Online Electrical Conductivity as a Measure to Characterize the Carbon Black Dispersion in Oil Containing Rubber Compounds with a Different Polarity of Rubber

2004 ◽  
Vol 77 (5) ◽  
pp. 815-829 ◽  
Author(s):  
H. H. Le ◽  
I. Prodanova ◽  
S. Ilisch ◽  
H.-J. Radusch

Abstract The influence of viscosity, polarity of the rubber matrix and the types and contents of extender oil on the carbon black dispersion has been characterized using the online electrical conductivity measurement. A corresponding change of the online conductivity with the rubber infiltration and extent of carbon black dispersion has been observed. The infiltration rate increases with increasing polarity and decreasing viscosity of the rubber matrix, whereby the matrix polarity shows a stronger effect than the viscosity. The oil addition accelerates the infiltration process. This is caused by the reduction of the matrix viscosity and the intensification of the filler-matrix interaction. Oil addition affects the carbon black dispersion in non-polar rubber much more than in polar rubber. Furthermore, in non-polar rubber, polar oil shows a stronger effect than non-polar oil.

2019 ◽  
Vol 136 ◽  
pp. 01015
Author(s):  
Wei Chen ◽  
Jiarui Hu ◽  
Yi Xie ◽  
Hengyi Zhou ◽  
Chao Feng ◽  
...  

The effect of Fe and P (Ni and Si) on the microstructure and properties of Cu-10Zn alloys has been investigated using hardness test, electrical conductivity measurement, optical microscopy and transmission electron microscopy. γ-Fe precipitates formed during the aging process, but there is almost no effect of precipitation strengthening on the Cu-Zn-Fe-P alloy and sparsely Fe3P precipitates existed in the matrix. After homogenization treatment at 900°C for 2h, hot rolling by 80%, cold rolling by 80%, and ageing treatment at 400°C for 30min, Cu-Zn-Ni-Si alloy obtained good combinations of hardness (219.8HV) and electrical conductivity(28.2%IACS). Ni2Si precipitates formed during aging process and the crystal orientation relationship between matrix and precipitates is:(200)α || (100)δ, [100]α || [010]δ,. Compared with Cu-Zn-Fe-P, Cu-Zn-Ni-Si has finer grains, and the precipitation strengthening effect is more obvious.


Author(s):  
Yunfeng Dong ◽  
Morten Stendahl Jellesen ◽  
Rune Juul Christiansen ◽  
Jesper Hovelskov ◽  
Jorgen Sundgren ◽  
...  

2016 ◽  
Vol 697 ◽  
pp. 327-330 ◽  
Author(s):  
Ke Shan ◽  
Xing Min Guo ◽  
Feng Rui Zhai ◽  
Zhong Zhou Yi

Y0.06Sr0.94Ti0.6Fe0.4O3-δ-YSZ composites were prepared by mixing Y, Fe co-doped SrTiO3 (Y0.06Sr0.94Ti0.6Fe0.4O3-δ known as YSTF) and 8 mol% Y2O3 stabilized ZrO2 (YSZ) in different weight fractions. The phase stability, phase compatibility, microstructure and mixed ionic-electronic conductivity of composites were investigated. Phase analysis by XRD showed no clearly detectable secondary phases. The electrical conductivity measurement on the YSTF-YSZ composites showed a drastic decrease in total electrical and ionic conductivities when more than 10 wt% of YSZ was used in the composites. The total electrical conductivity was 0.102 S/cm for Y0.06Sr0.94Ti0.6Fe0.4O3-δ and 0.043 S/cm for YSTF-20YSZ at 700 oC, respectively. The value at 700 oC is approximately 2.4 times higher than that of YSTF-20YSZ. The ionic conductivity of Y0.06Sr0.94Ti0.8Fe0.2O3-δ varies from 0.015S/cm at 700 oC to 0.02 S/cm at 800 oC, respectively. The value at 800°C is approximately 12.5 times higher than YSTF-20YSZ. The ion transference numbers of YSTF-YSZ composites vary from 0.14 to 0.28 at 800 °C.


2017 ◽  
Vol 28 (1) ◽  
pp. 348-355 ◽  
Author(s):  
Khin Khin Tha ◽  
Ulrich Katscher ◽  
Shigeru Yamaguchi ◽  
Christian Stehning ◽  
Shunsuke Terasaka ◽  
...  

2012 ◽  
Vol 109 (1) ◽  
pp. 159-162 ◽  
Author(s):  
Baoan Liu ◽  
Xin Yin ◽  
Minglei Zhao ◽  
Qinghua Zhang ◽  
Mingxia Xu ◽  
...  

1987 ◽  
Vol 22 (6) ◽  
pp. 761-764 ◽  
Author(s):  
S. S. Nabatov ◽  
A. N. Dremin ◽  
S. O. Shubitidze ◽  
V. V. Yakushev

1980 ◽  
Vol 85 (B4) ◽  
pp. 1876 ◽  
Author(s):  
Tsutomu Mashimo ◽  
Ken-Ichi Kondo ◽  
Akira Sawaoka ◽  
Yasuhiko Syono ◽  
Humihiko Takei ◽  
...  

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