Rubber Resins: Some Properties and Possibilities of Use

1944 ◽  
Vol 17 (3) ◽  
pp. 731-737
Author(s):  
Charles F. Mason

Abstract However, their present uses and possible future uses deserve consideration. Their tendency to thicken in certain solvents has been applied to use in imparting false body (thickening) to certain varnishes. In such cases it is likely that the rubber resin is modified to reduce tackiness before compounding it into quick-drying spirit varnishes. As plasticizers for brittle resins and asphalts they afford a very inexpensive raw material. But, again, experiments must be performed to see if the rubber resin is compatible with the natural or synthetic one, as there is little information as to whether plasticizers form solid solutions or only mechanical mixtures with the resins after heating and mixing. In one case a large shoe manufacturer purchased many tons of gutta-percha resin for impregnation of threads used in sewing on soles; the object was to prevent the entrance of moisture into the shoe and to supply a flexible adhesive. Electric friction tape, which must have an eversoft tacky surface, is coated with a compound of a bitumen, regenerated rubber, and a gutta resin, and is similar in composition to readily appliable insulation pastes, which are used on underground electric cables. The use in ever-soft adhesives and in flypaper are only two of the minor ones. The application of these resins to textiles in the form of emulsions shows large possibilities, as they can be emulsified with ammonium oleate or linoleate and, on drying, leave behind films of rubber resin and the fat acid of the emulsifier. A hardened balata resin has been used in linoleum cement. The soft resin or even the oily one can be hardened by heating for four hours at 80° C, after adding 1 per cent of manganese resinate or 0.5 per cent of calcium carbonate. Treatment of the same resin with sulfur chloride results in a viscous resin which, when warm, can be pulled out into ropes like taffy candy and, when cold, is still viscous. In closing, the writer wishes to state that, even if a reader may fail to find here the exact information he desires about a certain rubber resin, let it be hoped that what information he does find will save many hours of fruitless toil.

2015 ◽  
Vol 77 (3) ◽  
Author(s):  
Anuar Othman ◽  
Nasharuddin Isa ◽  
Rohaya Othman

Precipitated calcium carbonate (PCC) chemically can be synthesized in the laboratory. In this study, hydrated lime or calcium hydroxide was used as raw material with sucrose as additive to produce PCC. The process was compared with the one without additive. PCC produced was observed based on morphology, mineral composition and size by using Fesem-Edx and LPSA, respectively. PCC products without additive demonstrated fine and more uniform size of calcite PCC as compared to the one with additive. Nevertheless, the process with additive produced more PCC product than without additive.


2008 ◽  
Vol 47 (18) ◽  
pp. 7104-7111 ◽  
Author(s):  
Sanni Eloneva ◽  
Sebastian Teir ◽  
Justin Salminen ◽  
Carl-Johan Fogelholm ◽  
Ron Zevenhoven

2014 ◽  
Vol 788 ◽  
pp. 28-33
Author(s):  
Peng Deng ◽  
Yu Qin Liu ◽  
Wen Gui Yao ◽  
Hong Wen Ma

In this paper, a new process for the production of the primary magnesium is introduced using the dolomite as the raw material. The magnesia and calcium carbonate were prepared from dolomite by acidification. The content of magnesium oxide can reach 98.92% about the magnesia obtained. The magnesia is used to produce primary magnesium by aluminothermic reduction under vacuum condition. The reduction ratio of MgO can be up to 86.14% under the temperature of 1200°C for 5hrs, briquetting pressure of 10MPa and the molar ratio of MgO to Al of 3:2. The content of magnesium is more than 99.90%. The major phases in the briquette residue are corundum and spinel, which can be used as refractory.


2015 ◽  
Vol 827 ◽  
pp. 203-207 ◽  
Author(s):  
Mastuki ◽  
Malik Anjelh Baqiya ◽  
Darminto

Synthesis of Ca-Fe-O using solution mixing method employing CaCO3 and Fe2O3•H2O has been conducted. Extraction of limestone as the raw material of precipitated calcium carbonate (PCC) and iron sands as that of Fe2O3•H2O was prepared to explore various compound of C-Fe-O, where the CaFe4O7 phase is mainly expected. The PCC and Fe2O3•H2O each are dissolved in 1 M HNO3 and mixed to be most homogeneous. The results of the synthesis are characterized by DTA/GTA and then sintered at temperatures of 800°C, 900°C and 1000°C.The sintered samples were characterized by XRD, FTIR, and VSM. The sintering temperature at 800°C, 900°C and 1000°C gave result the phase content of CaFe4O7 being respectively 55.42%, 44.55% and 36.39%. Other major phases in the Ca-Fe-O samples consist of Ca2Fe9O13 and Ca4Fe14O25. The remanence value of the corresponding samples is 2.11, 1.28, and 1.74 emu/g respectively.


