Investigation Of Asphaltene Deposition Tendency From Abu Dhabi Crude Oil/brine Mixture Induced By Electrodeposition

2014 ◽  
Author(s):  
Hadil Abu Khalifeh ◽  
Hadi Belhaj ◽  
Mohammed Haroun
Keyword(s):  
Crude Oil ◽  
Abu Dhabi ◽  
Asphaltene Deposition ◽  
Deposition Tendency

Asphaltene Deposition Induced by Carbon Oxide and its Influence on Displacement Efficiency

2012 ◽  
Vol 594-597 ◽  
pp. 2451-2454
Author(s):  
Feng Lan Zhao ◽  
Ji Rui Hou ◽  
Shi Jun Huang
Keyword(s):  
Crude Oil ◽  
Oil Recovery ◽  
Carbon Oxide ◽  
Viscosity Reduction ◽  
Core Flooding ◽  
Displacement Efficiency ◽  
Oil Composition ◽  
Oil Viscosity ◽  
Asphaltene Deposition ◽  
Total Oil

CO2is inclined to dissolve in crude oil in the reservoir condition and accordingly bring the changes in the crude oil composition, which will induce asphaltene deposition and following formation damage. In this paper, core flooding device is applied to study the effect of asphaltene deposition on flooding efficiency. From the flooding results, dissolution of CO2into oil leads to recovery increase because of crude oil viscosity reduction. But precipitated asphaltene particles may plug the pores and throats, which will make the flooding effects worse. Under the same experimental condition and with equivalent crude oil viscosity, the recovery of oil with higher proportion of precipitated asphaltene was relatively lower during the CO2flooding, so the asphltene precipitation would affect CO2displacement efficiSubscript textency and total oil recovery to some extent. Combination of static diffusion and dynamic oil flooding would provide basic parameters for further study of the CO2flooding mechanism and theoretical evidence for design of CO2flooding programs and forecasting of asphaltene deposition.

Study of Wax Deposition Rate in Waxy Crude Oil Pipeline

2013 ◽  
Vol 401-403 ◽  
pp. 891-894 ◽  
Author(s):  
Qing Lin Cheng ◽  
Xu Xu Wang ◽  
Xian Li Li ◽  
Wei Sun ◽  
Ling De Meng
Keyword(s):  
Crude Oil ◽  
Deposition Rate ◽  
Normal Operation ◽  
Wax Deposition ◽  
Waxy Crude Oil ◽  
Waxy Crude ◽  
Oil Pipeline ◽  
Oil Transportation ◽  
Different Seasons ◽  
Deposition Tendency

In waxy crude oil transportation process, wax crystals start to precipitate as the oil temperature drops to wax appearance point, and then form a network structure gradually which attaches to the wall. The problem of wax deposition seriously affects the normal operation of pipeline. Based on the wax deposition tendency coefficient method, combined with experimental data, the parameters related to wax deposition tendency coefficient is fitted, and the wax deposition rate equation of crude oil is determined finally. The variation law of wax deposition rate along the pipeline is analyzed, and the influence of different seasons and different throughput the on wax deposition rate is discussed subsequently.

Review of the Molecular Structure and Aggregation of Asphaltenes and Petroleomics

SPE Journal ◽  
2008 ◽  
Vol 13 (01) ◽  
pp. 48-57 ◽  
Author(s):  
Oliver C. Mullins
Keyword(s):  
Pressure Drop ◽  
Crude Oil ◽  
Common Knowledge ◽  
Oil Refining ◽  
Crude Oils ◽  
Strong Temperature Dependence ◽  
Specific Chemical ◽  
Asphaltene Content ◽  
Asphaltene Deposition ◽  
Asphaltic Materials

Summary Tremendous strides have been made recently in asphaltene science. Many advanced analytical techniques have been applied recently to asphaltenes, elucidating many asphaltene properties. The inability of certain techniques to provide correct asphaltene parameters has also been clarified. Longstanding controversies have been resolved. For example, molecular structural issues of asphaltenes have been resolved; in particular, asphaltene molecular weight is now known. The primary aggregation threshold has recently been established by a variety of techniques. Characterization of asphaltene interfacial activity has advanced considerably. The hierarchy of asphaltene aggregation has emerged into a fairly comprehensive picture, essentially in accord with the Yen model with the additional inclusion of certain constraints. Crude oil and asphaltene science is now poised to develop proper structure-function relations that are the defining objective of the new field: petroleomics. The purpose of this paper is to review these developments in order to present a more clear and accessible picture of asphaltenes, especially considering that the asphaltene literature is a bit opaque. Introduction The asphaltenes are a very important class of compounds in crude oils (Chilingarian and Yen 1978; Bunger and Li 1981; Sheu and Mullins 1995; Mullins and Sheu 1998; Mullins et al. 2007c). The asphaltenes represent a complex mixture of compounds and are defined by their solubility characteristics, not by a specific chemical classification. A common (laboratory) definition of asphaltenes is that they are toluene soluble, n-heptane insoluble. Other light alkanes are sometimes used to isolate asphaltenes. This solubility classification is very useful for crude oils because it captures the most aromatic portion of crude oil. As we will see, this solubility defintion also captures those molecular components of asphaltene that aggregate. Other carbonaceous materials such as coal do possess an asphaltene fraction, but that often will not correspond to the most aromatic fraction. Petroleum asphaltenes, the subject of this paper, can undergo phase transitions that are an impediment in the production of crude oil. Fig. 1 shows a picture of an asphaltene deposit in a pipeline; obviously, asphaltene deposition is detrimental to the production of oil. Immediately it becomes evident that different operational definitions apply for the term asphaltene in the field vs. the lab. Indeed, the field deposit is very enriched in n-heptane-insoluble, toluene-soluble materials, but this field asphaltene deposit is not identically the standard laboratory solubility class. It is common knowledge that a pressure drop on certain live crude oils (containing dissolved gas) can cause asphaltene flocculation, the first step in creating deposits that are seen in Fig. 1. Highly compressible, very undersaturated crude oils are most susceptible to asphaltene deposition problems with a pressure drop (de Boer et al. 1995). In depressurization flocculation, the character of the asphaltene flocs is dependent on the extent of pressure drop, suggesting some variations in the corresponding chemical composition (Hammami et al. 2000; Joshi et al. 2001). Comingling different oils can result in asphaltene precipitation that can resemble solvent precipitation. Asphaltenes are hydrogen-deficient compared to alkanes; thus, either hydrogen must be added or coke removed in crude oil refining to generate transportation fuels. Thus, asphaltene content lowers the economic value of crude oil. Increasing asphaltene content is associated with dramatically increasing viscosity, especially at room temperature; again, this is of operational concern. The strong temperature dependence of viscosity of asphaltic materials is one of their important properties that make them useful for paving and coating; application of asphaltic materials is facile at moderately high temperatures, while desired rheological properties are obtained at ambient temperatures.

