Correlation of Vulcanization and Viscoelastic Properties of Nanocomposites Based on Natural Rubber and Different Nanofillers, with Molecular and Supramolecular Structure

2010 ◽  
Vol 83 (1) ◽  
pp. 16-34 ◽  
Author(s):  
Mithun Bhattacharya ◽  
Anil K. Bhowmick
Keyword(s):  
Natural Rubber ◽  
Rheological Properties ◽  
Supramolecular Structure ◽  
Carbon Nanofiber ◽  
Volume Fraction ◽  
Barrier Properties ◽  
Qualitative Description ◽  
Viscoelastic Parameters ◽  
Low Volume ◽  
And Performance

Abstract Elastomer nanocomposites reinforced with low volume fraction of nanofillers, such as nanoclays and carbon nanofibers, have long been known to possess significantly improved mechanical, thermal, dynamic mechanical, flame retardant, and barrier properties. The present work attempts to evaluate the effect of nanofillers (like modified and unmodified montmorillonite, sepiolite, carbon nanofiber, and carbon black) and their amount on vulcanization, as well as dynamic and rheological properties in the prevulcanization and postvulcanization stages. Upon using organomodified nanoclay, optimum cure time was reduced and cure rate index increased; whereas, in comparison, carbon nanofiber resulted in a slower cure. The influence of loading of some representative nanofillers on natural rubber was studied through qualitative description of critical dynamic viscoelastic parameters, which indicated the formation of supramolecular structure even at low volume fraction. The nanocomposite vulcanizates showed solidlike rheological behavior and upon implementation of dispersion techniques the activation energy of flow was reduced by around 60%. The knowledge of cure and rheological properties of the compounds, which evolves from the structure formation, can be utilized for assessing process optimization, cost reduction, and performance of the nanocomposites.

Elastomer Nanocomposites

2008 ◽  
Vol 81 (3) ◽  
pp. 384-469 ◽  
Author(s):  
Madhuchhanda Maiti ◽  
Mithun Bhattacharya ◽  
Anil K. Bhowmick
Keyword(s):  
Carbon Nanotubes ◽  
High Performance ◽  
Volume Fraction ◽  
Layered Silicate ◽  
Barrier Properties ◽  
Review Article ◽  
Layered Silicates ◽  
Structure And Properties ◽  
Uniform Dispersion ◽  
Low Volume

Abstract Recently, elastomer - nanocomposites reinforced with low volume fraction of nanofillers have attracted great interest due to their fascinating properties. The incorporation of nanofillers such as layered silicate clays, carbon nanotubes, nanofibers, calcium carbonate, metal oxides or silica nanoparticles into elastomers improves significantly their mechanical, thermal, dynamic mechanical, barrier properties, flame retardancy, etc. The properties of nanocomposites depend greatly on the chemistry of polymer matrices, nature of nanofillers, and the method in which they are prepared. The uniform dispersion of nanofillers in elastomer matrices is a general prerequisite for achieving desired mechanical and physical characteristics. In this review article, current developments in the field of elastomer nanocomposites reinforced with layered silicates, silica, carbon nanotubes, nanofibers and various other nanoparticles have been addressed. Attention has been paid to the structure and properties of such high-performance nanocomposites, along with the theories and models existing in this field.

Rheological Properties Influence Tackiness, Application and Performance of Nail Polish/Lacquer Formulations

2021 ◽  
pp. 109-150
Author(s):  
Leidy Nallely Jimenez ◽  
Carina D. V. Martínez Narváez ◽  
Chenxian Xu ◽  
Samantha Bacchi ◽  
Vivek Sharma
Keyword(s):  
Rheological Properties ◽  
Nail Polish ◽  
And Performance

scholarly journals Assessment of Graphene Oxide and Nanoclay Based Hybrid Filler in Chlorobutyl-Natural Rubber Blend for Advanced Gas Barrier Applications

Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1098
Author(s):  
Jibin Keloth Paduvilan ◽  
Prajitha Velayudhan ◽  
Ashin Amanulla ◽  
Hanna Joseph Maria ◽  
Allisson Saiter-Fourcin ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Carbon Black ◽  
Natural Rubber ◽  
Gas Permeability ◽  
Chemical Properties ◽  
Barrier Properties ◽  
Hybrid Filler ◽  
Physical And Chemical ◽  
Chlorobutyl Rubber ◽  
And Chemical Properties

Nanomaterials have engaged response from the scientific world in recent decades due to their exceptional physical and chemical properties counter to their bulk. They have been widely used in a polymer matrix to improve mechanical, thermal, barrier, electronic and chemical properties. In rubber nanocomposites, nanofillers dispersion and the interfacial adhesion between polymer and fillers influences the composites factual properties. In the present work, a comparison of the hybrid effects of carbon black with two different nanofillers (graphene oxide and nanoclay) was studied. The 70/30 composition of chlorobutyl rubber/natural rubber elastomer blend was taken as per the blend composition optimized from our previous studies. The hybrid effects of graphene oxide and nanoclay in dispersing the nanofillers were studied mainly by analyzing nanocomposite barrier properties. The results confirm that the combined effect of carbon black with graphene oxide and nanoclay could create hybrid effects in decreasing the gas permeability. The prepared nanocomposites which partially replace the expensive chlorobutyl rubber can be used for tyre inner liner application. Additionally, the reduction in the amount of carbon black in the nanocomposite can be an added advantage of considering the environmental and economic factors.

LOW CONCENTRATION LIMIT FOR A FLUID FLOW THROUGH A FILTER

1998 ◽  
Vol 08 (04) ◽  
pp. 623-643 ◽  
Author(s):  
SANJA MARUŠIĆ
Keyword(s):  
Asymptotic Behavior ◽  
Fluid Flow ◽  
Volume Fraction ◽  
Periodic Array ◽  
Concentration Limit ◽  
Global Flow ◽  
Low Concentration ◽  
Flow Through ◽  
Low Volume ◽  
Filtration Law

A fluid flow through an ∊-periodic array of obstacles distributed on a hypersurface (filter) is considered. The study of the asymptotic behavior as ∊→0 for two critical sizes of obstacles ∊ and ∊2 gives two different laws describing a global flow. In this paper we study the case of an intermediate obstacle size ∊β, 1 < β < 2 and we prove the continuity of the filtration law in the low-volume fraction limit.

Corrosion Inhibition of Mild Steel by Electrodeposited Poly(M-Aminophenol) Coating

2021 ◽  
Vol 317 ◽  
pp. 498-505
Author(s):  
Sabrina M. Yahaya ◽  
Mohamad Kamal Harun ◽  
Ismaliza Ismail ◽  
Rosmamuhamadani Ramli
Keyword(s):  
Mild Steel ◽  
Steel Surface ◽  
Electrochemical Impedance ◽  
Impedance Measurement ◽  
Barrier Properties ◽  
Electrical Circuit ◽  
Significant Drop ◽  
Mild Steel Surface ◽  
Barrier Resistance ◽  
And Performance

In this study, poly(m-aminophenol) (PMAP) coating was electrochemically synthesized by cyclic voltammetry (CV) on mild steel surface to investigate the effects of its barrier protection within the scope of its electrochemical impedance towards further oxidation of the mild steel substrates. The developed PMAP coating were characterized by Fourier Transform Infrared (FTIR) spectroscopy and Field Emission Scanning Electron Microscopy (FESEM). The barrier resistance ability of PMAP coating towards corrosion of mild steel was determined in 0.5 M aqueous sodium chloride solution (NaCl) at various immersion times by the electrochemical impedance spectroscopy (EIS). The barrier properties were interpreted through impedance measurement using Nyquist and Bode plots. Equivalent electrical circuit models derived from the plots were employed to describe the coating barrier behaviour and performance. Data obtained showed that, the oxidation peak of PMAP coating were observed at potential +1.0 V (Ag/AgCl). The micrograph of FESEM indicates the formation of a dense and continous PMAP coatings. In FTIR analyses, the presence of peak around 1082 cm-1 ascribed to C–O–C etheric linkage which supported the formation of electro polymerized PMAP coating on mild steel surface. EIS measurement revealed that, PMAP coatings experienced a significant drop in total impedance values with time followed by the development of an electrochemical reactions on coating/metal interface, which indicates the gradual degradation of the barrier resistance ability of the PMAP coatings.