2015 ◽  
Vol 2015 ◽  
pp. 1-14 ◽  
Author(s):  
Hamed Khodadadi Tirkolaei ◽  
Huriye Bilsel

Calcium carbonate is a widely used raw material by many industries. It can be precipitated through microbial process within soil pores as cementitious bonding agent between grains for geotechnical applications. It is called microbially induced calcium carbonate precipitation (MICP). Designing an appropriate biogrout material for injection into soil is essential for controlling the amount, type, time, and place of the biocement production within pores. For this purpose, understanding the active reactions and the kinetics of bacterial growth and urea hydrolysis is necessary. A conductometric method and spectrophotometry were used in this study to, respectively, monitor the urea hydrolysis reaction progress and bacterial growth inS. pasteurii-inoculated urea-NB-NH4Cl solution at different level of the environmental factors that are initial cell concentration, urea concentration, and temperature. Variation in conductivity of the solution versus logarithmic scale of time was depicted as microbial ureolysis characteristic curve (MUCC) through which lag duration, specific rate, and potential of urea hydrolysis at each condition were obtained. Central composite face-centered (CCF) design, which is one of the response surface methodologies, was employed to statistically fit polynomial models explaining the bacterial growth and the characteristics obtained from MUCCs in terms of the environmental factors and their interactions. An optimization analysis based on the urea-normalized responses was also carried out.


2011 ◽  
Vol 75 (5) ◽  
pp. 2573-2582 ◽  
Author(s):  
C. H. Yoder ◽  
R. W. Schaeffer ◽  
P. McWilliams ◽  
A. Rowand ◽  
X. Liu ◽  
...  

AbstractThe relative stabilities of the copper/zinc solid solutions of hydroxyl sulphates, carbonates, nitrates, chlorides and bromides were studied by attempting their preparation using a variety of methods. All of the naturally occurring solid solutions except rosasite were obtained as single phases. Rosasite crystallized in a mixture with malachite and calcium carbonate during a room temperature preparation from calcium carbonate, copper nitrate and zinc nitrate. The solid solution with the antlerite stoichiometry [endmember Cu3SO4(OH)4] as well as the nitrates were not produced by the methods employed. All of the natural polymorphs of Cu2(OH)3Cl were obtained and a new method for the preparation of botallackite is reported. Botallackite was found to be stable in solution for over a year, contrary to previous reports. A bromine-bearing analogue of botallackite was prepared. Compounds were characterized by X-ray diffractometry, which was used to determine the unit-cell parameters, and by atomic absorption spectroscopy. The relative instability of solid solutions with certain stoichiometries is discussed in terms of the Jahn-Teller effect and relative solubilities.


2016 ◽  
Vol 851 ◽  
pp. 8-13
Author(s):  
Nuchnapa Tangboriboon ◽  
Jularpar Suttiprapar

Calcium hydroxyapatite made from duck eggshell react to phosphoric acid with the Ca/P mole ratio 1.67 and calcined at 800º, 900º, and 1000°C for each temperature 2 hr. Duck eggshell is a source of calcium carbonate having high purity content more than 98.101 %w/w and small amount of other metal oxides. Duck eggshell is a bio-material similar to other calcium sources i.e. coral, animal bone, and seashell. There are many advantages of using duck eggshell as a raw material such as abundant, low price, high purity of calcium carbonate content, easy to calcium phosphate formation, biocompatibility, bioactive, non-toxic for human, and the high percentage of ceramic yield 69.73%w/w. In addition, one of the most important advantages is to reduce the amount of duck eggshell waste from household and food industries as environmental conservation. The optimum condition to obtain high purity hydroxyapatite is sintering calcium phosphate at 1000°C for 2 hr. The average particle size, specific surface are, pore diameter, and true density of sample sintered at 1000°C for 2 hr are 39.92 µm, 2.12 m2/g, 98.96 Å, 3.02 g/cm3, respectively, in soft fine white powder. Furthermore, the results obtained by XRF, SEM, and XRD confirmed of sample fired at 1000°C for 2 hr to be calcium hydroxyapatite (HA, Ca10(PO4)6(OH)2) of Ca/P mole ratio 1.67 and small amount of calcium phosphate (β-TCP, Ca3PO4) of Ca/P mole ratio 1.5. Therefore, the duck eggshell is a potentially bio-ceramic material to prepare calcium hydroxyapatite applied for biomedical, bio-dental, and many industries i.e. pharmaceutical, toothpaste, cosmetic, and nutrient food etc.


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