Impact of Water Cut on Asphaltene Deposition Tendency

2014 ◽  
Author(s):  
J. Wang ◽  
T. Fan ◽  
J.S. Buckley ◽  
J.L. Creek
Keyword(s):  
Asphaltene Deposition ◽  
Water Cut ◽  
Deposition Tendency

Coiled Tubing Dewaxing Operations: Case Studies in Reduced Production Wells of Northeast India

2021 ◽  
Author(s):  
Ishaan Singh ◽  
Akash Ramesh Pathak ◽  
Juhi Kaushik ◽  
Bholanath Bandyopadhyay ◽  
Danny Aryo Wijoseno ◽  
...  
Keyword(s):  
Crude Oil ◽  
Northeast India ◽  
Outer Diameter ◽  
Fluid Temperature ◽  
Equipment Failure ◽  
Operational Parameters ◽  
Coiled Tubing ◽  
Asphaltene Deposition ◽  
Pumping Rates

Abstract Executing interventions in wells encrusted with wax is challenging because experience with global coiled tubing (CT) dewaxing operations is limited, and equipment failure and stuck pipe risks are high. With few jobs performed worldwide, CT dewaxing (hot oil circulation with CT) operations are largely unexplored. The deviated wells in a field in northeast India pose several challenges including completely seized wellbore due to paraffin/asphaltene deposition, previous failed well cleanout attempts, very slow and low bottomhole assembly (BHA) penetration, pumping corrosive and flammable low wax crude (LWC) through CT, high chances of CT getting stuck, and pumping heated 69°C LWC through the CT. This case study delivers insights about design, safety, and operational considerations for 1.5-in. CT dewaxing and nitrogen lift operations in a subhydrostatic well in the field. The objective of this CT dewaxing and nitrogen kickoff operation was to clear the well of paraffin/asphaltene/wax to 1600 m and activate it with nitrogen, and this paper describes solutions for cleaning out and nitrogen-lifting wells with declining production due to paraffin and asphaltene deposition. One well is described in this case study, but this approach can be used perform CT intervention in similar wells. For this case, simulations were sensitized to identify the best combination of pumping rates, CT speeds, and fluid temperature to remove deposits hindering BHA penetration. This study proposes prevention measures using appropriate grounding and procedures, which determine if the crude oil can be pumped through CT. By use of this methodology, 581 dewaxing runs have been performed in 78 wells. Extensive on-job experience and lessons learnt by performing this operation over the last 3 years bring excellent results and prevent misruns. In many cases, production has been restored from nil; several examples feature a fivefold improvement of productivity thanks to this intervention method. Optimized operational parameters such as CT speed, pumping rates, and the use of smaller outer diameter BHAs doubled operational efficiency during those operations. In addition, strict application of the recommendations prevented the occurrence of operational problems such as stuck CT, crude oil flashing, sand bridging, and equipment failure.

Preventing Asphaltene Deposition by Inhibitor Squeeze Injection: Case Studies from Giant Carbonate Abu Dhabi Fields

2021 ◽  
Author(s):  
Sameer Punnapala ◽  
Dalia Salim Abdullah ◽  
Mark Grutters ◽  
Zaharia Cristea ◽  
Hossam El Din Mohamed El Naggar ◽  
...  
Keyword(s):  
Implementation Strategy ◽  
Field Trials ◽  
Abu Dhabi ◽  
Complex Nature ◽  
Full Field ◽  
Oil Companies ◽  
Asphaltene Deposition ◽  
Proactive Measures ◽  
Intervention Costs ◽  
Performance Results

Abstract Asphaltene deposition is a notorious flow assurance problem faced by oil companies that causes production loss and large expenses for operators. The complex nature of asphaltenes and limited data available makes it challenging to develop a full field implementation strategy that is economically viable as well. Conducting asphaltene clean-up operations whenever wells get plugged up are the reactive approach to deal with asphaltene issues. However these approaches often result in prolonged well downtime, production losses and high well intervention costs. As part of proactive measures, chemical inhibitors were screened for formation squeeze and field trials conducted to assess their performance. Results from these trials helped to frame the full-field implementation strategy that is promising from a technical-economic standpoint. This paper describes the asphaltene mitigation journey of a major Abu Dhabi oil operator that resulted in multi-million dollar savings.

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