Reinforcement of Polymers. I. Tear Resistance of Filled Mixes and Adhesion of Elastomer to Filler as a Function of Duration and Temperature of Elastomer and Filler Contact
Abstract In accordance with the concepts being developed by the authors of the present paper, the influence of fillers on the properties of filled systems is determined by adhesion of the polymer to the filler. There are indications of the significance of this factor in many papers dealing with the study of reinforcement. However, they do not advance adhesion as a basic factor which determines reinforcement. This has become possible after the development of a procedure for the evaluation of adhesion of polymers to powdered fillers. This paper lists experimental data on the correlation between the duration and temperature of contact of the elastomer with filler particles on the tear resistance of filled mixes, on one hand, and the time and temperature dependence of the adhesion of the system components to one another, on the other. The selection of tear resistance as a characteristic of the physicomechanical properties of the system is governed by the fact that failure starts, as a rule, from a random local defect. Most frequently this is a small cut or surface crack. For this reason, the assertion of a number of researchers that the operating properties of products are more fully characterized by tear resistance rather than by tensile strength is fully acceptable. Besides, tearing is the most general type of destruction of materials, inasmuch as it takes place during rupture as well as during wear.