Bikash Maity ◽  
...  
Keyword(s):  
Drug Delivery ◽  
State Of The Art ◽  
Functional Materials ◽  
Review Article ◽  
Molecular Scaffolds ◽  
Protein Sensing ◽  
Luminescent Probes ◽  
Guest Binding ◽  
Fluorogenic Probes ◽  
Self Assembled

Luminescent micelles are extensively studied molecular scaffolds used in applied supramolecular chemistry. These are particularly important due to their uniquely organized supramolecular structure and chemically responsive physical and optical features. Various luminescent tags can be incorporated with these amphiphilic micelles to create efficient luminescent probes that can be utilized as “chemical noses” (sensors) for toxic and hazardous materials, bioimaging, drug delivery and transport, etc. Due to their amphiphilic nature and well-defined reorganized self-assembled geometry, these nano-constructs are desirable candidates for size and shape complementary guest binding or sensing a specific analyte. A large number of articles describing micellar fluorogenic probes are reported, which are used for cation/anion sensing, amino acid and protein sensing, drug delivery, and chemo-sensing. However, this particular review article critically summarizes the sensing application of nitroaromatic (e.g., trinitrotoluene (TNT), trinitrobenzene (TNB), trinitrophenol (TNP), dinitrobenzene (DNB), etc.) and nitramine explosives (e.g., 1,3,5-trinitro-1,3,5-triazinane, trivially named as “research department explosive” (RDX), 1,3,5,7-tetranitro-1,3,5,7-tetrazocane, commonly known as “high melting explosive” (HMX) etc.). A deeper understanding on these self-assembled luminescent “functional materials” and the physicochemical behavior in the presence of explosive analytes might be helpful to design the next generation of smart nanomaterials for forensic applications. This review article will also provide a “state-of-the-art” coverage of research involving micellar–explosive adducts demonstrating the intermolecular charge/electron transfer (CT/ET) process operating within the host–guest systems.

Supramolecular architectures in CoIIand CuIIcomplexes with thiophene-2-carboxylate and 2-amino-4,6-dimethoxypyrimidine ligands

2016 ◽  
Vol 72 (5) ◽  
pp. 442-450 ◽  
Author(s):  
Ammasai Karthikeyan ◽  
Packianathan Thomas Muthiah ◽  
Franc Perdih
Keyword(s):  
Hydrogen Bonds ◽  
Water Molecule ◽  
Coordination Polymers ◽  
Three Dimensional ◽  
Functional Materials ◽  
Supramolecular Architecture ◽  
Dinuclear Copper ◽  
One Dimensional ◽  
Wide Range ◽  
The One

The coordination chemistry of mixed-ligand complexes continues to be an active area of research since these compounds have a wide range of applications. Many coordination polymers and metal–organic framworks are emerging as novel functional materials. Aminopyrimidine and its derivatives are flexible ligands with versatile binding and coordination modes which have been proven to be useful in the construction of organic–inorganic hybrid materials and coordination polymers. Thiophenecarboxylic acid, its derivatives and their complexes exhibit pharmacological properties. Cobalt(II) and copper(II) complexes of thiophenecarboxylate have many biological applications, for example, as antifungal and antitumor agents. Two new cobalt(II) and copper(II) complexes incorporating thiophene-2-carboxylate (2-TPC) and 2-amino-4,6-dimethoxypyrimidine (OMP) ligands have been synthesized and characterized by X-ray diffraction studies, namely (2-amino-4,6-dimethoxypyrimidine-κN)aquachlorido(thiophene-2-carboxylato-κO)cobalt(II) monohydrate, [Co(C5H3O2S)Cl(C6H9N3O2)(H2O)]·H2O, (I), andcatena-poly[copper(II)-tetrakis(μ-thiophene-2-carboxylato-κ2O:O′)-copper(II)-(μ-2-amino-4,6-dimethoxypyrimidine-κ2N1:N3)], [Cu2(C5H3O2S)4(C6H9N3O2)]n, (II). In (I), the CoIIion has a distorted tetrahedral coordination environment involving one O atom from a monodentate 2-TPC ligand, one N atom from an OMP ligand, one chloride ligand and one O atom of a water molecule. An additional water molecule is present in the asymmetric unit. The amino group of the coordinated OMP molecule and the coordinated carboxylate O atom of the 2-TPC ligand form an interligand N—H...O hydrogen bond, generating anS(6) ring motif. The pyrimidine molecules also form a base pair [R22(8) motif]viaa pair of N—H...N hydrogen bonds. These interactions, together with O—H...O and O—H...Cl hydrogen bonds and π–π stacking interactions, generate a three-dimensional supramolecular architecture. The one-dimensional coordination polymer (II) contains the classical paddle-wheel [Cu2(CH3COO)4(H2O)2] unit, where each carboxylate group of four 2-TPC ligands bridges two square-pyramidally coordinated CuIIions and the apically coordinated OMP ligands bridge the dinuclear copper units. Each dinuclear copper unit has a crystallographic inversion centre, whereas the bridging OMP ligand has crystallographic twofold symmetry. The one-dimensional polymeric chains self-assembleviaN—H...O, π–π and C—H...π interactions, generating a three-dimensional supramolecular architecture.