Physical and rheological properties of epoxidized natural rubber modified bitumens

2014 ◽  
Vol 63 ◽  
pp. 242-248 ◽  
Author(s):  
Ramez A. Al-Mansob ◽  
Amiruddin Ismail ◽  
Aows N. Alduri ◽  
Che Husna Azhari ◽  
Mohamed Rehan Karim ◽  
...  
Keyword(s):  
Natural Rubber ◽  
Rheological Properties ◽  
Epoxidized Natural Rubber

scholarly journals Aggregation kinetics of irreversible patches coupled with reversible isotropic interaction leading to chains, bundles and globules

2018 ◽  
Vol 90 (6) ◽  
pp. 1085-1098 ◽  
Author(s):  
Isha Malhotra ◽  
Sujin B. Babu
Keyword(s):  
Self Assembly ◽  
Patch Size ◽  
Colloidal Particles ◽  
Volume Fraction ◽  
Interaction Strength ◽  
Colloidal System ◽  
Angle Distribution ◽  
Volume Fractions ◽  
Low Volume ◽  
A Chain

Abstract In the present study we are performing simulation of simple model of two patch colloidal particles undergoing irreversible diffusion limited cluster aggregation using patchy Brownian cluster dynamics. In addition to the irreversible aggregation of patches, the spheres are coupled with isotropic reversible aggregation through the Kern–Frenkel potential. Due to the presence of anisotropic and isotropic potential we have also defined three different kinds of clusters formed due to anisotropic potential and isotropic potential only as well as both the potentials together. We have investigated the effect of patch size on self-assembly under different solvent qualities for various volume fractions. We will show that at low volume fractions during aggregation process, we end up in a chain conformation for smaller patch size while in a globular conformation for bigger patch size. We also observed a chain to bundle transformation depending on the attractive interaction strength between the chains or in other words depending on the quality of the solvent. We will also show that bundling process is very similar to nucleation and growth phenomena observed in colloidal system with short range attraction. We have also studied the bond angle distribution for this system, where for small patches only two angles are more probable indicating chain formation, while for bundling at very low volume fraction a tail is developed in the distribution. While for the case of higher patch angle this distribution is broad compared to the case of low patch angles showing we have a more globular conformation. We are also proposing a model for the formation of bundles which are similar to amyloid fibers using two patch colloidal particles.

Finite deformation and fractional order viscoelasticity of an auxetic foam

2022 ◽  
pp. 1045389X2110643
Author(s):  
Eugenia Stanisauskis ◽  
Paul Miles ◽  
William Oates
Keyword(s):  
Fractional Order ◽  
Finite Deformation ◽  
Viscoelastic Behavior ◽  
Integer Order ◽  
Relaxation Effects ◽  
Viscoelastic Parameters ◽  
Rate Dependent ◽  
Improve Model ◽  
Model Predictions ◽  
And Performance

Auxetic foams exhibit novel mechanical properties due to their unique microstructure for improved energy-absorption and cavity expansion applications that have fascinated the scientific community since their inception. Given the advancements in material processing and performance of polymer open cell auxetic foams, there is a strong desire to fully understand the nonlinear rate-dependent deformation of these materials. The influence of nonlinear compressibility is introduced here along with relaxation effects to improve model predictions for different stretch rates and finite deformation regimes. The viscoelastic behavior of the material is analyzed by comparing fractional order and integer order calculus models. All results are statistically validated using maximum entropy methods to obtain Bayesian posterior densities for the hyperelastic, auxetic, and viscoelastic parameters. It is shown that fractional order viscoelasticity provides [Formula: see text]–[Formula: see text] improvement in prediction over integer order viscoelastic models when the model is calibrated at higher stretch rates where viscoelasticity is more significant.

Sign in / Sign up

Export Citation Format

Share Document