Memory of Prior Dynamic Strain History in Filled Rubbers
Abstract We recently discovered that particle-reinforced rubbers after being sheared (or aged) in oscillation at a frequency ƒa at a small strain γa (e.g., ∼1% strain) for time ta can often display a spectrum hole or drop in their dissipation spectra. The location of the hole depends on the aging strain amplitude γa. The depth of this hole is influenced by both the oscillatory aging frequency ƒa and the aging duration ta, and follows a simple power relationship of the product of ƒa and ta. Sequential shear at two strains reveals that when γa1>γa2 the resulting dynamic spectra appear to be a combination of that aged at γa1 and γa2, whereas for γa1>γa2, the resulting dynamic spectra only reflect the characteristic hole burning of the second strain after holding at γa2. This new memory effect occurs at very small strains in filled elastomers and involves material stiffening during the strain aging; both of those features are quite different from the Mullins effect. Also, this new memory is found to last for more than 10 days without any noticeable sign of disappearing.