Periodically ordered nanohetero inorganic structures of nanoparticles, nanorods and layers in a matrix from self-assembled block copolymers

2014 ◽  
Vol 1706 ◽  
Author(s):  
Hiroaki Wakayama ◽  
Hirotaka Yonekura ◽  
Yasuaki Kawai
Keyword(s):  
Block Copolymers ◽  
Self Assembly ◽  
Three Dimensional ◽  
Functional Materials ◽  
Domain Size ◽  
Great Promise ◽  
Layer By Layer ◽  
Simple Method ◽  
Self Assembled ◽  
Size And Morphology

ABSTRACTPeriodically ordered nanohetero inorganic structures offer great promise due to their unique electric, ionic, magnetic, and photonic properties. Many studies have focused on the formation of periodically ordered nano-hetero inorganic structures through layer-by-layer adsorption, sputtering, and self-assembly methods. However, the construction of three-dimensional periodically ordered nanohetero inorganic structures with desired sizes and morphologies remains a great challenge. We present a simple method for producing three-dimensional periodically ordered inorganic nanoheterostructures with controlled shape and size by replicating self-assembled block copolymers (BCPs) containing precursors of metals and metal oxides. Precursors were dissolved with BCPs in a solvent. Upon evaporation of the solvent, each precursor was selectively introduced into a separate polymer block. Application of an external magnetic field (10 T) to the BCP-precursor composites resulted in a phase transition of from spheres to hexagonal cylinders. Subsequent pyrolytic removal of the BCPs produced periodically ordered nanoheterostructures that were structural replicates of the precursor–BCP composites. Self-assembled nano-hetero inorganic structures of nanoparticles, nanorods and layers in a matrix were produced. The morphology and domain size can be tailored by controlling the molecular weight and relative block length of block copolymers. The controlled size and morphology of the inorganic nanoheterostructures demonstrate the method’s utility for producing highly functional materials.

Nanopatterning of Functional Materials by Gas Phase Pattern Deposition of Self-Assembled Molecular Thin Films in Combination with Electrodeposition

Langmuir ◽  
2011 ◽  
Vol 27 (20) ◽  
pp. 12760-12768 ◽  
Author(s):  
Antony George ◽  
A. Wouter Maijenburg ◽  
Minh Duc Nguyen ◽  
Michiel G. Maas ◽  
Dave H. A. Blank ◽  
...  
Keyword(s):  
Thin Films ◽  
Gas Phase ◽  
Functional Materials ◽  
Phase Pattern ◽  
Molecular Thin Films ◽  
Self Assembled

Synthesis and characterization of photochromic triethylene glycol-containing spiropyrans and their assembly in solution

2021 ◽  
Author(s):  
Yiwei Zhang ◽  
Maggie Ng ◽  
Michael Ho-Yeung Chan ◽  
Nathan Man-Wai Wu ◽  
Lixin Wu ◽  
...  
Keyword(s):  
Functional Materials ◽  
Triethylene Glycol ◽  
Synthesis And Characterization ◽  
Self Assembled

A series of photochromic triethylene glycol (TEG)-containing spiropyrans (SPs) has been synthesized, and systematic and controlled formation of their self-assembled functional materials has been achieved.

A novel self-assembled supramolecular architecture involving cation, anion and a calix[4]arene heteroditopic receptor

2002 ◽  
Vol 43 (41) ◽  
pp. 7311-7314 ◽  
Author(s):  
Alessandro Casnati ◽  
Chiara Massera ◽  
Nicola Pelizzi ◽  
Ivan Stibor ◽  
Evgueni Pinkassik ◽  
...  
Keyword(s):  
Supramolecular Architecture ◽  
Self Assembled

Peroxidase activity of the coronene bisimide supramolecular architecture and its applications in colorimetric sensing of H2O2 and glucose

2017 ◽  
Vol 5 (32) ◽  
pp. 6572-6578 ◽  
Author(s):  
Meiding Yang ◽  
Huipeng Zhou ◽  
Yongxin Li ◽  
Qingfeng Zhang ◽  
Juanmin Li ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Peroxidase Activity ◽  
Supramolecular Architecture ◽  
Colorimetric Sensing ◽  
Self Assembled ◽  
First Time

Distinct peroxidase-like catalytic activity of small organic probe self-assembled nanofibers is reported for the first time.

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